公开(公告)号：US20130143999A1

公开(公告)日：2013-06-06

申请号：US13814696

申请日：2011-08-09

申请人： Akiko Tanaka ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Akiko Tanaka ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： C09J133/10

CPC分类号： C09J133/10 ,  C08F220/18 ,  C08F2220/1825 ,  C08K7/00 ,  C08K9/06 ,  C08K2003/2237 ,  C08K2201/011 ,  C08L33/14 ,  C09J7/381 ,  C09J125/06 ,  C09J133/066 ,  C09J151/003 ,  C09J2203/318 ,  C09J2205/102 ,  C09J2425/00 ,  C09J2433/00 ,  C09J2451/00 ,  Y10T428/14 ,  Y10T428/28 ,  C08F220/20

摘要： Provided are: an adhesive composition that is capable of providing an adhesive layer in which titanium-based nanoparticles are stably dispersed, said adhesive layer having more enhanced mechanical characteristics, excellent refractive index and excellent adhesive force; and an adhesive sheet or the like which uses the adhesive composition. An adhesive composition is prepared so as to contain: a (meth)acryl-based polymer that contains, as a monomer component, 50% by weight or more of a (meth)acrylate represented by the formula CH2═C(R1)COOR2 (wherein R1 represents hydrogen or a methyl group, and R2 represents a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms), has a weight average molecular weight of from 500,000 to 3,000,000 as determined by gel permeation chromatography, and does not substantially contain an acid component; an aromatic polymer that has a weight average molecular weight of from 200 to 900 as determined by gel permeation chromatography in an amount of 120-400 parts by weight per 100 parts by weight of the (meth)acrylic polymer; and titanium-based nanoparticles that has an average particle size of 5 to 100 nm in an amount of 150 to 600 parts by weight per 100 parts by weight of the (meth)acrylic polymer.

摘要翻译： 提供：能够提供其中钛基纳米粒子稳定分散的粘合剂层的粘合剂组合物，所述粘合剂层具有更强的机械特性，优异的折射率和优异的粘合力; 以及使用该粘合剂组合物的粘合片等。 制备粘合剂组合物以包含：（甲基）丙烯酸基聚合物，其包含作为单体成分的50重量％以上由式CH 2 = C（R 1）COOR 2表示的（甲基）丙烯酸酯 其中R1表示氢或甲基，R2表示取代或未取代的碳原子数为1〜20的烷基），通过凝胶渗透色谱法测定的重均分子量为500,000〜3,000,000，基本上不含有 酸组分; 通过凝胶渗透色谱测定的重均分子量为200-900的芳族聚合物，每100重量份的（甲基）丙烯酸聚合物的量为120-400重量份; 和相对于（甲基）丙烯酸系聚合物100重量份，平均粒径为5〜100nm的钛系纳米粒子为150〜600重量份。

公开(公告)号：US08389611B2

公开(公告)日：2013-03-05

申请号：US11814775

申请日：2006-01-10

申请人： Fumiaki Shirafuji ,  Masayuki Satake ,  Kohei Yano ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Fumiaki Shirafuji ,  Masayuki Satake ,  Kohei Yano ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： C08K5/101 ,  C08K5/01 ,  C08K5/03

CPC分类号： C09J133/04

摘要： An object of the present invention is to provide a pressure sensitive adhesive composition for an optical member, which is excellent in coating property because of low viscosity, can reduce an amount of an organic solvent used, and can form a pressure sensitive adhesive layer excellent in durability and having high surface uniformity. The present invention relates to a pressure sensitive adhesive composition for an optical member, which comprises a (meth)acrylic polymer, a C6 to C9 hydrocarbon-based solvent (A), and a high-boiling highly solubilizing solvent (B) having a boiling point higher than that of the above hydrocarbon-based solvent and having a higher ability to solubilize the (meth)acrylic polymer than that of the above hydrocarbon-based solvent, wherein a content of the hydrocarbon-based solvent (A) is 20 to 60 wt % based on the total amount of the solvents, and a ratio of the content (wt %) of the hydrocarbon-based solvent (A) to the content (wt %) of the high-boiling highly solubilizing solvent (B) (high-boiling highly solubilizing solvent (B)/hydrocarbon-based solvent (A)) is 0.05 to 4.

