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    FCC catalyst
    23.
    发明申请
    FCC catalyst 审中-公开
    FCC催化剂

    公开(公告)号：US20090082193A1

    公开(公告)日：2009-03-26

    申请号：US12287234

    申请日：2008-10-07

    申请人： William A. Wachter

    发明人： William A. Wachter

    IPC分类号： B01J29/08 ,  B01J21/12

    CPC分类号： B01J29/084 ,  B01J21/12 ,  B01J21/16 ,  B01J29/7007 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0232 ,  C10G11/02 ,  C10G11/05

    摘要： This invention relates to a mesoporous catalytic cracking catalyst, a process for the production of such catalysts, and a process utilizing such catalysts in cracking operations. The mesoporous fluidized catalytic cracking catalyst is selective for minimizing the production of coke and light gas. The catalyst comprises an amorphous, porous matrix having pores ranging in diameter from about 1 Å to about 10 Å and ranging in diameter from about 40 Å to about 500 Å, but substantially free of pores ranging in diameter from about 10 Å to about 40 Å.

    摘要翻译： 本发明涉及介孔催化裂化催化剂，制备这种催化剂的方法，以及在裂化操作中利用这种催化剂的方法。 中孔流化催化裂化催化剂是选择性地使焦炭和轻质气体的生产最小化。 该催化剂包括无定形多孔基体，其具有直径从大约至大约等于或约为范围内的孔的范围，但基本上不含直径从约至约为40埃的孔。 。

    Fluid cracking process for producing low emissions fuels
    25.
    发明授权
    Fluid cracking process for producing low emissions fuels 失效
    用于生产低排放燃料的流体裂解过程

    公开(公告)号：US5318695A

    公开(公告)日：1994-06-07

    申请号：US982933

    申请日：1992-11-30

    申请人： Paul E. Eberly ,  William E. Winter ,  William L. Schuette ,  William A. Wachter ,  Tan-Jen Chen

    发明人： Paul E. Eberly ,  William E. Winter ,  William L. Schuette ,  William A. Wachter ,  Tan-Jen Chen

    IPC分类号： C10G11/05 ,  C10G11/00 ,  C10G11/02

    CPC分类号： C10G11/05

    摘要： A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen. The catalyst is an amorphous silica-alumina or a zeolitic material having a relatively small unit cell size. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.

    摘要翻译： 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮气和芳烃特别低，氢气相对较高。 该催化剂是具有相对小的晶胞尺寸的无定形二氧化硅 - 氧化铝或沸石材料。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2 +环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。

    Highly attrition resistant mesoporous catalytic cracking catalysts
    26.
    发明授权
    Highly attrition resistant mesoporous catalytic cracking catalysts 失效
    高耐磨中孔催化裂化催化剂

    公开(公告)号：US5221648A

    公开(公告)日：1993-06-22

    申请号：US816021

    申请日：1991-12-30

    申请人： William A. Wachter

    发明人： William A. Wachter

    IPC分类号： B01J29/06 ,  B01J29/08 ,  B01J35/10 ,  C10G11/05

    CPC分类号： C10G11/05 ,  B01J29/06 ,  B01J29/084 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/109 ,  B01J35/1095

    摘要： A catalytic cracking catalyst for converting a hydrocarbon feedstock at elevated temperature in the substantial absence of hydrogen, into lower average molecular weight, lower boiling hydrocarbons useful as transportation fuels. The catalyst is a composite of a crystalline aluminosilicate zeolite in concentration ranging as high as about 80 percent, based on the total weight of the catalyst, within a mesoporous silica-alumina matrix. The matrix, preferably, is constituted of silica sols modified by alumina and clay and it is characterized as of polymodal pore size distribution, as measured by mercury porosimetry, a first mode wherein at least 75 percent, preferably about 80 percent to 90 percent, of the pore volume measured between 45 Angstroms and 2000 Angstroms is in pores greater than 160 Angstroms in diameter, and a second mode wherein up to about 20 percent of the pore diameters are greater than 100 Angstroms but less than 160 Angstroms in diameter. These catalysts are highly active, and selective in the production of olefins without high coke made. The attrition-resistance of these catalysts, as measured by the Davison Index, is quite low, ranging generally from about 1 to about 8, more generally from about 1 to about 5, or less.

    摘要翻译： 用于将基本上不存在氢气的升高温度下的烃原料转化为较低平均分子量的催化裂化催化剂，用作运输燃料的低沸点烃。 该催化剂是在介孔二氧化硅 - 氧化铝基质中，基于催化剂的总重量，高达约80％的结晶硅铝酸盐沸石的复合物。 基质优选地由氧化铝和粘土改性的硅溶胶构成，并且其特征在于通过水银孔率法测定的多晶型孔径分布，第一模式，其中至少75％，优选约80％至90％的 在45埃和2000埃之间测量的孔体积是在直径大于160埃的孔中，而第二种模式，其中至多约20％的孔径大于100埃但小于160埃直径。 这些催化剂是高活性的，并且在制备没有高焦炭的烯烃的生产中是选择性的。 通过戴维森指数测量，这些催化剂的耐磨性相当低，通常为约1至约8，更通常为约1至约5，或更少。

