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公开(公告)号：US20230016289A1
公开(公告)日：2023-01-19
申请号：US17783041
申请日：2020-12-09
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Paul T. Q. Nguyen , Edward J. Blok , Anthony J. Dias , Ranjan Tripathy , Jason A. Mann
Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 20 to about 40 phr of a polybutadiene having a cis-1,4 linkage content of at least 95%; about 40 to about 70 phr styrene/ butadiene copolymer; about 5 to about 30 phr natural rubber or polyisoprene; a curative agent; an antioxidant; about 1 to about 20 phr carbon black; about 1 to about 30 phr plasticizing oil; about 40 to about 80 phr silica; about 1 to about 15 phr silane coupling agent and about 5 to about 30 phr of a polymer selected from the group consisting of an ethylene-propylene-diene terpolymer, butyl rubber, poly(isobutylene-co-para-methylstyrene) and poly(isobutylene-co-para-methylstyrene-co-isoprene) terpolymer.
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公开(公告)号：US20210017369A1
公开(公告)日：2021-01-21
申请号：US17043254
申请日：2019-04-09
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Anthony J. Dias , Paul T.Q. Nguyen , Erick E, Wurzinger , Andy H. Tsou
IPC: C08L23/16 , C08L23/32 , C08F136/06 , C08F136/08 , C08L9/06 , C08L7/00 , C08L57/02 , C08K3/04 , C08K3/36 , C08K3/06 , C08K5/18 , C08K5/548 , B60C1/00
Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 30 to about 50 phr of polybutadiene having a cis-1,4 linkage content of at least 95%; about 40 to about 60 phr of styrene/butadiene copolymer; about 0 to about 20 phr of natural rubber or polyisoprene; about 0 to about 30 phr of a processing oil; about 10 to about 30 phr of a hydrocarbon resin; about 50 to about 75 phr of a filler; a curative agent; an antioxidant; a silane coupling agent; and about 5 to about 30 phr of a propylene-ethylene-diene terpolymer containing from about 2 wt % to about 30 wt % of ethylene and/or C4-C20 α-olefins derived units.
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公开(公告)号：US20200094234A1
公开(公告)日：2020-03-26
申请号：US16575835
申请日：2019-09-19
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Lubin Luo , Edward J. Blok , Alan A. Galuska , Anupriya Jain , Alexander V. Zabula , Yen-Hao Lin
Abstract: A process to form a cyclic olefin polymerization catalyst which includes contacting a metal alkoxide with a transition metal halide to form a transition metal precatalyst, and contacting the transition metal precatalyst with a metal alkyl activator to form the activated catalyst comprising a transition metal carbene moiety. A cyclic olefin polymerization process is also disclosed.
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24.发明申请公开(公告)号：US20190284319A1
公开(公告)日：2019-09-19
申请号：US16356826
申请日：2019-03-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Rhutesh K. Shah , Jo Ann M. Canich , Edward J. Blok
IPC: C08F210/16
Abstract: This invention relates to production of propylene-predominant copolymers using a transition metal complex and at least two different non-coordinating anion activators. An olefinic feed comprising a C3-C40 alpha olefin, ethylene, and a diene monomer is contacted under polymerization reaction conditions with a catalyst system comprising a first non-coordinating anion activator, a second non-coordinating borate activator differing from the first non-coordinating anion activator, and a transition metal complex comprising a tetrahydro-s-indacenyl or tetrahydro-as-indacenyl group bound to a group 3-6 transition metal. A molar ratio of the first non-coordinating anion activator to the second non-coordinating anion activator is sufficient to produce a melt flow rate under the polymerization reaction conditions for the resulting copolymer of about 30 g/10 min or below as determined by ASTM D-1238 (230° C., 2.16 kg).
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公开(公告)号：US10336845B2
公开(公告)日：2019-07-02
申请号：US15503146
申请日：2015-08-31
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Andy H. Tsou , Edward J. Blok , Gabor Kiss , Rhutesh K. Shah
IPC: C08L9/00 , C08F210/18 , B60C1/00 , C08F290/04 , C08L21/00 , C08L23/16 , C08K3/013 , C08L7/00 , C08F4/659
Abstract: A propylene-ethylene-diene terpolymer and method of making such comprising from 2% to 25% wt % by weight of ethylene, from 98% to 75% wt % by weight propylene and from 1% to 21% wt % by weight of a diene, wherein the terpolymer has a crystallinity of less than 3%, a melt flow rate (MFR) of less than 10 and a Tg by DSC of from −2° C. to −25° C. and methods to prepare the terpolymer are depicted.
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Patent Agency Ranking
公开(公告)号：US10059782B2
公开(公告)日：2018-08-28
申请号：US15118730
申请日：2015-03-06
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Ian C. Stewart , David T. Harris
IPC: C08F8/42 , B60C1/00 , C08F279/00 , C08F291/02 , C08K5/00 , C08L9/00 , C08L21/00 , C08L51/04 , C08L9/06
CPC classification number: C08F8/42 , B60C1/0016 , C08F279/00 , C08F291/02 , C08K3/00 , C08K5/0025 , C08L9/00 , C08L9/06 , C08L21/00 , C08L51/04 , C08F230/08
Abstract: This invention relates to a process for the preparation of a silane-functionalized resin composition comprising the steps of mixing a polymer backbone, a silane, and a free radical initiator; and producing a silane-functionalized resin composition. The polymer backbone is selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof.