摘要翻译： 本发明的目的是提供一种用于光学部件的粘合剂组合物，由于粘度低而具有优异的涂布性能，可以减少所用的有机溶剂的量，并且可以形成优异的压敏粘合剂层 耐久性好，表面均匀性好。 本发明涉及一种用于光学部件的压敏粘合剂组合物，其包含（甲基）丙烯酸类聚合物，C6〜C9烃类溶剂（A）和具有沸点的高沸点高溶解性溶剂（B） 比上述烃基溶剂高，并且与上述烃类溶剂相比，具有较高的（甲基）丙烯酸类聚合物的溶解能力，其中烃系溶剂（A）的含量为20〜60 （A）的含量（重量％）与高沸点高增溶溶剂（B）的含量（重量％）的比例（重量％）（高） 沸腾高溶解性溶剂（B）/烃系溶剂（A））为0.05〜4。

公开(公告)号：US20120064336A1

公开(公告)日：2012-03-15

申请号：US13321364

申请日：2010-05-18

申请人： Akiko Tanaka ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Akiko Tanaka ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： C09J7/02 ,  B05D3/06 ,  B05D3/02 ,  C09J133/08 ,  B05D5/10 ,  B82Y99/00

CPC分类号： C09J4/06 ,  C08K3/08 ,  C08K5/0025 ,  C08K7/18 ,  C09J7/385 ,  C09J135/06 ,  C09J2205/102 ,  C09J2205/31 ,  Y10T428/2809

摘要： An ultraviolet-curable pressure-sensitive adhesive composition, comprising one or more monomer components comprising an acrylic monomer; an aromatic low-molecular-weight polymer having a weight-average molecular weight of 500 to 4000 inclusive, the molecular weight being according to gel permeation chromatography; and a photopolymerization initiator; wherein when the composition is turned into a pressure-sensitive adhesive layer, the haze value of the composition is 10% or less.

摘要翻译： 一种紫外线固化型压敏粘合剂组合物，其包含一种或多种包含丙烯酸类单体的单体组分; 重均分子量为500〜4000的芳族低分子量聚合物，分子量为凝胶渗透色谱法; 和光聚合引发剂; 其中当组合物变成压敏粘合剂层时，组合物的雾度值为10％以下。

公开(公告)号：US07939604B2

公开(公告)日：2011-05-10

申请号：US12108911

申请日：2008-04-24

申请人： Yutaka Moroishi ,  Fumiko Nakano ,  Tetsuo Inoue ,  Yoshihide Kawaguchi ,  Kohei Yano

发明人： Yutaka Moroishi ,  Fumiko Nakano ,  Tetsuo Inoue ,  Yoshihide Kawaguchi ,  Kohei Yano

IPC分类号： C09J133/00 ,  C09J133/02 ,  C09J133/08 ,  C09J133/10 ,  C09J11/08

CPC分类号： C09J133/02 ,  C08K5/5435 ,  C08L33/02 ,  C08L33/14 ,  C08L2205/02 ,  C08L2312/00 ,  C08L2666/04 ,  C09J133/14 ,  G02F2202/28 ,  Y10T428/2891

摘要： Provided are a pressure sensitive adhesive composition for optical members and a pressure sensitive adhesive composition for optical members. The pressure sensitive adhesive composition for optical members according to the present invention comprises 100 parts by weight of an acrylic polymer (A) having a weight-average molecular weight of 500,000 or more, containing at least 50 wt % alkyl (meth)acrylate having an alkyl group with 5 or more carbon atoms and 0.2 to 2 wt % unsaturated carboxylic acid as the monomer unit, 0.1 to 4 parts by weight of an acrylic polymer (B) having a weight-average molecular weight of 2,000 to 50,000, containing at least 70 wt % alkyl (meth)acrylate and 1 to 7 wt % unsaturated carboxylic acid as the monomer unit and having a higher carboxylic acid equivalent than that of the acrylic polymer (A), 0.01 to 1 part by weight of a silane coupling agent, and a crosslinking agent.

摘要翻译： 提供了一种用于光学部件的压敏粘合剂组合物和用于光学部件的压敏粘合剂组合物。 本发明的光学元件用压敏粘合剂组合物包含100重量份的重均分子量为500,000以上的丙烯酸类聚合物（A），其含有至少50重量％的（甲基）丙烯酸烷基酯，其具有 具有5个或更多个碳原子的烷基和0.2至2重量％的不饱和羧酸作为单体单元，0.1至4重量份的重均分子量为2,000至50,000的丙烯酸类聚合物（B），至少包含 70重量％的（甲基）丙烯酸烷基酯和1至7重量％的不饱和羧酸作为单体单元并且具有比丙烯酸类聚合物（A）更高的羧酸当量，0.01至1重量份的硅烷偶联剂， 和交联剂。