    Fluid cat cracking with high olefins production
    28.
    发明授权
    Fluid cat cracking with high olefins production 有权
    流体催化裂化产生高烯烃

    公开(公告)号：US07261807B2

    公开(公告)日：2007-08-28

    申请号：US10131737

    申请日：2002-04-24

    申请人： B. Erik Henry ,  William A. Wachter ,  George A. Swan, III

    发明人： B. Erik Henry ,  William A. Wachter ,  George A. Swan, III

    IPC分类号： C10G11/00 ,  C10G11/14 ,  C10G11/02 ,  C10G11/04

    CPC分类号： C10G11/18 ,  C10G2400/20

    摘要： The propylene production of a fluid catalytic cracking unit employing a large pore zeolite cracking catalyst, produces more propylene by adding a naphtha cracking riser and a medium pore zeolite catalytic component to the unit, and recycling at least a portion of the naphtha crackate to the naphtha riser. The large pore size zeolite preferably comprises a USY zeolite and the medium pore size is preferably ZSM-5. Propylene production per unit of naphtha feed to the naphtha riser is maximized, by using the 60–300° F. naphtha crackate as the feed.

    摘要翻译： 使用大孔沸石裂化催化剂的流化催化裂化装置的丙烯生产通过向该装置中加入石脑油裂化提升管和中孔沸石催化组分产生更多的丙烯，并将至少一部分石脑油裂解物再循环至石脑油 冒口 大孔径沸石优选包含USY沸石，中等孔径优选为ZSM-5。 通过使用60-300°F的石脑油裂解液作为进料，使石脑油提升管的单位石脑油进料的丙烯产量最大化。

    Process for producing polypropylene from C3 olefins selectively produced by a two stage fluid catalytic cracking process
    29.
    发明授权
    Process for producing polypropylene from C3 olefins selectively produced by a two stage fluid catalytic cracking process 失效
    通过两阶段流化催化裂化方法选择性生产的C3烯烃生产聚丙烯的方法

    公开(公告)号：US06258257B1

    公开(公告)日：2001-07-10

    申请号：US09517551

    申请日：2000-03-02

    申请人： George A. Swan, III ,  Michael W. Bedell ,  Paul K. Ladwig ,  John E. Asplin ,  Gordon F. Stuntz ,  William A. Wachter ,  B. Erik Henry

    发明人： George A. Swan, III ,  Michael W. Bedell ,  Paul K. Ladwig ,  John E. Asplin ,  Gordon F. Stuntz ,  William A. Wachter ,  B. Erik Henry

    IPC分类号： C10G5102

    CPC分类号： C10G57/02 ,  C10G2400/20

    摘要： A process for producing polymers from olefins selectively produced by a two stage process for selectively producing C2 to C4 olefins from a gas oil or resid is disclosed herein. The gas oil or resid is reacted in a first stage comprising a fluid catalytic cracking unit wherein it is converted in the presence of conventional large pore zeolitic catalyst to reaction products, including a naphtha boiling range stream. The naphtha boiling range stream is introduced into a second stage comprising a process unit containing a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feed is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500 to 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone.

    摘要翻译： 本文公开了一种通过二级方法选择性制备聚合物的方法，用于从瓦斯油或渣油中选择性地生产C2至C4烯烃。 瓦斯油或渣油在包括流化催化裂化装置的第一阶段中反应，其中在常规大孔沸石催化剂存在下将其转化为包括石脑油沸程的反应产物。 将石脑油沸程流引入包含含有反应区，汽提区，催化剂再生区和分馏区的处理单元的第二阶段。 石脑油进料在反应区中与含有约10至50wt。 在包括约500至650℃的温度和约10至40psia的烃分压的反应条件下具有平均孔径小于约0.7纳米的结晶沸石的百分比。 蒸气产物被顶部收集，催化剂颗粒在通向催化剂再生区的途中通过汽提区。 挥发物在汽提区中用蒸汽汽提，并将催化剂颗粒送入催化剂再生区，其中焦炭从催化剂燃烧，然后再循环到反应区。

    Methods for making catalysts
    30.
    发明授权
    Methods for making catalysts 失效
    催化剂的制备方法

    公开(公告)号：US6153552A

    公开(公告)日：2000-11-28

    申请号：US960030

    申请日：1997-10-29

    申请人： William A. Wachter ,  Jeffrey T. Elks ,  Stephen Neil Vaughn

    发明人： William A. Wachter ,  Jeffrey T. Elks ,  Stephen Neil Vaughn

    IPC分类号： B01J29/85 ,  B01J37/00 ,  B01J27/14

    CPC分类号： B01J29/85 ,  B01J37/0045 ,  B01J2229/42

    摘要： Catalysts that are useful for hydrocarbon conversions and oxygenate conversions, and a method for making such catalysts. The method for making the catalysts comprises forming a mixture comprising molecular sieves comprising pores having a diameter smaller than about 10 Angstroms, an inorganic sol, and an external phosphorus source, and drying the mixture.

    摘要翻译： 可用于烃转化和含氧化合物转化的催化剂，以及制备这种催化剂的方法。 制备催化剂的方法包括形成包含直径小于约10埃的分子筛的混合物，无机溶胶和外部磷源，并干燥该混合物。