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公开(公告)号：US09994664B2
公开(公告)日：2018-06-12
申请号：US15283647
申请日：2016-10-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Eugene R. Uhl , Edward J. Blok , Dennis Kumor , Randal H. Kerstetter, III , Ronald DeYoung
IPC: B29B9/06 , C08F279/00 , C08L101/10 , B60C1/00 , C08C19/25 , C08J3/12 , C08L23/22 , B29D30/06 , C08K3/36 , C08L45/00 , C08L47/00 , C08L101/02 , C08F8/42 , C08L51/00 , C08F10/14 , B29K9/00
CPC classification number: C08F279/00 , B29B9/065 , B29D30/06 , B29K2009/00 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0041 , C08C19/25 , C08F8/42 , C08F10/14 , C08J3/12 , C08J2351/00 , C08K3/36 , C08L21/00 , C08L23/22 , C08L45/00 , C08L47/00 , C08L51/003 , C08L101/02 , C08L101/10 , Y02T10/862 , Y10T156/10 , C08F240/00
Abstract: An underwater pelletizing method for pelletizing brittle hydrocarbon resins with low melt viscosity. A feed material comprising the hydrocarbon resin is formed into a melt, extruded through a die into a water bath below the Tg of the hydrocarbon resin to form a plurality of extrudates and cut adjacent the die surface to form a slurry of resin pellets. A graft monomer and/or other reactants, such as a hydrosilylation agent, may be introduced into the resin melt to chemically modify the hydrocarbon resin.
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公开(公告)号：US09840569B2
公开(公告)日：2017-12-12
申请号：US15118701
申请日：2015-03-06
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Ian C. Stewart , David T. Harris
CPC classification number: C08F8/42 , B60C1/0016 , C08F2810/30 , C08F2810/40 , C08K3/36 , C08K5/548 , C08L9/00 , C08L9/06 , C08L45/00 , C08L2205/025 , C08F132/08
Abstract: This invention relates to a functionalized resin composition having the formula P—S—X where S is a spacer selected from at least one of C2-C40 straight chain and branched alkyl, C6-C40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, and X is a silane.
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公开(公告)号：US20170022315A1
公开(公告)日：2017-01-26
申请号：US15283647
申请日：2016-10-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Eugene R. Uhl , Edward J. Blok , Dennis Kumor , Randal H. Kerstetter, III , Ronald DeYoung
CPC classification number: C08F279/00 , B29B9/065 , B29D30/06 , B29K2009/00 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0041 , C08C19/25 , C08F8/42 , C08F10/14 , C08J3/12 , C08J2351/00 , C08K3/36 , C08L21/00 , C08L23/22 , C08L45/00 , C08L47/00 , C08L51/003 , C08L101/02 , C08L101/10 , Y02T10/862 , Y10T156/10 , C08F240/00
Abstract: An underwater pelletizing method for pelletizing brittle hydrocarbon resins with low melt viscosity. A feed material comprising the hydrocarbon resin is formed into a melt, extruded through a die into a water bath below the Tg of the hydrocarbon resin to form a plurality of extrudates and cut adjacent the die surface to form a slurry of resin pellets. A graft monomer and/or other reactants, such as a hydrosilylation agent, may be introduced into the resin melt to chemically modify the hydrocarbon resin.
Abstract translation: 一种用于造粒具有低熔体粘度的脆性烃树脂的水下造粒方法。 将包含烃树脂的进料材料形成熔体，通过模具挤出到低于烃树脂的Tg的水浴中以形成多个挤出物，并在模具表面附近切割以形成树脂颗粒的浆料。 可以将接枝单体和/或其它反应物（例如氢化硅烷化剂）引入树脂熔体中以化学改性烃树脂。
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公开(公告)号：US12043729B2
公开(公告)日：2024-07-23
申请号：US17040845
申请日：2019-03-29
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Paul Tu Quang Nguyen , Ranjan Tripathy , Jason A. Mann , Yuan-Ju Chen , Edward J. Blok , Anthony J. Dias , Abdul M. Jangda
IPC: C08L23/22 , C08F8/32 , C08F8/40 , C08F8/44 , C08K3/06 , C08K5/00 , C08K5/31 , C08K5/40 , C08K5/435 , C08K5/44
CPC classification number: C08L23/22 , C08F8/32 , C08F8/40 , C08F8/44 , C08K3/06 , C08K5/0025 , C08K5/31 , C08K5/40 , C08K5/435 , C08K5/44 , C08F2810/30 , C08F2810/50 , C08L2312/00
Abstract: Provided herein are isobutylene-based polymer compositions comprising functionalized isobutylene-based polymer with olefinic side chain substituents, and a sulfur donor and/or accelerator cure system. The functionalized polymer is produced via nucleophilic substitution reaction in solution. The present functionalized isobutylene-based polymer compositions together with various accelerators and sulfur donors can form thermosets useful for pharmaceutical and tire applications without the use of zinc or a zinc oxide activator.
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