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公开(公告)号：US5015798A
公开(公告)日：1991-05-14
申请号：US454532
申请日：1989-12-21
申请人： Scott Han , Robert E. Palermo , Judy A. Pearson , Dennis E. Walsh
发明人： Scott Han , Robert E. Palermo , Judy A. Pearson , Dennis E. Walsh
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2529/40 , Y10S585/943
摘要： There is provided a process for the direct partial oxidation of methane with oxygen, whereby organic compounds comprising higher hydrocarbons including C.sub.5 + liquid hydrocarbons are produced. The catalyst used in this reaction may be a ZSM-5 catalyst. The process involves the use of an initial cofeed, such as propane, in admixture with the methane and oxygen to induce the formation of liquid hydrocarbons. As the reaction progresses, the flow of cofeed is shut off, and liquid hydrocarbons continue to be produced.
摘要翻译： 提供了用氧气直接部分氧化甲烷的方法，由此产生包含C5 +液体烃的高级烃的有机化合物。 在该反应中使用的催化剂可以是ZSM-5催化剂。 该方法涉及使用初始共进料（例如丙烷）与甲烷和氧气混合以诱导液体烃的形成。 随着反应的进行，共同进料的流动被切断，液态烃继续生产。
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公开(公告)号：US4819831A
公开(公告)日：1989-04-11
申请号：US99860
申请日：1987-09-22
摘要： Uniform droplets of a liquid are produced by positioning the end of a capillary tube in the throat of a venturi. Gas flowing through the venturi detaches droplets from the end of the capillary tube without requiring high volume gas flow or excessively high velocity of the droplets.
摘要翻译： 通过将毛细血管的末端定位在文氏管的喉部中来产生均匀的液体液滴。 流经文丘里管的气体从毛细管末端分离液滴，而不需要高体积气体流动或液滴的过高速度。
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公开(公告)号：US4494961A
公开(公告)日：1985-01-22
申请号：US504115
申请日：1983-06-14
申请人： Chaya Venkat , Dennis E. Walsh
发明人： Chaya Venkat , Dennis E. Walsh
摘要： The invention provides a method for increasing the cetane number of a low hydrogen content, highly aromatic distillate fuel by subjecting it to catalytic partial oxidation. Catalysts employed include transition metal oxides alone or in conjuction with alkali metal or alkaline earth metal compounds. Partial oxidation in accordance with the method of this invention not only results in cetane number improvement, but also allows a higher concentration of aromatic substituents in the fuel blend.
摘要翻译： 本发明提供一种通过使其进行催化部分氧化来提高低含量的高芳族馏分燃料的十六烷值的方法。 所用的催化剂包括单独的或与碱金属或碱土金属化合物结合的过渡金属氧化物。 根据本发明的方法的部分氧化不仅导致十六烷值改进，而且还允许在燃料共混物中更高浓度的芳族取代基。
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公开(公告)号：US4428826A
公开(公告)日：1984-01-31
申请号：US409395
申请日：1982-08-19
申请人： Dennis E. Walsh
发明人： Dennis E. Walsh
CPC分类号： C10G11/05
摘要： Raw shale oil is selectively dewaxed to lower the pour point by contacting a shale oil charge with a low acid crystalline zeolite. The low acid catalysts can be formed by extensive ion exchange of ZSM-5 type catalysts. The shale oil is dewaxed in the absence of hydrogen at high temperature and low pressure.
摘要翻译： 通过使页岩油与低酸性结晶沸石接触，选择性地将原始页岩油脱蜡以降低倾点。 低酸催化剂可以通过ZSM-5型催化剂的大量离子交换形成。 页岩油在高温低压不存在氢气的情况下脱蜡。
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公开(公告)号：US4324651A
公开(公告)日：1982-04-13
申请号：US214602
申请日：1980-12-09
申请人： Louis D. Rollmann , Dennis E. Walsh
发明人： Louis D. Rollmann , Dennis E. Walsh
CPC分类号： B01D11/0407 , C10C3/08 , C10G21/003
摘要： An asphalt-containing mineral oil can be deasphalted at temperatures above about 80.degree. C. with methanol serving as the deasphalting solvent. Two liquid phases are produced, an asphalt-rich phase and a methanol-rich phase. By cooling the methanol-rich phase to a temperature below 80.degree. C., two additional liquid phases are produced, an oil-rich phase and a methanol-rich phase.
