Method for treating magnesium alloy by chemical conversion
    21.
    发明授权
    Method for treating magnesium alloy by chemical conversion 失效
    通过化学转化处理镁合金的方法

    公开(公告)号:US06755918B2

    公开(公告)日:2004-06-29

    申请号:US10167479

    申请日:2002-06-13

    IPC分类号: C23C2200

    摘要: The present invention discloses a method for treating magnesium alloys by chemical conversion. This method can improve corrosion resistance and paint adhesion of magnesium alloys, and produces an admirable appearance. Additionally, the method of the present invention is more environmentally friendly than conventional processes, because non-chromate chemicals are used in acid pickling and chemical conversion. Furthermore, the method of the present invention can be widely applied to the magnesium alloys manufactured by casting and rolling.

    摘要翻译: 本发明公开了一种通过化学转化处理镁合金的方法。 该方法可以提高镁合金的耐腐蚀性和涂料附着力,并产生令人羡慕的外观。 此外,本发明的方法比常规方法更环保,因为在酸洗和化学转化中使用非铬酸盐化学品。 此外,本发明的方法可以广泛地应用于通过铸造和轧制制造的镁合金。

    METHOD FOR PREPARING PLASTIC PARTICLES COATED WITH METAL
    22.
    发明申请
    METHOD FOR PREPARING PLASTIC PARTICLES COATED WITH METAL 审中-公开
    制备涂有金属的塑料颗粒的方法

    公开(公告)号:US20120094035A1

    公开(公告)日:2012-04-19

    申请号:US12906317

    申请日:2010-10-18

    IPC分类号: C23C22/78

    摘要: The present invention relates to a method for preparing plastic particles coated with metal, which comprises the following steps. First, mix a plurality of plastic particles with a tin/palladium solution to form a first mixed liquid. Alternatively, first mix the plurality of plastic particles with a stannous chloride/hydrochloric acid solution. Then mix the plurality of plastic particles adsorbing the plurality of stannous ions with a palladium chloride/hydrochloric acid solution and form the first mixed liquid. Next, microwave the first mixed liquid so that the tin/palladium colloidal particles coat the plastic particles and thus forming first metal particles. Afterwards, mix the first metal particles with an electroless nickel solution and form a second mixed liquid. Metal nickel then coats the first metal particles and forming a plurality of second metal particles. Use microwave to activate the plurality of tin/palladium colloidal particles adsorbed on the surfaces of the plastic particles, and hence increasing adsorption of the plated metal layer on the surfaces of the plastic particle. Thereby, roughness and peeling-off of the plated metal layer can be reduced.

    摘要翻译: 本发明涉及一种制备涂覆有金属的塑料颗粒的方法,包括以下步骤。 首先,将多个塑料颗粒与锡/钯溶液混合以形成第一混合液体。 或者,首先将多个塑料颗粒与氯化亚锡/盐酸溶液混合。 然后将多个吸附多个亚锡离子的塑料颗粒与氯化钯/盐酸溶液混合并形成第一混合液体。 接下来,对第一混合液进行微波处理,使得锡/钯胶体粒子涂覆塑料粒子,形成第一金属粒子。 然后,将第一金属颗粒与无电镍溶液混合并形成第二混合液体。 然后,金属镍涂覆第一金属颗粒并形成多个第二金属颗粒。 使用微波来激活吸附在塑料颗粒表面上的多个锡/钯胶体颗粒,从而增加电镀金属层在塑料颗粒表面上的吸附。 由此,可以减少电镀金属层的粗糙度和剥离。

    Preparing method for coating PMMA particles with silicon dioxide
    23.
    发明授权
    Preparing method for coating PMMA particles with silicon dioxide 有权
    用二氧化硅涂覆PMMA颗粒的制备方法

    公开(公告)号:US08354138B2

    公开(公告)日:2013-01-15

    申请号:US12637713

    申请日:2009-12-14

    摘要: A preparing method for coating polymethylmethacrylate (PMMA) particles with silicon dioxide is disclosed and includes the following steps of: preparing a silicon dioxide solution by mixing a silicon dioxide powder and a solvent; adding a dispersant-and-interface-modifier agent into the silicon dioxide solution; performing a wet grinding to the silicon dioxide solution with the dispersant-and-interface-modifier agent so as to obtain a plurality of nano-sized silicon dioxide particles with negative charge; performing an interface modification to a plurality of PMMA particles to be charged with positive charge; adding the PMMA particles into the silicon dioxide solution; making the PMMA particles adsorb the nano-sized silicon dioxide particles; and performing a solid-liquid separation process to the silicon dioxide solution so as to obtain the chemical composite particles.