公开(公告)号：US20100304134A1

公开(公告)日：2010-12-02

申请号：US12864047

申请日：2009-01-20

申请人： Fumiko Nakano ,  Yutaka Moroishi ,  Aimi Matsuura ,  Toshitsugu Hosokawa ,  Akiko Tanaka

发明人： Fumiko Nakano ,  Yutaka Moroishi ,  Aimi Matsuura ,  Toshitsugu Hosokawa ,  Akiko Tanaka

IPC分类号： B32B17/04 ,  B32B38/10

CPC分类号： C09J5/06 ,  C08F2220/1825 ,  C08K5/14 ,  C08L33/08 ,  C09J7/385 ,  C09J133/08 ,  C09J2201/606 ,  C09J2205/302 ,  G02F1/1335 ,  G02F2202/28 ,  Y10T156/1126 ,  Y10T156/1153 ,  Y10T156/1911 ,  Y10T428/28 ,  C08F220/06 ,  C08F2220/281

摘要： An object of the invention is to provide a pressure-sensitive adhesive optical film-peeling method capable of easily detaching the pressure-sensitive adhesive optical film from a glass substrate with no damage to the glass substrate or no adhesive deposit on the glass substrate, and to provide a pressure-sensitive adhesive optical film suitable for use in such a peeling method. The invention is directed to a method for peeling a pressure-sensitive adhesive optical film from an optical film-carrying glass substrate including a glass substrate and the pressure-sensitive adhesive optical film bonded thereto, which includes: exposing the optical film-carrying glass substrate to an environment at a temperature of 40 to 98° C. and a relative humidity of 60 to 99% for three minutes or more; and then peeling the pressure-sensitive adhesive optical film from the glass substrate under the environment.

摘要翻译： 本发明的目的是提供一种能够容易地从玻璃基板上分离玻璃基板的粘合型光学膜剥离方法，而不会损伤玻璃基板，也可以不在玻璃基板上粘合， 以提供适合用于这种剥离方法的压敏粘合剂光学膜。 本发明涉及一种剥离由粘合有玻璃基板和粘合型光学膜的玻璃基板的带光学薄膜玻璃基板的粘合型光学薄膜的方法，该方法包括：将带光学薄膜的玻璃基板 温度为40〜98℃，相对湿度为60〜99％的环境3分钟以上; 然后在环境下从玻璃基板剥离压敏粘合剂光学膜。

公开(公告)号：US20090233102A1

公开(公告)日：2009-09-17

申请号：US11720688

申请日：2005-11-17

申请人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： B32B27/40 ,  C08K3/18 ,  B05D3/00

CPC分类号： C09J175/04 ,  C08G18/7642 ,  C08G2170/40 ,  C09J133/04 ,  G02B5/30 ,  Y10T428/31551

摘要： The invention relates to a pressure-sensitive adhesive for an optical film, comprising 0.02 to 2 parts by weight of a peroxide (B) and 0.01 to 5 parts by weight of an isocyanate-based compound (C) contained in 100 parts by weight of a (meth)acrylic polymer (A) consisting primarily of an alkyl(meth)acrylate and not containing a functional group reactive with an isocyanate group. By using the invented pressure-sensitive adhesive for an optical film, there can be obtained a pressure sensitive adhesion type optical film that can suppress warping and light leakage caused by a stress accompanying a dimensional change of members such as an optical film, has high durability, is excellent in handling ability in the manufacturing process and is excellent in quality.

摘要翻译： 本发明涉及一种用于光学膜的压敏粘合剂，其包含0.02至2重量份的过氧化物（B）和0.01至5重量份的异氰酸酯基化合物（C），其包含在100重量份的 主要由（甲基）丙烯酸烷基酯组成的不含与异氰酸酯基反应的官能团的（甲基）丙烯酸聚合物（A）。 通过使用本发明的光学膜用粘合剂，可以获得能够抑制伴随光学膜等构件的尺寸变化的应力引起的翘曲和漏光的压敏粘合型光学膜，具有高耐久性 ，在制造工序中的处理能力优异，质量优异。

公开(公告)号：US20060121273A1

公开(公告)日：2006-06-08

申请号：US11290165

申请日：2005-11-30

申请人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

发明人： Yuusuke Toyama ,  Masayuki Satake ,  Akiko Ogasawara ,  Yutaka Moroishi ,  Fumiko Nakano

