Low oxygen biomass-derived pyrolysis oils and methods for producing the same
    21.
    发明授权
    Low oxygen biomass-derived pyrolysis oils and methods for producing the same 有权
    低氧生物质衍生的裂解油及其制备方法

    公开(公告)号:US08404910B2

    公开(公告)日:2013-03-26

    申请号:US12707408

    申请日:2010-02-17

    IPC分类号: C07C1/00

    摘要: Methods are provided for producing low oxygen biomass-derived pyrolysis oil from carbonaceous biomass feedstock. The carbonaceous biomass feedstock is pyrolyzed in the presence of a steam reforming catalyst to produce char and pyrolysis gases. During pyrolysis, a portion of the oxygenated hydrocarbons in the pyrolysis gases is converted into hydrocarbons by steam reforming also yielding carbon oxides and hydrogen gas. The hydrogen gas at least partially deoxygenates a residual portion of the oxygenated hydrocarbons. Additional hydrogen gas may also be produced by water-gas shift reactions to deoxygenate the residual portion of the oxygenated hydrocarbons in the pyrolysis gases. Deoxygenation may occur in the presence of a hydroprocessing catalyst. A condensable portion of the pyrolysis gases is condensed to form low oxygen biomass-derived pyrolysis oil.

    摘要翻译: 提供用于从含碳生物质原料生产低氧生物质衍生的热解油的方法。 碳水生物质原料在蒸汽重整催化剂存在下热解生成焦炭和裂解气。 在热解过程中,热分解气体中的一部分氧化烃通过也可产生碳氧化物和氢气的蒸汽重整转化为烃。 氢气至少部分地使氧化烃的残留部分脱氧。 还可以通过水煤气变换反应产生另外的氢气,以使热解气体中的氧化烃的残余部分脱氧。 脱氧可能在加氢处理催化剂存在下进行。 热解气体的可冷凝部分被冷凝以形成低氧生物质衍生的热解油。

    PROCESS FOR PRODUCING TEREPHTHALIC ACID
    23.
    发明申请
    PROCESS FOR PRODUCING TEREPHTHALIC ACID 有权
    生产过敏性酸的方法

    公开(公告)号:US20120004450A1

    公开(公告)日:2012-01-05

    申请号:US13155553

    申请日:2011-06-08

    IPC分类号: C07C51/265 C07C51/16

    摘要: A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid.

    摘要翻译: 固体对苯二甲酸组合物和由对二甲苯生产对苯二甲酸的方法。 该方法包括形成包含对二甲苯,溶剂,溴源和催化剂的混合物; 并通过在氧化条件下将氧化剂与氧化剂接触来氧化对二甲苯以产生包含对苯二甲酸,对甲苯甲酸,4-羧基苯甲醛的固体氧化产物。 溶剂包括具有1至7个碳原子的羧酸和二烷基咪唑鎓离子液体; 催化剂包括钴,钛,锰,铬,铜,镍,钒,铁,钼,锡,铈和锆中的至少一种。 固体对苯二甲酸组合物包含小于约4,000ppm重量的4-羧基苯甲醛含量和大于约2,000ppm重量的对甲苯甲酸。

    LOW OXYGEN BIOMASS-DERIVED PYROLYSIS OILS AND METHODS FOR PRODUCING THE SAME
    26.
    发明申请
    LOW OXYGEN BIOMASS-DERIVED PYROLYSIS OILS AND METHODS FOR PRODUCING THE SAME 审中-公开
    低氧生物质衍生的热解油及其生产方法

