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公开(公告)号：US06203695B1
公开(公告)日：2001-03-20
申请号：US09528197
申请日：2000-03-17
IPC分类号： C10G4500
CPC分类号： B01J37/0018 , B01J21/04 , B01J23/85 , B01J35/0026 , B01J35/023 , B01J35/1019 , B01J35/1061 , B01J35/108 , C10G45/04 , C10G45/08 , C10G49/02 , C10G49/04
摘要： A process for hydrotreating a hydrocarbon feed, comprising subjecting said feed to hydrotreating conditions in the presence of a catalyst comprising an essentially alumina-based extruded support, essentially constituted by a plurality of juxtaposed agglomerates, optionally at least one catalytic metal or a compound of a catalytic metal from group VIB (group 6 of the new periodic table notation) and/or optionally, at least one catalytic metal or a compound of a catalytic metal from group VIII (group 8, 9 and 10 of the new periodic table notation), in which the sum S of the group VIB and VIII metals, expressed as the oxides, is 0% to 50% by weight, and wherein each of these agglomerates is partly in the form of packs of flakes and partly in the form of needles, said needles being uniformly dispersed both about the packs of flakes and between the flakes, in which the alumina agglomerates are obtained by forming a starting alumina originating from rapid dehydration of hydrargillite and in which the amount of alumina from boehmite decomposition is 5% to 70% by weight.
摘要翻译： 一种用于加氢烃化进料的方法，包括在催化剂存在下使所述进料加氢处理，所述催化剂包含基本上由氧化铝为基础的挤出载体，所述催化剂基本上由多个并置的附聚物，任选的至少一种催化金属或 来自VIB族的催化金属（新周期表符号的第6族）和/或任选的至少一种催化金属或来自第VIII族的催化金属的化合物（新的周期表符号的第8,9和10族） 其中以氧化物表示的VIB族和VIII族金属的总和S为0重量％至50重量％，并且其中这些附聚物中的每一个部分为薄片包装形式，部分为针状， 所述针均匀地分散在薄片包装片和薄片之间，其中通过形成起始氧化铝，其中氧化铝附聚物通过形成来自hydrargite的快速脱水的起始氧化铝和 其中勃姆石分解的氧化铝的量为5重量％至70重量％。
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公开(公告)号：US5733514A
公开(公告)日：1998-03-31
申请号：US782496
申请日：1997-01-10
申请人： Pierre Boucot , Paul Gateau , Michel Maute , Philippe Courty , Jerome Weill
发明人： Pierre Boucot , Paul Gateau , Michel Maute , Philippe Courty , Jerome Weill
CPC分类号： B01J23/002 , B01J23/005 , B01J23/78 , B01J8/02 , B01J8/0278 , B01J8/0403 , C01B3/36 , C01B3/382 , B01J2208/00495 , B01J2208/0053 , B01J2219/182 , Y02P20/52
摘要： The present invention relates to a process and a device for manufacturing synthesis gas. The reactor according to the invention comprises within a single housing: A non catalytic combustion chamber (1) comprising at least one device (2) for injecting a fuel and at least one device (3) for injecting an oxidizer so as to achieve a partial combustion in said chamber, and at least one catalytic bed (4) which the gases coming from combustion chamber (1) run into, and also comprising at least one device (6) for injecting an additional oxidizer. The reactor and the process according to the invention may be applied to any chemical manufacturing utilizing synthesis gas, such as the manufacturing of ammonia, urea, methanol, higher hydrocarbons, etc.