IPC分类号： B32B27/04 ,  D06N3/00 ,  B32B7/12

CPC分类号： C09J175/04 ,  C08G18/289 ,  C08G18/6229 ,  C08G18/8022 ,  C08G2170/40 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J2433/00 ,  Y10T428/1059 ,  Y10T428/24438 ,  Y10T428/28 ,  Y10T428/2826 ,  Y10T428/2887 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/3192 ,  Y10T442/2738

摘要： It is an object of the invention to provide a pressure sensitive adhesive for an optical film with which a pressure sensitive adhesive type optical film capable of suppressing bowing and light leakage caused by a stress accompanying a dimensional change of members such as an optical film, high in durability, excellent in handling ability in an aspect of a fabrication process thereof and good in quality can be obtained. There is provided a pressure sensitive adhesive for an optical film comprising: 100 parts by weight of a (meth)acrylic-based polymer (A) including an alkyl (meth)acrylate (a1) and a (meth)acrylic-based monomer containing a hydroxyl group (a2), as a copolymerizable component, in content in the range of from 0.01 to 5 parts by weight relative to 100 parts by weight of the alkyl (meth)acrylate (a1); 0.02 to 2 parts by weight of a peroxide (B); and 0.001 to 2 parts by weight of an isocyanate-based compound (C), the contents of the peroxide (B) and the isocyanate-based compound (C) being values relative to 100 parts by weight of the (meth)acrylic-based polymer (A).

摘要翻译： 本发明的目的是提供一种用于光学膜的压敏粘合剂，通过该压敏粘合剂型光学膜能够抑制伴随诸如光学膜的部件的尺寸变化的应力引起的弯曲和漏光 在耐久性方面，可以获得在其制造方法方面的良好的处理能力和良好的质量。 提供一种用于光学膜的压敏粘合剂，其包括：100重量份的包含（甲基）丙烯酸烷基酯（a1）的（甲基）丙烯酸类聚合物（A）和（甲基）丙烯酸类单体，其包含 相对于100重量份的（甲基）丙烯酸烷基酯（a1），作为可共聚成分的羟基（a2）的含量范围为0.01〜5重量份。 0.02〜2重量份过氧化物（B）; 和0.001〜2重量份的异氰酸酯系化合物（C），过氧化物（B）和异氰酸酯系化合物（C）的含量相对于（甲基）丙烯酸系化合物（C）的100重量份 聚合物（A）。

公开(公告)号：US20050049366A9

公开(公告)日：2005-03-03

申请号：US10803976

申请日：2004-03-19

申请人： Tomoko Doi ,  Michiharu Yamamoto ,  Yutaka Moroishi ,  Yoshihide Kawaguchi ,  Fumiko Nakano

发明人： Tomoko Doi ,  Michiharu Yamamoto ,  Yutaka Moroishi ,  Yoshihide Kawaguchi ,  Fumiko Nakano

IPC分类号： C08F293/00 ,  C09J7/02 ,  C09J153/00 ,  C08F120/10

CPC分类号： C08F293/00 ,  C08F2438/01 ,  C09J7/387 ,  C09J153/00

摘要： An ultraviolet crosslinking pressure-sensitive adhesive composition showing good pressure-sensitive adhesive characteristics is obtained by using a block copolymer of styrenic polymer component and acrylic polymer component. The pressure-sensitive adhesive composition is produced by conducting living radical polymerization of styrenic monomer and acrylic monomer in a proper order in the presence of a transition metal and its ligand using a polymerization initiator to obtain a block copolymer (a) wherein at least one styrenic polymer block A and at least one acrylic polymer block B are bound to each other and mixing it with a trichloromethyl group-containing triazine derivative (b) or, alternatively, to obtain a block copolymer (a) which contains carboxy precursor groups in the acrylic polymer block B, and converting the precursor groups to carboxyl groups, before or after mixing with the component (b), by heat-treating in the presence of an acid catalyst.