    公开(公告)号:US20110232166A1

    公开(公告)日:2011-09-29

    申请号:US12731992

    申请日:2010-03-25

    申请人: Joseph A. Kocal

    发明人: Joseph A. Kocal

    IPC分类号: C10L1/18

    摘要: Methods are provided for producing low oxygen biomass-derived pyrolysis oil from carbonaceous biomass feedstock. In an embodiment, hydrogen gas is produced in the presence of a low temperature reforming catalyst from hemicellulose extracted from the carbonaceous biomass feedstock. The carbonaceous biomass feedstock, both whole and hemicellulose-depleted, is pyrolyzed in the presence of a pyrolysis upgrading catalyst to produce char and pyrolysis gases comprising oxygenated hydrocarbons and steam. A portion of the oxygenated hydrocarbons are converted into hydrocarbons. A residual portion of the oxygenated hydrocarbons of the pyrolysis gases is deoxygenated with the hydrogen and optionally, additional hydrogen gas. A condensable portion of the pyrolysis gases is condensed into low oxygen biomass-derived pyrolysis oil.

    摘要翻译: 提供用于从含碳生物质原料生产低氧生物质衍生的热解油的方法。 在一个实施方案中,在从碳质生物质原料提取的半纤维素的低温重整催化剂存在下,产生氢气。 碳质生物质原料(全部和半纤维素贫化)在热解提质催化剂存在下热解,以产生包含含氧烃和蒸汽的焦炭和热解气体。 一部分氧化烃转化成烃。 热解气体的氧化烃的残余部分与氢气和任选的另外的氢气脱氧。 热解气体的可冷凝部分被冷凝成低氧生物质衍生的裂解油。

    Methods of denitrogenating diesel fuel
    28.
    发明授权
    Methods of denitrogenating diesel fuel 有权
    脱氮柴油的方法

    公开(公告)号:US07749377B2

    公开(公告)日:2010-07-06

    申请号:US11985144

    申请日:2007-11-14

    IPC分类号: C10G17/00

    CPC分类号: C10G45/02 C10G21/20 C10G21/22

    摘要: A process for denitrogenating diesel fuel includes contacting diesel fuel containing one or more nitrogen compounds with an acid ionic liquid in an extraction zone to selectively remove the nitrogen compound(s) and produce a denitrogenated diesel fuel effluent containing denitrogenated diesel fuel and acid ionic liquid containing nitrogen species; and separating denitrogenated diesel fuel from the denitrogenated diesel fuel effluent.

    摘要翻译: 一种用于脱氮柴油的方法包括将含有一种或多种氮化合物的柴油与酸性离子液体在萃取区中接触以选择性地除去氮化合物,并产生含有脱氮柴油燃料和酸性离子液体的脱氮柴油燃料流出物, 氮物种 并将脱氮的柴油与脱氮的柴油流出物分离。

    PROCESS FOR THE DIRECT PRODUCTION OF METHANOL FROM METHANE
    30.
    发明申请
    PROCESS FOR THE DIRECT PRODUCTION OF METHANOL FROM METHANE 有权
    从甲烷直接生产甲醇的方法

    公开(公告)号:US20070149833A1

    公开(公告)日:2007-06-28

    申请号:US11560960

    申请日:2006-11-17

    IPC分类号: C07C29/03

    摘要: A process for the production of methanol from methane has been developed. The process involves reacting methane with an oxidant such as oxygen or a peroxide in the presence of a catalyst and a solvent in a reaction zone to produce an effluent stream comprising a methanol product. The effluent stream is next separated into a gaseous stream comprising unreacted methane and carbon dioxide and a liquid stream comprising the methanol product and solvent. Next the gaseous stream is further separated to provide a methane stream which is recycled to the reaction zone. Finally, a methanol stream is isolated and a solvent stream is recycled to the reaction zone.

    摘要翻译: 已经开发了从甲烷生产甲醇的方法。 该方法包括在反应区中在催化剂和溶剂存在下使甲烷与氧化剂如氧或过氧化物反应,以产生包含甲醇产物的流出物流。 然后将流出物流分离成包含未反应的甲烷和二氧化碳的气流以及包含甲醇产物和溶剂的液体流。 接下来,进一步分离气流以提供甲烷流,其被再循环到反应区。 最后,分离甲醇流,将溶剂流再循环到反应区。