摘要翻译： 含沥青的矿物油可以在高于约80℃的温度下脱甲烷，甲醇用作脱沥青溶剂。 产生两个液相，富沥青相和富含甲醇的相。 通过将富含甲醇的相冷却到低于80℃的温度，产生另外两个液相，富油相和富含甲醇的相。
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26.发明申请公开(公告)号：US20130174485A1
公开(公告)日：2013-07-11
申请号：US13822776
申请日：2011-10-03
IPC分类号： C01B3/38
CPC分类号： C01B3/386 , B01D53/48 , B01D2253/108 , B01D2253/1124 , B01D2255/20792 , B01D2256/16 , B01D2256/20 , B01D2257/304 , B01D2257/306 , B01D2257/308 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/042 , C01B2203/043 , C01B2203/0485 , C01B2203/066 , C01B2203/1005 , C01B2203/1023 , C01B2203/1029 , C01B2203/1047 , C01B2203/1064 , C01B2203/1082 , C01B2203/1235 , C01B2203/1247 , C01B2203/142
摘要： A reforming process and apparatus exhibiting improved catalyst longevity towards reforming a high sulfur-containing liquid fuel. The process involves contacting in a first reforming zone a first oxidant and a liquid fuel containing high molecular weight organosulfur compounds with a partial oxidation catalyst under CPDX reaction conditions to form a first reformate stream containing a mixture of unconverted and partially-converted hydrocarbons and one or more low molecular weight sulfur compounds; and then contacting in a second reforming zone the first reformate stream with steam and optionally a second oxidant in the presence of an autothermal reforming catalyst under ATR reaction conditions to form a second reformate stream containing carbon monoxide and hydrogen and one or more low molecular weight sulfur compounds. The low molecular weight sulfur compounds can be readily removed from the first and/or second reformate streams by gas phase adsorption methods.
摘要翻译： 一种重整方法和装置，其显示出改善催化剂寿命以重新制备高含硫液体燃料。 该方法包括使第一氧化剂和含有高分子量有机硫化合物的液体燃料与CPDX反应条件下的部分氧化催化剂接触以形成含有未转化和部分转化的烃的混合物的第一重整产物流，以及一 更低分子量的硫化合物; 然后在ATR反应条件下，在自热重整催化剂存在下，在第二重整区使第一重整产物流与蒸汽和任选的第二氧化剂接触，以形成含有一氧化碳和氢气以及一种或多种低分子量硫的第二重整产物流 化合物。 低分子量硫化合物可以通过气相吸附方法从第一和/或第二重整产物流中容易地除去。
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27.发明授权公开(公告)号：US08444951B2
公开(公告)日：2013-05-21
申请号：US12924876
申请日：2010-10-06
IPC分类号： C01B3/26
CPC分类号： B01F3/04049 , B01D2253/112 , B01D2257/304 , B01F5/045 , B01J8/0214 , B01J8/0221 , B01J8/0278 , B01J8/0285 , B01J8/043 , B01J2208/00203 , B01J2208/0053 , B01J2208/00646 , B01J2208/00716 , C01B3/382 , C01B2203/0244 , C01B2203/0455 , C01B2203/0485 , C01B2203/0894 , C01B2203/1276 , F01N2240/30 , F02M25/12 , F02M27/02 , F02M31/125 , Y02T10/121 , Y02T10/126
摘要： The present invention provides a process and apparatus for the gasification of a liquid fuel and includes providing a supply of a liquid fuel, a supply of oxidant, and a supply of liquid water; atomizing the liquid fuel and mixing it with the oxidant and steam; catalytically reacting the fuel-oxidant-steam mixture in a catalyst bed; initiating the catalytic reaction with an ignition source; positioning a heat exchanger in proximity with the catalyst bed so as to convert the liquid water to steam; and feeding the steam into the catalytic reaction, thereby eliminating the need for a liquid fuel vaporizer. A preferred catalyst bed includes an ultra-short-channel-length metal substrate.