摘要翻译： 通过使用苯乙烯类聚合物组分和丙烯酸类聚合物组分的嵌段共聚物，获得显示出良好的压敏粘合剂特性的紫外线交联压敏粘合剂组合物。 通过使用聚合引发剂在过渡金属及其配位体的存在下，以适当的顺序进行苯乙烯类单体和丙烯酸类单体的活性自由基聚合，得到嵌段共聚物（a），其中至少一种苯乙烯类 聚合物嵌段A和至少一个丙烯酸类聚合物嵌段B彼此结合并与含三氯甲基的三嗪衍生物（b）混合，或者可以获得在丙烯酸中含有羧基前体基团的嵌段共聚物（a） 聚合物嵌段B，并且在与组分（b）混合之前或之后，通过在酸催化剂的存在下进行热处理将前体基团转化成羧基。

公开(公告)号：US20140370277A1

公开(公告)日：2014-12-18

申请号：US14241563

申请日：2012-08-20

申请人： Masatsugu Higashi ,  Yutaka Moroishi ,  Shigeru Fujita ,  Tetsuo Inoue

发明人： Masatsugu Higashi ,  Yutaka Moroishi ,  Shigeru Fujita ,  Tetsuo Inoue

IPC分类号： C09J151/00 ,  G02B1/10 ,  G02B5/30 ,  G02B1/04

CPC分类号： C09J151/003 ,  C08F265/06 ,  C09J7/385 ,  G02B1/04 ,  G02B1/105 ,  G02B1/14 ,  G02B5/305 ,  Y10T428/2809 ,  Y10T428/2826 ,  Y10T428/2848 ,  Y10T428/2891 ,  C08F220/32 ,  C08F2220/325 ,  C08F220/18 ,  C08F2220/1858

摘要： The purpose of the present invention is to provide: an adhesive composition for optical applications, which is capable of suppressing luminance unevenness without deteriorating the contrast characteristics in optical applications, and which can be used for optical members and prevents the optical members from separation in a reliability test; an adhesive layer; an optical member; an image display device and the like. An adhesive composition for optical applications, which contains a modified (meth)acrylic graft polymer and an isocyanate crosslinking agent, is prepared. The modified (meth)acrylic graft polymer is obtained by graft polymerizing chains, each of which contains a cyclic ether group-containing monomer, to the trunk polymer, and contains, as constituent components, an alkyl(meth)acrylate, a cyclic ether group-containing monomer, and an acyclic ether group-containing monomer. An adhesive layer for optical applications, which is formed from the composition, an optical member, an image display device and the like are also produced.

摘要翻译： 本发明的目的是提供：一种用于光学应用的粘合剂组合物，其能够抑制亮度不均匀性，而不会降低光学应用中的对比度特性，并且可以用于光学部件，并防止光学部件在光学部件中分离 可靠性试验; 粘合层; 光学构件; 图像显示装置等。 制备含有改性（甲基）丙烯酸接枝聚合物和异氰酸酯交联剂的用于光学应用的粘合剂组合物。 改性（甲基）丙烯酸接枝聚合物通过将含有含环状醚基团的单体的链接枝聚合到树脂聚合物上而获得，并且作为构成成分含有（甲基）丙烯酸烷基酯，环状醚基 的单体和含有无环醚基的单体。 还制造了由组合物形成的用于光学应用的粘合剂层，光学构件，图像显示装置等。

公开(公告)号：US5334686A

公开(公告)日：1994-08-02

申请号：US159124

申请日：1993-11-30

申请人： Masahiko Ando ,  Takeshi Yamanaka ,  Yutaka Moroishi ,  Yasuyuki Tokunaga ,  Yoshinao Kitamura

发明人： Masahiko Ando ,  Takeshi Yamanaka ,  Yutaka Moroishi ,  Yasuyuki Tokunaga ,  Yoshinao Kitamura

IPC分类号： C08F220/18 ,  C09J4/02 ,  C09J7/02 ,  C09J133/02 ,  C09J133/04 ,  C09J133/06 ,  C09J133/26 ,  C08F20/54

CPC分类号： C09J7/0217 ,  C08F220/18 ,  C09J133/064 ,  C09J2201/606 ,  Y10T428/31935

摘要： A pressure-sensitive adhesive and adhesive sheets using the pressure-sensitive adhesive are disclosed. The pressure-sensitive adhesive comprising (a) from 50 to 84% by weight of an acrylic monomer, (b) from 15 to 28% by weight of an N,N-di-substituted (meth)acrylamide, (c) from 1 to 10% by weight of a monomer having an acid group, and (d) from 0 to 25% by weight of other monomer copolmerizable with the components (a) to (c).

摘要翻译： 公开了使用压敏粘合剂的压敏粘合剂和粘合片。 压敏粘合剂包含（a）50至84重量％的丙烯酸单体，（b）15至28重量％的N，N-二取代的（甲基）丙烯酰胺，（c）1 至10重量％的具有酸基团的单体，和（d）0至25重量％的可与组分（a）至（c）共混的其它单体。