    摘要翻译: 公开了一种用二氧化硅涂覆聚甲基丙烯酸甲酯(PMMA)颗粒的制备方法,包括以下步骤:通过混合二氧化硅粉末和溶剂来制备二氧化硅溶液; 在二氧化硅溶液中加入分散剂和界面改性剂; 用分散剂 - 界面改性剂对二氧化硅溶液进行湿式研磨,得到多个具有负电荷的纳米尺寸的二氧化硅颗粒; 对要充满正电荷的多个PMMA粒子进行界面修饰; 将PMMA颗粒加入到二氧化硅溶液中; 使PMMA颗粒吸附纳米尺寸的二氧化硅颗粒; 对二氧化硅溶液进行固液分离处理,得到化学复合粒子。

    Method for preparing surface modification coating of metal bipolar plates
    25.
    发明申请
    Method for preparing surface modification coating of metal bipolar plates 审中-公开
    金属双极板表面改性涂层的制备方法

    公开(公告)号:US20100323101A1

    公开(公告)日:2010-12-23

    申请号:US12585366

    申请日:2009-09-14

    IPC分类号: H01M4/04

    摘要: A method for preparing a surface modification coating of metal bipolar plates is disclosed, which comprises the following steps: providing a metal substrate; pre-treating the metal substrate by substrate processing, depositing a Ni-based alloy layer on the metal substrate, or the combination thereof to form an activated layer on the surface of the metal substrate; packing the metal substrate in a powder mixture comprising permeated master metal, an activator, and filler powders; heat-treating the metal substrate in the powder mixture to allow the permeated master metal to diffuse into the activated layer and then to form a surface modification coating. The permeation rate of the permeated master metal can be increased due to high defect concentration of the activated layer. Hence, a corrosion-resistant surface modification coating is prepared at a low temperature, and it can decrease the interface contact resistance between the metal bipolar plates and gas diffusion layers.

    摘要翻译: 公开了一种制备金属双极板的表面改性涂层的方法,其包括以下步骤:提供金属基板; 通过基板处理对金属基板进行预处理,在金属基板上沉积Ni基合金层或其组合以在金属基板的表面上形成活化层; 将金属基材包装在包含渗透的母金属,活化剂和填料粉末的粉末混合物中; 对粉末混合物中的金属基材进行热处理以允许渗透的母金属扩散到活化层中,然后形成表面改性涂层。 渗透的主金属的渗透速率由于活性层的高缺陷浓度而增加。 因此,在低温下制备耐腐蚀表面改性涂层,并且可以降低金属双极板和气体扩散层之间的界面接触电阻。

    Method for preparing surface modification coating of metal bipolar plates
    26.
    发明申请
    Method for preparing surface modification coating of metal bipolar plates 有权
    金属双极板表面改性涂层的制备方法

    公开(公告)号:US20100075063A1

    公开(公告)日:2010-03-25

    申请号:US12585367

    申请日:2009-09-14

    IPC分类号: B05D5/12

    摘要: A method for preparing a surface modification coating of metal bipolar plates is disclosed, which comprises the following steps: providing a substrate; pre-treating the substrate by processing the substrate, depositing a Ni-layer on the substrate, or a combination thereof, to form an activated layer on the surface of the substrate; packing the substrate in a powder mixture containing a permeated master metal, an activator, and filler powder; and heat-treating the packing to allow the permeated master metal to diffuse into the activated layer and then to form a surface modification coating. The permeation rate of the permeated master metal can be increased due to the activated layer having a high defect concentration. Hence, it is possible to prepare a surface modification coating at a low temperature. The surface modification coating of the present invention can also decrease the interface contact resistance between the bipolar plates and gas diffusion layers.