摘要翻译： 本发明提供一种用于液化燃料气化的方法和装置，包括提供液体燃料，氧化剂供应和液态水的供应; 雾化液体燃料并将其与氧化剂和蒸汽混合; 在催化剂床中催化反应燃料 - 氧化剂 - 蒸汽混合物; 引发与点火源的催化反应; 将热交换器定位在催化剂床附近，以便将液态水转化成蒸汽; 并将蒸汽进料到催化反应中，从而不再需要液体燃料蒸发器。 优选的催化剂床包括超短通道长度的金属基材。
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公开(公告)号：US08337757B2
公开(公告)日：2012-12-25
申请号：US12322970
申请日：2009-02-09
申请人： Subir Roychoudhury , Joel M. Desjardins , David Spence , Richard Mastanduno , Dennis E. Walsh , William C. Pfefferle
发明人： Subir Roychoudhury , Joel M. Desjardins , David Spence , Richard Mastanduno , Dennis E. Walsh , William C. Pfefferle
IPC分类号： G05B13/00
CPC分类号： C01B3/26 , C10J3/723 , C10J2200/06 , G05D23/1931 , Y10T436/207497 , Y10T436/218
摘要： A method is provided for controlling the operating temperature of a catalytic reactor using a closed-loop system that provides for varying the reactor input and other operating parameters in order to maintain the operating temperature of the reactor at or near the initial setpoint temperature for operation of the reactor. In one example, maximum and minimum operating temperatures with a catalytic partial oxidation reactor are controlled, as well as maintaining control over the corresponding minimum required ratio of oxygen atoms to carbon atoms, such that the operating temperature within the reactor is maintained below the material limits but above threshold temperatures for coking.
摘要翻译： 提供了一种用于使用闭环系统来控制催化反应器的操作温度的方法，所述闭环系统提供改变反应器输入和其它操作参数，以便将反应器的操作温度保持在或接近初始设定点温度，以操作 反应堆。 在一个实例中，控制具有催化部分氧化反应器的最大和最小操作温度，以及保持对氧原子与碳原子的相应最小所需比例的控制，使得反应器内的操作温度保持在材料极限以下 但高于焦化阈值温度。
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29.发明授权Process for oxidative conversion of methane to higher hydrocarbons using metal sulfide oxidizing agent 失效使用金属硫化物氧化剂将甲烷氧化转化成高级烃的方法
公开(公告)号：US5191138A
公开(公告)日：1993-03-02
申请号：US794560
申请日：1991-11-19
IPC分类号： C07C2/82
CPC分类号： C07C2/82 , Y10S585/943
摘要： There is provided a process for converting methane to hydrocarbons having at least two carbon atoms (i.e. higher hydrocarbons). The process involves oxidizing methane with a metal sulfide oxidizing agent. After this conversion of methane, the reduced metal sulfide may be regenerated by oxidation of the reduced metal sulfide.
摘要翻译： 提供了将甲烷转化为具有至少两个碳原子的烃（即高级烃）的方法。 该方法涉及用金属硫化物氧化剂氧化甲烷。 在甲烷转化后，还原的金属硫化物可以通过还原的金属硫化物的氧化再生。
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公开(公告)号：US5105044A
公开(公告)日：1992-04-14
申请号：US597220
申请日：1990-10-15
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2523/06 , C07C2523/34 , Y10S585/943
摘要： There is provided a catalyst and a process for the direct partial oxidation of methane with oxygen, whereby hydrocarbons having at least two carbon atoms are produced. The catalyst used in this reaction is a spinel oxide, such as MgMn.sub.2 O.sub.4 or CaMn.sub.2 O.sub.4, modified with an alkali metal, such as Li or Na.
摘要翻译： 提供了用氧气直接部分氧化甲烷的催化剂和方法，由此产生具有至少两个碳原子的烃。 在该反应中使用的催化剂是用碱金属如Li或Na改性的尖晶石氧化物，例如MgMn 2 O 4或CaMn 2 O 4。
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