COMPOSITIONS AND METHODS FOR TREATING SUBTERRANEAN FORMATIONS
    22.
    发明申请
    COMPOSITIONS AND METHODS FOR TREATING SUBTERRANEAN FORMATIONS 审中-公开
    组合物和处理亚硝酸盐形成的方法

    公开(公告)号:US20160032176A1

    公开(公告)日:2016-02-04

    申请号:US14449961

    申请日:2014-08-01

    CPC classification number: C09K8/725 C09K8/74

    Abstract: Methods for treating subterranean wells in which the producing formation is a carbonate comprise preparing a treatment fluid comprising either: (a) an aqueous solution of a multivalent-cation reacting polymer; (b) a solution comprising a fatty acid and an ethanolamine; (c) an aqueous acidic solution of one or more compounds whose calcium salts are insoluble; or (d) an aqueous solution comprising urea or alkane derivatives thereof or both and polyvinylpyrrolidone (PVP). The treatment fluid is placed in the well such that the solution contacts the carbonate formation at a pressure lower than the fracturing pressure. The treatment fluid is allowed to react with the carbonate formation, thereby depositing a film onto the formation surface or part of the formation surface. Then an acid solution is placed in the well such that the acid contacts the carbonate formation at a pressure lower than the fracturing pressure.

    Abstract translation: 用于处理生产地层为碳酸盐的地下井的方法包括制备处理流体,其包括:(a)多价阳离子反应聚合物的水溶液; (b)包含脂肪酸和乙醇胺的溶液; (c)钙盐不溶的一种或多种化合物的酸性水溶液; 或(d)包含尿素或其烷烃衍生物或二者的水溶液和聚乙烯吡咯烷酮(PVP)。 将处理流体放置在井中,使得溶液在低于压裂压力的压力下接触碳酸盐岩层。 使处理流体与碳酸盐岩形成反应,从而在成形表面或地层表面的一部分上沉积膜。 然后将酸溶液放置在井中,使得酸在低于压裂压力的压力下接触碳酸盐岩层。

    AQUEOUS SOLUTION AND METHODS FOR MANUFACTURE AND USE
    24.
    发明申请
    AQUEOUS SOLUTION AND METHODS FOR MANUFACTURE AND USE 审中-公开
    水溶液及其制造方法

    公开(公告)号:US20150240147A1

    公开(公告)日:2015-08-27

    申请号:US14189714

    申请日:2014-02-25

    CPC classification number: C09K8/68 C09K8/74

    Abstract: Oilfield treatment compositions contain water, hydrochloric acid and urea. The urea and water may be present at a urea/water weight ratio between 0.8 and 12.0, and the hydrochloric acid and urea may be present at a urea/hydrochloric acid molar ratio between 0.1 and 0.5. The compositions are present as one liquid phase. The volumes of the compositions are substantially higher than those of the water volumes; consequently, the amount of water necessary to perform various well-service operations is lower.

    Abstract translation: 油田处理组合物含有水,盐酸和尿素。 尿素和水可以以0.8和12.0之间的尿素/水重量比存在,并且盐酸和尿素可以以0.1至0.5的尿素/盐酸摩尔比存在。 组合物作为一个液相存在。 组合物的体积显着高于水体积; 因此,执行各种良好服务操作所需的水量较低。

    VISCOSIFIED ACID FLUID AND METHOD FOR USE THEREOF
    25.
    发明申请
    VISCOSIFIED ACID FLUID AND METHOD FOR USE THEREOF 审中-公开
    粘稠酸流体及其使用方法

    公开(公告)号:US20150034315A1

    公开(公告)日:2015-02-05

    申请号:US13955521

    申请日:2013-07-31

    CPC classification number: C09K8/68 C09K8/725 C09K8/74 C09K2208/30 E21B43/267

    Abstract: A method includes providing an oilfield treatment fluid including an aqueous HCl solution having greater than 15% HCl by weight, and a fixing agent (FA) in a molar ratio of FA:HCl of between 0.5 and 2.5 inclusive. The FA is urea and/or a urea derivative. The oilfield treatment fluid further includes a viscosifying agent that is not a plant-based polysaccharide gum. The method further includes providing the oilfield treatment fluid to a high pressure pump, and operating the high pressure pump to treat a formation fluidly coupled to a wellbore.

    Abstract translation: 一种方法包括提供一种油田处理流体,其包含重量大于15%的HCl的HCl水溶液,和FA:HCl的摩尔比在0.5和2.5之间的固定剂(FA)。 FA是尿素和/或尿素衍生物。 油田处理液还包括不是植物性多糖胶的增粘剂。 该方法还包括将油田处理流体提供给高压泵,并且操作高压泵以处理流体连接到井眼的地层。

    Electrochemical hydrogen sensor
    26.
    发明授权

    公开(公告)号:US11333625B2

    公开(公告)日:2022-05-17

    申请号:US16871735

    申请日:2020-05-11

    Abstract: A process for determining a content of hydrogen in a fluid medium includes contacting the fluid medium with a sensor. The sensor has a housing enclosing a chamber containing an ionic liquid electrolyte, a window which is permeable to hydrogen and positioned in an opening in the housing, and electrodes in contact with the ionic liquid electrolyte in the chamber. Hydrogen is allowed to pass through the window from the fluid medium into the electrolyte and the sensor is heated. Temperature and pressure of the fluid medium is determined and electrical potential is applied to the electrodes. The method also includes measuring current flow. The sensor can be used to observe hydrogen concentration by voltammetry. The method and sensor may be used for measuring downhole hydrogen content, monitoring fiber-optic cables for damage by hydrogen, corrosion monitoring, and in small-scale process plants where hydrogen is part of a gas stream.

    ELECTROCHEMICAL HYDROGEN SENSOR
    27.
    发明申请

    公开(公告)号:US20200271617A1

    公开(公告)日:2020-08-27

    申请号:US16871735

    申请日:2020-05-11

    Abstract: A process for determining a content of hydrogen in a fluid medium includes contacting the fluid medium with a sensor. The sensor has a housing enclosing a chamber containing an ionic liquid electrolyte, a window which is permeable to hydrogen and positioned in an opening in the housing, and electrodes in contact with the ionic liquid electrolyte in the chamber. Hydrogen is allowed to pass through the window from the fluid medium into the electrolyte and the sensor is heated. Temperature and pressure of the fluid medium is determined and electrical potential is applied to the electrodes. The method also includes measuring current flow. The sensor can be used to observe hydrogen concentration by voltammetry. The method and sensor may be used for measuring downhole hydrogen content, monitoring fiber-optic cables for damage by hydrogen, corrosion monitoring, and in small-scale process plants where hydrogen is part of a gas stream.

    Erosion and wear resistant sonoelectrochemical probe

    公开(公告)号:US10386320B2

    公开(公告)日:2019-08-20

    申请号:US14279263

    申请日:2014-05-15

    Abstract: The present invention, in one set of embodiments, provides methods and systems for integrating conducting diamond electrodes into a high power acoustic resonator. More specifically, but not by way of limitation, in certain embodiments of the present invention, diamond electrodes may be integrated into a high power acoustic resonator to provide a robust sensing device that may provide for acoustic cleaning of the electrodes and increasing the rate of mass transport to the diamond electrodes. The diamond electrodes may be used as working, reference or counter electrodes or a combination of two or more of such electrodes. In certain aspects, the high power acoustic resonator may include an acoustic horn for focusing acoustic energy and the diamond electrodes may be coupled with the acoustic horn.

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