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公开(公告)号：US20130199969A1
公开(公告)日：2013-08-08
申请号：US13367935
申请日：2012-02-07
CPC分类号： B01J31/26 , B01J21/04 , B01J23/8885 , B01J27/0515 , B01J31/0234 , B01J31/22 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/0009 , B01J37/0201 , B01J37/0203 , B01J37/18 , B01J37/20 , B01J2231/005 , B01J2531/845 , C10G45/12 , C10G49/04
摘要： A composition and method of making such a composition that has application in the hydroprocessing of hydrocarbon feedstocks. The method comprises selecting an organic additive by the use of a correlation model for predicting catalytic activity as a function of a physical property that is associated with the organic additive and incorporating the organic additive into a support material to provide the additive impregnated composition.
摘要翻译： 制备这种组合物的组合物和方法，其可用于烃原料的加氢处理。 该方法包括通过使用用于预测催化活性的相关模型来选择有机添加剂，作为与有机添加剂相关的物理性能的函数，并将有机添加剂并入载体材料中以提供添加剂浸渍的组合物。
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公开(公告)号：US20130048540A1
公开(公告)日：2013-02-28
申请号：US13593855
申请日：2012-08-24
申请人： Gladys Esperanza Noguera Herrera , Solange Carolina Araujo Ferrer , Angel Benjamin Rivas Herrera , Javier Ramon Hernandez Polanco , Dietrich Alonso Mendoza Chacon , Omayra Zuleika Delgado Gonzalez
发明人： Gladys Esperanza Noguera Herrera , Solange Carolina Araujo Ferrer , Angel Benjamin Rivas Herrera , Javier Ramon Hernandez Polanco , Dietrich Alonso Mendoza Chacon , Omayra Zuleika Delgado Gonzalez
CPC分类号： B01J23/883 , B01J27/0515 , B01J37/20 , C10G45/08 , C10G47/06 , C10G49/04
摘要： A catalyst composition comprising an emulsion of an aqueous phase in an oil phase, wherein the aqueous phase contains a group 6 metal, and wherein between about 55 and 100 wt % of the group 6 metal is sulfurated. A method for making a catalyst emulsion, comprising the steps of providing an aqueous phase comprising an aqueous solution of a group 6 metal, wherein between about 55 and 100 wt % of the group 6 metal is sulfurated; and mixing the aqueous phase into an oil phase to form an emulsion of the aqueous phase in the oil phase. A hydroconversion process, comprising the steps of contacting the catalyst of claim 1 with a feedstock in a hydroconversion zone under hydroconversion conditions.
摘要翻译： 一种催化剂组合物，其包含油相中水相的乳液，其中所述水相含有第6族金属，并且其中所述第6族金属的约55至100重量％被硫化。 一种制备催化剂乳液的方法，包括以下步骤：提供包含第6族金属的水溶液的水相，其中第6族金属的约55至100重量％被硫化; 并将水相混合到油相中以形成油相中水相的乳液。 一种加氢转化方法，包括在加氢转化条件下将权利要求1的催化剂与加氢转化区中的原料接触的步骤。
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公开(公告)号：US20120317872A1
公开(公告)日：2012-12-20
申请号：US13495785
申请日：2012-06-13
CPC分类号： C10L9/086 , B01J27/047 , B01J27/0515 , B01J27/188 , B01J27/19 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J37/0201 , B01J37/031 , B01J37/20 , C10G1/065 , C10G2300/1014 , C10G2300/202 , C10G2300/4081 , C10G2400/04 , C10G2400/08 , C10L5/44 , C10L9/08 , Y02E50/10 , Y02E50/13 , Y02E50/30 , Y02P30/20 , Y02T50/678
摘要： Biofuels can be produced by: (i) providing a biomass containing celluloses, hemicelluloses, lignin, nitrogen compounds and sulfur compounds; (ii) contacting the biomass with a digestive solvent to form a pretreated biomass containing carbohydrates; (iii) contacting the pretreated biomass with hydrogen in the presence of a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co and/or Ni incorporated into a suitable support to form a plurality of oxygenated intermediates, and (vi) processing at least a portion of the oxygenated intermediates to form a liquid fuel.
摘要翻译： 生物燃料可以通过以下方式生产：（i）提供含有纤维素，半纤维素，木质素，氮化合物和硫化合物的生物质; （ii）使生物质与消化溶剂接触以形成含有碳水化合物的经预处理的生物质; （iii）在含有（a）硫，（b）Mo或W的负载氢解催化剂和（c）Co和/或Ni掺入合适的载体中以形成多个含氧的 中间体，和（vi）加工至少一部分氧合中间体以形成液体燃料。
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公开(公告)号：US20120172207A1
公开(公告)日：2012-07-05
申请号：US13331704
申请日：2011-12-20
IPC分类号： B01J31/02
CPC分类号： B01J23/883 , B01J23/24 , B01J23/85 , B01J23/8872 , B01J23/8873 , B01J27/051 , B01J27/0515 , B01J35/0073 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1095 , B01J37/20 , C10G49/04 , C10G49/06 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/301 , C10G2300/701 , C10G2300/703 , C10G2300/802
摘要： An improved process to make a slurry catalyst for the upgrade of heavy oil feedstock is provided. The sulfiding of the metal precursor/catalyst precursor is carried out at least twice (“enhanced sulfiding”) in the improved process to form a slurry catalyst with improved surface area and porosity value. The slurry catalyst under an enhanced sulfiding scheme is characterized as having increased catalytic activities over a slurry catalyst without an enhanced sulfidation step.