摘要翻译： 本发明涉及一种制造合成气的方法和装置。 根据本发明的反应器包括在单个壳体内：非催化燃烧室（1），其包括用于喷射燃料的至少一个装置（2）和用于注入氧化剂的至少一个装置（3），以实现部分 所述室中的燃烧和来自燃烧室（1）的气体的至少一个催化床（4）进入，并且还包括用于注入另外的氧化剂的至少一个装置（6）。 根据本发明的反应器和方法可以应用于利用合成气的任何化学制造，例如氨，尿素，甲醇，高级烃等的制造。
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23.发明授权Process for sweetening petroleum cuts without regular addition of alkaline solution using a basic solid catalyst 失效使用碱性固体催化剂不经常地加入碱性溶液来甜化石油馏分的方法
公开(公告)号：US5633216A
公开(公告)日：1997-05-27
申请号：US474767
申请日：1995-06-07
IPC分类号： B01J21/16 , B01J27/26 , B01J37/00 , C10G27/10 , B01J29/072
CPC分类号： B01J21/16 , B01J27/26 , C10G27/10 , B01J37/0009
摘要： A process for sweetening a petroleum cut containing mercaptans, wherein said petroleum cut is subjected to oxidation conditions by its being passed in the presence of air in contact with a porous catalyst said process being characterized in that said catalyst comprises 10 to 98% by weight of at least one mineral solid phase constituted of analkaline aluminosilicate with a Si/Al atomic ratio less than or equal to 5, 1 to 60% by weight of active carbon, 0.02 to 2% by weight of at least one metal chelate and 0 to 20% by weight of at least one organic or mineral binding agent, has a basicity determined according to the 2896 ASTM standard with 20 milli-equivalents of potash per gram and a total BET surface area of 10 m.sup.2 g.sup.-1, and contains inside its pore structure a permanent aqueous phase representing 0.1 to 40% by weight of dry catalyst.
摘要翻译： 一种用于甜化含有硫醇的石油馏分的方法，其中所述石油馏分通过在与多孔催化剂接触的空气存在下通过氧化条件，所述方法的特征在于所述催化剂包含10至98重量％ 至少一种由Si / Al原子比小于或等于5,1-60重量％的活性炭，0.02-2重量％的至少一种金属螯合物和0至20重量份的由矾土铝硅酸盐构成的矿物固相 至少一种有机或矿物结合剂的重量百分比具有根据2896 ASTM标准确定的碱度，每克20毫克当量钾和总共BET表面积为10m 2·g -1，并包含在其孔结构内 代表0.1-40重量％干催化剂的永久性水相。
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公开(公告)号：US5632787A
公开(公告)日：1997-05-27
申请号：US382587
申请日：1995-02-02
申请人： Pierre Boucot , Paul Gateau , Michel Maute , Philippe Courty , Jerome Weill
发明人： Pierre Boucot , Paul Gateau , Michel Maute , Philippe Courty , Jerome Weill
CPC分类号： B01J23/002 , B01J23/005 , B01J23/78 , B01J8/02 , B01J8/0278 , B01J8/0403 , C01B3/36 , C01B3/382 , B01J2208/00495 , B01J2208/0053 , B01J2219/182 , Y02P20/52
摘要： A reactor for manufacturing synthesis gas as a single housing, equipped with a non-catalytic combustion chamber having at least one device for injecting a fuel and at least one device for injecting an oxidizer so as to achieve partial combustion in said chamber, and at least one catalytic bed from which the gases coming from the combustion chamber discharge into, said catalytic bed being equipped with at least one device for injecting an additional oxidizer. A process for operating the reactor may be applied to any chemical manufacturing utilizing synthesis gas, such as the manufacturing of ammonia, urea, methanol, higher hydrocarbons, etc.
摘要翻译： 一种用于制造合成气作为单个壳体的反应器，其装备有具有至少一个用于喷射燃料的装置的非催化燃烧室和至少一个用于注入氧化剂的装置，以便在所述室中实现部分燃烧，并且至少 一个催化床，来自燃烧室的气体从该催化床排出，所述催化床配备有至少一个用于注入另外的氧化剂的装置。 用于操作反应器的方法可以应用于使用合成气的任何化学制造，例如氨，尿素，甲醇，高级烃等的制造。
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25.发明授权
公开(公告)号：US5601701A
公开(公告)日：1997-02-11
申请号：US193590
申请日：1994-02-08
IPC分类号： B01J20/02 , B01J23/24 , B01J23/44 , B01J23/74 , B01J27/04 , B01J37/20 , C10G45/04 , C10G45/10 , C10G67/06
摘要： The invention concerns a process for the elimination of mercury from hydrocarbons by passage of the feedstock with hydrogen over a catalyst then bringing the product obtained into contact with a mercury retention bed, the catalyst comprising at least one element selected from the group constituted by iron, nickel, cobalt, molybdenum, tungsten, palladium, wherein at least 5% is in the sulphide state. Any arsenic present in the feedstock is also eliminated.In accordance with the invention, the catalyst is simultaneously presulphurated and reduced.The invention results in a considerable reduction in operation period and high retention efficiency at temperatures between 120.degree. C. and 250.degree. C. and in the presence of 0-1000 mg of sulphur/kg of feed.
