摘要:
The present invention provides zeolites and zeolite-like material having an enhanced microporosity. It was found that such zeolites can be obtained using a zeolite synthesis method comprising the preparation of a gel or solution for the synthesis of a zeolite, said gel or solution comprising appropriate amounts of (i) a conventional monomeric or polymeric silica source and (ii) a molecular template as a microstructuring agent, characterized in that said gel or solution further comprises an organosilane compound having limited self-assembling capacity.
摘要:
The invention pertains to a catalyst that consists of a substrate made of at least one matrix and at least one zeolite that is selected from the group composed of the zeolites ZSM-48, EU-11, and ZBM-30, whereby, at the level of the zeolite, at least one noble metal of Group VIII is deposited on said substrate. The noble metal is preferably located on the outer surfaces of the zeolite crystals, and more preferable at the mouths of pores. The invention also pertains to a process for preparing the catalyst and utilizing the catalyst to treat hydrocarbon feedstocks, and especially for improving their pour points.
摘要:
The invention relates to an intraluminal device, in particular an intraluminal prosthesis, shunt, catheter or local drug delivery device. In order to increase the bio-compatibility of this device, it is provided with at least one coating. The coating contains a therapeutic agent which is comprised in a matrix that sticks to the intraluminal device. Instead of being formed by a little bio-compatible polymer, the matrix is formed by a bio-compatible oil or fat, such as cod-liver oil or olive oil. Preferably, the bio-compatible oil or fat further comprises alfa-tocopherol.
摘要:
The present invention relates to a new synthesis procedure for a family of silica based polymer materials synthesized through the interconnection of silicate oligomers with reactive silanes. By using this synthesis it is possible to generate novel silica based polymer materials. The present invention thus also relates to the members of this group of ordered silica based polymer materials whereby silicate oligomers are interconnected trough siloxane bridges and with empirical formulae Abx, whereby A presents the silicate oligomer, b the siloxane bridge and x the ratio between the number of silanes and the number of silicate oligomers in the material. This group of materials are particularly useful for certain applications. In another aspect, the present invention provides the use of the materials of present invention as a fire retardant coating, to enforce polymers, as a cross linking agent in polymers, as adsorbent in water purification, in separation processes, as catalyst or catalyst support in catalysis, for spin-coating of thin films, for spin-coating of thin films with low k dielectric layers in integrated circuit applications, in sensors, as (super)hydrophobic anti-ice coating on airplanes and windmills, as anti-fouling coating inside for instance in pipelines, as anti-dirt coating.
摘要:
Treatment of a fungal biofilm on implants is via a combination of drugs and/or via the implant pre-treatment with one drug or via the combination of drugs.
摘要:
The present invention relates to the use of atomic layer deposition (ALD) techniques to enhance the acid catalytic activity of nanoporous materials.
摘要:
A method is provided for making pure-silica-zeolite films useful as low-k material, specifically, more hydrophobic, homogeneous and with absence of cracks. The method utilizes a UV cure; preferably the UV cure is performed at temperatures at higher than the deposition temperature. The UV-assisted cure removes the organic template promoting organic functionalization and silanol condensation, making the silica-zeolite films more hydrophobic. Moreover, the zeolite material is also mechanically stronger and crack-free. The method can be used to prepare pure-silica-zeolite films more suitable as low-k materials in semiconductor processing.
摘要:
The invention provides a controlled release delivery system comprising a bio-active compound and a matrix carrier, wherein said matrix carrier is an amorphous microporous non-fibrous silicon or titanium oxide being loaded with said bio-active compound and wherein the micropores of said matrix carrier have a mean size in the range of 0.4 to 2.0 nm.
摘要:
The invention describes a new class of crystalline silica material having two levels or porosity and structural order. At the first level, building units are nanoslabs of uniform size having zeolite framework. At the second structural level, nanoslabs are assembled, e.g. linked through their corners, edges or faces following patterns imposed by interaction with cationic surfactant or triblock copolymer molecules. After evacuation of these molecules, microporosity is obtained inside the nanoslabs, and a precise mesoporosity between the nanoslabs depending on the tiling pattern of the zeolite nanoslabs, as evidenced by X-ray diffraction. These materials are useful for the fixation of biologically active species, such as poorly soluble drugs.
摘要:
Disclosed is a process for the preparation of 2-butene-1,4-diol comprising contacting a mixture of water and 1,2-epoxy-3-butene with a catalyst comprising a metal halide, zeolite and a non-protic solvent.