    摘要翻译: 公开了一种制备金属双极板的表面改性涂层的方法,其包括以下步骤:提供基材; 通过处理衬底,在衬底上沉积Ni层或其组合来预处理衬底,以在衬底的表面上形成活化层; 将基材包装在含有渗透的母金属,活化剂和填料粉末的粉末混合物中; 并且对该填料进行热处理以允许渗透的母金属扩散到活化层中,然后形成表面改性涂层。 由于具有高缺陷浓度的活化层,可以增加渗透的母金属的渗透速率。 因此,可以在低温下制备表面改性涂层。 本发明的表面改性涂层也可以降低双极板和气体扩散层之间的界面接触电阻。

    Method for reducing stress in nickel-based alloy plating
    27.
    发明授权
    Method for reducing stress in nickel-based alloy plating 失效
    减少镍基合金电镀应力的方法

    公开(公告)号:US06699379B1

    公开(公告)日:2004-03-02

    申请号:US10302844

    申请日:2002-11-25

    IPC分类号: C25D1500

    摘要: An improved plating method in combination with a low-temperature thermal treatment is disclosed. The method for reducing the stress in the nickel-based alloy plating comprises the steps of: (a) adding ceramic particles into a plating bath containing soluble nickel salts; and (b) placing a substrate in the plating bath and thereafter carrying out a pulse-current electroplating in the plating bath. The method of this invention can prevent substrate softening or deformation problems. The use of a post low-temperature thermal treatment can slightly increase the hardness of the coating products. The use of the low-temperature thermal treatment can reduce the stress of the coatings since the hydrogen embrittlement resulting from exist of hydrogen in the coatings is eliminated.

    摘要翻译: 公开了一种结合低温热处理的改进的电镀方法。 减少镍基合金镀层中的应力的方法包括以下步骤:(a)将陶瓷颗粒加入含有可溶性镍盐的镀浴中; 和(b)将基板放置在电镀液中,然后在电镀液中进行脉冲电流电镀。 本发明的方法可以防止基板软化或变形问题。 使用后期低温热处理可以稍微提高涂层产品的硬度。 使用低温热处理可以降低涂层的应力,因为消除了由涂层中的氢存在引起的氢脆化。

    Method for preparing surface modification coating of metal bipolar plates
    29.
    发明授权
    Method for preparing surface modification coating of metal bipolar plates 有权
    金属双极板表面改性涂层的制备方法

    公开(公告)号:US08420184B2

    公开(公告)日:2013-04-16

    申请号:US12585367

    申请日:2009-09-14

    IPC分类号: B05D5/12

    摘要: A method for preparing a surface modification coating of metal bipolar plates is disclosed, which comprises the following steps: providing a substrate; pre-treating the substrate by processing the substrate, depositing a Ni-layer on the substrate, or a combination thereof, to form an activated layer on the surface of the substrate; packing the substrate in a powder mixture containing a permeated master metal, an activator, and filler powder; and heat-treating the packing to allow the permeated master metal to diffuse into the activated layer and then to form a surface modification coating. The permeation rate of the permeated master metal can be increased due to the activated layer having a high defect concentration. Hence, it is possible to prepare a surface modification coating at a low temperature. The surface modification coating of the present invention can also decrease the interface contact resistance between the bipolar plates and gas diffusion layers.

    摘要翻译: 公开了一种制备金属双极板的表面改性涂层的方法,其包括以下步骤:提供基材; 通过处理衬底,在衬底上沉积Ni层或其组合来预处理衬底,以在衬底的表面上形成活化层; 将基材包装在含有渗透的母金属,活化剂和填料粉末的粉末混合物中; 并且对该填料进行热处理以允许渗透的母金属扩散到活化层中,然后形成表面改性涂层。 由于具有高缺陷浓度的活化层,可以增加渗透的母金属的渗透速率。 因此,可以在低温下制备表面改性涂层。 本发明的表面改性涂层也可以降低双极板和气体扩散层之间的界面接触电阻。