摘要翻译： 本发明涉及一种通过使原料通过原料与氢气在催化剂上消除汞的方法，然后将所得产物与汞保留床接触，所述催化剂包含至少一种选自铁， 镍，钴，钼，钨，钯，其中至少5％处于硫化物状态。 原料中存在的任何砷也被消除。 根据本发明，催化剂同时被预硫化并还原。 本发明导致在120℃至250℃的温度和0-1000mg硫/ kg进料存在下的操作周期和高保留效率的显着降低。
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公开(公告)号：US5401392A
公开(公告)日：1995-03-28
申请号：US148543
申请日：1993-11-08
CPC分类号： C10G25/003 , C10G45/04 , C10G67/06 , C10G2300/205
摘要： For removing mercury and any arsenic in hydrocarbon charges containing mercury and sulfur, the charge is contacted with an arsenic collecting material having catalytic properties ("catalyst") in hydrogen, the material containing at least one metal selected from the group consisting of nickel, cobalt, iron, palladium, and platinum; at least one metal selected from the group consisting of chromium, molybdenum, tungsten, and uranium; and an active phase carrier. Downstream of the catalyst or mixed therewith is a mercury collecting material containing a sulfide of at least one metal selected from the group consisting of copper, iron, and silver or sulfur, and an active phase carrier.
摘要翻译： 为了除去含有汞和硫的烃装料中的汞和任何砷，电荷与氢气中具有催化性质（“催化剂”）的砷收集材料接触，该材料含有选自镍，钴中的至少一种金属 ，铁，钯和铂; 选自铬，钼，钨和铀中的至少一种金属; 和活性载体。 催化剂的下游或与其混合的是含有选自铜，铁和银或硫的至少一种金属的硫化物的汞收集材料和活性相载体。
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公开(公告)号：US4277458A
公开(公告)日：1981-07-07
申请号：US57464
申请日：1979-07-13
申请人： Andre Sugier , Philippe Courty , Andre Deschamps , Henri Gruhier
发明人： Andre Sugier , Philippe Courty , Andre Deschamps , Henri Gruhier
CPC分类号： C01B17/508 , B01D53/48 , B01J23/682
摘要： A gas containing carbon oxysulfide or carbon disulfide is passed in admixture with oxygen through a catalyst formed of a carrier, vanadium oxide and silver, the proportion of iron oxide, if any, being lower than 1% by weight. The amount of vanadium oxide may be 0.5 to 10% by weight and that of silver 0.05 to 4% by weight.
摘要翻译： 将含有硫氧化碳或二硫化碳的气体与氧气混合通过由载体，氧化钒和银形成的催化剂，氧化铁（如果有的话）的比例低于1重量％。 氧化钒的量可以为0.5〜10重量％，银的量为0.05〜4重量％。
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公开(公告)号：US4029738A
公开(公告)日：1977-06-14
申请号：US524880
申请日：1974-11-18
申请人： Philippe Courty , Andre Sugier , Bernard Raynal , Georges Berrebi
发明人： Philippe Courty , Andre Sugier , Bernard Raynal , Georges Berrebi
CPC分类号： B01D53/945 , B01J21/005 , B01J23/866 , Y02T10/22
摘要： Catalyst for the decomposition of nitrogen oxides, particularly for use in catalytic exhaust boxes in view of decomposing the nitrogen oxides contained in the exhaust gases from internal combustion engines, comprising, deposited on a carrier, from 3 to 20% of an active phase of the formula Ni.sub.x (Fe.sub.y Cr.sub.z)O.sub.t, in which x has a value from 0.5 to 1.5, y + z a value from 1.5 to 3, the ratio ##EQU1## A VALUE FROM 0.01 TO 0.9 AND T A VALUE LOWER THAN 10.
