Catalyst for light cycle oil upgrading
    22.
    发明授权
    Catalyst for light cycle oil upgrading 失效
    催化剂用于轻循环油升级

    公开(公告)号:US5219814A

    公开(公告)日:1993-06-15

    申请号:US629952

    申请日:1990-12-19

    IPC分类号: B01J29/16 C10G47/20

    CPC分类号: C10G47/20 B01J29/166

    摘要: A moderate pressure hydrocracking process in which a highly aromatic, substantially dealkylated feedstock is processed to high octane gasoline and low sulfur distillate by hydrocracking over a catalyst, preferably comprising ultrastable Y and a Group VIII metal and a Group VI metal, in which the amount of the Group VIII metal content is incorporated at specified proportion into the framework aluminum content of the ultrastable Y component. The feedstock which is preferably a light cycle oil has an aromatic content of at least 50, usually at least 60 percent, and an API gravity not more than 25. The hydrocracking typically operates at 400-1000 psig at moderate to high conversion levels to maximize the production of monocyclic aromatics which provide the requisite octane value to the product gasoline. The distillate products from the hydrocracker are reduced in their sulfur content.

    摘要翻译: 中等压力加氢裂化方法,其中高度芳香的,基本上脱烷基化的原料通过催化剂上的加氢裂化加工成高辛烷值汽油和低硫馏分,优选包括超稳定Y和VIII族金属和第VI族金属,其中 第VIII族金属含量以规定比例掺入超稳Y组分的骨架铝含量中。 优选轻循环油的原料具有至少50,通常至少60%的芳烃含量,API重力不超过25.加氢裂化通常在中等至高转化率的400-1000psig下操作,以使 生产提供产品汽油必需辛烷值的单环芳烃。 来自加氢裂化器的馏出物的硫含量降低。

    Method of flocculation and formulation of crystalline materials
    23.
    发明授权
    Method of flocculation and formulation of crystalline materials 有权
    结晶材料的絮凝和配制方法

    公开(公告)号:US07737316B2

    公开(公告)日:2010-06-15

    申请号:US11453154

    申请日:2006-06-14

    IPC分类号: C07C1/00 B01J27/182

    摘要: A method for determining an amount of flocculant effective to recover a molecular sieve crystalline product that comprises the steps of (a) preparing a molecular sieve crystalline product mixture; (b) separating the molecular sieve crystalline product mixture into a plurality of samples; (c) mixing at least two of the plurality of samples with a quantity of flocculant to produce a plurality of flocculated samples, wherein at least two of the plurality of flocculated samples have a different ratio of flocculant to molecular sieve crystalline product mixture; (d) measuring the viscosity or zeta potential of at least two of the plurality of flocculated samples having a different ratio of flocculant to molecular sieve crystalline product mixture; (e) establishing a relationship between the quantity of flocculant and the viscosity or zeta potential measurements; and (f) determining from the relationship the amount of flocculant effective to recover the molecular sieve crystalline product.

    摘要翻译: 一种用于测定有效回收分子筛结晶产物的絮凝剂的量的方法,其包括以下步骤:(a)制备分子筛结晶产物混合物; (b)将分子筛结晶产物混合物分离成多个样品; (c)将多个样品中的至少两个与一定量的絮凝剂混合以产生多个絮凝样品,其中所述多个絮凝样品中的至少两个具有不同的絮凝剂与分子筛结晶产物混合物的比例; (d)测量具有不同比例的絮凝剂与分子筛结晶产品混合物的多个絮凝样品中的至少两个的粘度或ζ电位; (e)建立絮凝剂的数量与粘度或ζ电位测量之间的关系; 和(f)从关系中确定有效回收分子筛结晶产物的絮凝剂的量。

    Catalyst and process for isoparaffin-olefin alkylation
    26.
    发明授权
    Catalyst and process for isoparaffin-olefin alkylation 失效
    用于异链烷烃烯烃烷基化的催化剂和方法

    公开(公告)号:US5516962A

    公开(公告)日:1996-05-14

    申请号:US283928

    申请日:1994-08-01

    IPC分类号: B01J29/04 C07C2/58

    CPC分类号: B01J29/04

    摘要: There are provided a catalyst, a method for making this catalyst, and a process for using this catalyst in the alkylation of an isoparaffin with an olefin to provide an alkylate. The catalyst may be made from an as-synthesized material which, upon calcination, is capable of generating zeolites designated MCM-22. The as-synthesized material is then combined with a binder material, such as alumina, by an extrusion process. The uncalcined bound material may then be ammonium exchanged, followed by a calcination treatment. The as-synthesized material may also be swollen with a suitable swelling agent, such as a cetyltrimethylammonium compound, prior to the binding process.

    摘要翻译: 提供催化剂,制备该催化剂的方法,以及使用该催化剂将异链烷烃与烯烃烷基化以提供烷基化物的方法。 催化剂可以由合成原料制成,其在煅烧时能够产生称为MCM-22的沸石。 然后通过挤出方法将合成后的材料与粘合剂材料如氧化铝组合。 然后将未煅烧的结合材料进行铵交换,随后进行煅烧处理。 在结合过程之前,合成的材料也可以用合适的溶胀剂如十六烷基三甲基铵化合物溶胀。

    Gasoline upgrading process
    29.
    发明授权
    Gasoline upgrading process 失效
    汽油升级过程

    公开(公告)号:US5298150A

    公开(公告)日:1994-03-29

    申请号:US929544

    申请日:1992-08-13

    摘要: Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment over an acidic catalyst comprising a zeolite sorbing 10 to 40 mg 3-methylpentane at 90.degree. C., 90 torr, per gram dry zeolite in the hydrogen form, e.g., ZSM-22, ZSM-23, or ZSM-35. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. The use of the specified zeolite provides greater desulfurization, gasoline selectivity, and octane than obtained using ZSM-5.

    摘要翻译: 相对高辛烷值的低硫汽油由催化裂化的含硫石脑油通过加氢脱硫然后在含有吸附10至40mg 3-甲基戊烷的沸石酸性催化剂上处理,该沸石在90℃,90托,每克 氢形式的干沸石,例如ZSM-22,ZSM-23或ZSM-35。 在第二步骤中对酸性催化剂的处理恢复了由于氢化处理而发生的辛烷值损失,并导致具有与进料石脑油相当的辛烷值的低硫汽油产物。 使用指定的沸石比使用ZSM-5获得的提供更大的脱硫,汽油选择性和辛烷值。