Abstract:
An electrode for use in electrochemical ion exchange which includes a hydrolysable metal phosphate such as zirconium phosphate (Zr(HPO.sub.4).sub.2) which has been hydrolysed at least in part is regenerated. The electrode is made the anode of an electrochemical cell in which the electrolyte is an aqueous solution containing one or more phosphate ions provided, for example, by a dissolved salt (eg Na.sub.3 PO.sub.4, Na.sub.2 HPO.sub.4 or NaH.sub.2 PO.sub.4) or orthophosphoric acid, or both. Preferably, the electrolyte is acidic (eg pH 2). Operation of the cell reverses the hydrolysis reaction and enhances the performance of the electrode.
Abstract translation:用于电化学离子交换的电极,其包括至少部分被水解的可水解金属磷酸盐如磷酸锆(Zr(HPO 4)2)。 电极被制成电化学电池的阳极,其中电解质是含有例如由溶解的盐(例如Na 3 PO 4,Na 2 HPO 4或NaH 2 PO 4)或正磷酸或两者提供的一种或多种磷酸根离子的水溶液。 优选地,电解质是酸性的(例如pH 2)。 电池的操作反转水解反应并提高电极的性能。
Abstract:
A liquid is subjected to ultrasound within a stainless steel pipe (35) of wall thickness 2.5 mm. Three ultrasonic transducers (56) are equally spaced around the pipe, each fixed to one end of a tapered resonant coupler (46) with a nodal flange (48) by which it is supported with its wider end coaxially within a steel collar (38) welded to the outside of the pipe wall. The space around the sides and the end of the coupler is filled by a buffer liquid such as olive oil. When the transducers (56) are energised they resonate, as do the couplers (46), and ultrasound is transmitted through the buffer liquid and the wall into the liquid inside the pipe (35). Within the pipe the intensity can be sufficient to cause cavitation, and so to cause sonochemical effects.
Abstract:
The onset of rolling contact fatigue in an object may be detected by measuring the residual stresses in the surface of the object, and monitoring changes in their magnitude or their direction. The values of residual stresses in the surface are those averaged over a depth that may be in the range say 0.1 mm to 8.0 mm, for example about 2.5 mm. For ferromagnetic objects such as rails, the method may utilize an electromagnetic probe. Prior to rolling contact fatigue the surface stresses are compressive, and the onset of rolling contact fatigue may be characterized by a marked decrease of the stress in the generally transverse direction.
Abstract:
The variation in properties of a ferromagnetic material with depth below the surface is assessed in a nondestructive fashion using a probe that incorporates an electromagnet. An alternating magnetic field is generated in the electromagnet and so in the object, and a magnetic sensor is arranged to sense a magnetic field due to the electromagnet. Signals from the magnetic sensor are analysed into an in-phase component and a quadrature component, and these are mapped directly into material property and lift-off components; this analysis enables accurate measurements of material property (such as stress) to be distinguished from changes in lift-off. The measurements are repeated for at least five different frequencies of the alternating magnetic field; and the measurements at different frequencies are deconvolved assuming a functional form for the variation of material property with depth, the function having no more than five unknown constants. The stress at depths for example in the range 0.5 mm to 5.0 mm can hence be measured nondestructively.
Abstract:
Fluids in a vessel are subjected to a high ultrasonic intensity, by means of several ultrasonic transducers attached to a wall of the vessel, each transducer (14) radiating no more than 3 W/cm2, the transducers being sufficiently close to each other, and the number of transducers being sufficiently high, that the power dissipation within the vessel is at least 25 W/litre. The number of transducers, the power of the transducers, and the volume of the vessel may be such that the power density is between 40 and 80 W/litre. The vessel may be double walled, and the space between the two walls be filled by a low attenuation buffer liquid (36) whose cavitation threshold is above that of the liquid being treated.
Abstract translation:容器中的流体通过附接到容器壁的几个超声波换能器受到高超声波强度,每个换能器(14)辐射不超过3W / cm 2,换能器足够靠近每个 换能器的数量足够高,容器内的功率消耗至少为25W /升。 换能器的数量,换能器的功率和容器的体积可以是功率密度在40和80W /升之间。 容器可以是双壁的,并且两个壁之间的空间由其空化阈值高于被处理液体的低衰减缓冲液(36)填充。
Abstract:
A plasma enhanced gas reactor including a reaction chamber having a pair of field-enhancing electrodes each of which has an axial passage through it by one of which a reactant gas is admitted to the reaction chamber, and by the other of which reaction products are removed from the reaction chamber.
Abstract:
An improved polymer film material for the packaging of perishable foodstuffs, wherein the surface structure of the polymer is altered by means of an ion bombardment process so as to reduce the rates of transport of oxygen and water vapor through the polymer material wherein the polymer film material is produced by subjecting at least one surface of the film to ion bombardment with ions selected from the group consisting of hydrogen, carbon, nitrogen, helium, and argon at energies of 30-80 KeV and ion doses in the range of 10.sup.12 to 10.sup.18 ions/cm.sup.2.
Abstract:
A method of, and apparatus for, preventing the formation of deposits on surfaces downstream of a mixer in which possibly supersaturated mixtures issuing from the mixer are surrounded by a sheath of unsaturated solution. In an arrangement described, the sheath of unsaturated mixture is obtained by bleeding off some of the mixture issuing from the mixer sufficiently downstream of the mixer definitely to be unsaturated and returning this portion of the mixture to surround that issuing from the mixer.
Abstract:
During filtration, periodic application of a potential difference between an electrically conducting filter medium and counter electrode (as anode) generates a gaseous product at the filter and cleans the filter. To minimise corrosion the counter electrode is of low chromium stainless steel, for example 9% chromium.
Abstract:
An apparatus for generating a liquid spray from two jets of fluid which issue from a pair of opposing nozzles and interact, wherein the fluid is supplied to the nozzles under fully turbulent conditions such that random variations in the momentum of the fluid as it leaves the nozzles occur which results in random variations in the orientation of the resultant spray of liquid drops.