摘要翻译： 考虑到分解来自内燃机的排气中含有的氮氧化物，包括沉积在载体上的活性相的3至20％，特别是用于催化排气箱中的氮氧化物的分解催化剂， 公式Nix（FeyCrz）Ot，其中x的值为0.5至1.5，y + za值为1.5至3，比率为0.01至0.9，TA值低于10。
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29.发明申请公开(公告)号：US20070089598A1
公开(公告)日：2007-04-26
申请号：US10585398
申请日：2003-04-16
申请人： Philippe Courty
发明人： Philippe Courty
IPC分类号： F41C9/00
CPC分类号： F41A3/62 , F41A3/46 , F41A3/74 , F41A9/68 , F41A17/06 , F41A17/54 , F41A19/33 , F42B5/08 , F42B5/18 , F42B5/184 , F42B5/188
摘要： The invention relates to a personal weapon, intended for semi-automatic and automatic firing of caseless ammunitions, provided with an electronic fire controller with biometric identification of the person firing. The weapon has a sealing device for the chamber based on using segments or corollas with variation of bore size mechanically or with gas pressure. A delay in opening the barrel/breech unit may be introduced using spigots driven by propellant gases. A device for sequencing compartments in tandem of the magazine uses the volume reduction of ammunition to double the power of the firearm. A removable locker permits the integral locking of breech unit, trigger, magazine and dismantling bolt for an absolute weapon safety. A telescopic extension device for the barrel increases the power of the ammunition and a gas bleed in the chamber permits the stabilisation of the firing.
摘要翻译： 本发明涉及一种用于半自动和自动燃烧无弹药的个人武器，其具有电子消防控制器，其具有人员射击的生物识别。 该武器具有用于腔室的密封装置，其基于使用具有机械或气体压力的孔尺寸变化的段或花冠。 可以使用由推进剂气体驱动的塞子引入打开桶/后膛单元的延迟。 “杂志”序列中的隔间装置用于减少弹药的数量使枪支的力量翻倍。 一个可拆卸的储物柜允许后膛单元，触发器，杂志和拆卸螺栓的一体式锁定，以获得绝对的武器安全。 用于枪管的伸缩式延伸装置增加了弹药的功率，并且腔室中的气体放出允许稳定化燃烧。
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30.发明授权Process for synthetizing hydrocarbons in the presence of a catalyst comprising a group VIII metal supported on silica-alumina 有权在包含负载在二氧化硅 - 氧化铝上的第Ⅷ族金属的催化剂存在下合成烃的方法公开(公告)号：US06465530B2
公开(公告)日：2002-10-15
申请号：US09778842
申请日：2001-02-08
IPC分类号： C07C2700
摘要： A process is described for synthetizing hydrocarbons from a mixture comprising carbon monoxide and hydrogen in the presence of a catalyst comprising at least one group VIII metal supported on a silica-alumina prepared by co-precipitating and calcining at a temperature in the range from about 500° C. to about 1200° C. for at least 6 hours such that said silica-alumina has a specific surface area of less than 260 m2/g. Said catalyst is used in a fixed bed or in suspension in a liquid phase of a three-phase reactor.
摘要翻译： 描述了一种方法，用于在包含一氧化碳和氢气的混合物的催化剂存在下合成烃，所述催化剂包含负载在二氧化硅 - 氧化铝上的至少一种第Ⅷ族金属，其通过共沉淀和在约500℃的温度下煅烧 约1200℃至少6小时，使得所述二氧化硅 - 氧化铝具有小于260m 2 / g的比表面积。 所述催化剂用于固定床或悬浮在三相反应器的液相中。
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