摘要翻译： 提供了一种制备用于提高重油原料的浆料催化剂的改进方法。 金属前体/催化剂前体的硫化在改进的方法中进行至少两次（“增强的硫化”），以形成具有改善的表面积和孔隙率值的浆料催化剂。 在增强的硫化方案下的浆料催化剂的特征在于在没有增强的硫化步骤的情况下具有比浆液催化剂增加的催化活性。
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公开(公告)号：US20120172206A1
公开(公告)日：2012-07-05
申请号：US13331630
申请日：2011-12-20
申请人： Joseph V. Nguyen , Julie Chabot , Ling Jiao , Christopher Paul Dunckley , Shuwu Yang , Erin P. Maris , Oleg Mironov , Bruce Edward Reynolds , Alexander E. Kuperman
发明人： Joseph V. Nguyen , Julie Chabot , Ling Jiao , Christopher Paul Dunckley , Shuwu Yang , Erin P. Maris , Oleg Mironov , Bruce Edward Reynolds , Alexander E. Kuperman
IPC分类号： B01J31/02
CPC分类号： B01J23/883 , B01J23/24 , B01J23/85 , B01J23/8872 , B01J23/8873 , B01J27/051 , B01J27/0515 , B01J35/0073 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1095 , B01J37/20 , C10G49/04 , C10G49/06 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/301 , C10G2300/701 , C10G2300/703 , C10G2300/802
摘要： A method for preparing an improved slurry catalyst for the upgrade of heavy oil feedstock is provided. In one embodiment, the process comprises: sulfiding at least a metal precursor solution with at least a sulfiding agent forming a sulfided Group VIB catalyst precursor, the metal precursor solution having a pH of at least 4 and a concentration of less than 10 wt. % of Primary metal in solution; and mixing the catalyst precursor with a hydrocarbon diluent to form the slurry catalyst composition. The slurry catalyst prepared therefrom has a BET total surface area of at least 100 m2/g, a total pore volume of at least 0.5 cc/g and a polymodal pore distribution with at least 80% of pore sizes in the range of 5 to 2,000 Angstroms in diameter.
摘要翻译： 提供了一种制备用于提高重油原料的改进的浆料催化剂的方法。 在一个实施方案中，该方法包括：至少硫化金属前体溶液与至少一种形成硫化VIB族催化剂前体的硫化剂，金属前体溶液的pH值至少为4，浓度小于10wt。 溶液中一次金属的含量％ 并将催化剂前体与烃稀释剂混合以形成淤浆催化剂组合物。 由其制备的浆料催化剂具有至少100m 2 / g的BET总表面积，至少0.5cc / g的总孔体积和至少80％孔径在5至2,000范围内的多孔分布 直径埃。
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公开(公告)号：US20120172205A1
公开(公告)日：2012-07-05
申请号：US13331528
申请日：2011-12-20
申请人： Julie Chabot , Ling Jiao , Joseph V. Nguyen , Christopher Paul Dunckley , Shuwu Yang , Erin P. Maris , Oleg Mironov , Bruce Edward Reynolds , Alexander E. Kuperman
发明人： Julie Chabot , Ling Jiao , Joseph V. Nguyen , Christopher Paul Dunckley , Shuwu Yang , Erin P. Maris , Oleg Mironov , Bruce Edward Reynolds , Alexander E. Kuperman
IPC分类号： B01J31/02
CPC分类号： B01J23/883 , B01J23/24 , B01J23/85 , B01J23/8872 , B01J23/8873 , B01J27/051 , B01J27/0515 , B01J35/0073 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1095 , B01J37/20 , C10G49/04 , C10G49/06 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/301 , C10G2300/701 , C10G2300/703 , C10G2300/802
摘要： An improved hydroprocessing slurry catalyst is provided for the upgrade of heavy oil feedstock. The slurry catalyst is prepared from at least a Group VIB metal precursor compound and optionally at least a Promoter metal precursor compound. The catalyst comprises dispersed particles in a hydrocarbon medium with the dispersed particles have an average particle size ranging from 1 to 300 μm. The catalyst has a total surface area of at least 100 m2/g. The catalyst is prepared from sulfiding and dispersing a metal precursor solution in a hydrocarbon diluent, the metal precursor comprising at least a Primary metal precursor and optionally a Promoter metal precursor, the metal precursor solution having a pH of at least 4 and a concentration of less than 10 wt. % of Primary metal in solution.
摘要翻译： 提供改进的加氢处理浆料催化剂用于重油原料的升级。 浆料催化剂由至少VIB族金属前体化合物和任选的至少一种助催化剂金属前体化合物制备。 该催化剂包含在烃介质中的分散颗粒，其中分散的颗粒的平均粒度范围为1至300μm。 催化剂的总表面积至少为100m 2 / g。 催化剂是通过将金属前体溶液硫化并分散在烃稀释剂中制备的，金属前体包含至少一种金属前体和任选的助催化剂金属前体，该金属前体溶液的pH值至少为4，浓度较低 超过10重量％ 溶液中初级金属的％。
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公开(公告)号：US20120168350A1
公开(公告)日：2012-07-05
申请号：US13331207
申请日：2011-12-20
IPC分类号： C10G47/02 , B01J27/051 , C10G45/04 , B01J27/04 , B01J37/20 , B01J31/02 , B01J27/049 , B01J27/047
CPC分类号： B01J23/883 , B01J23/24 , B01J23/85 , B01J23/8872 , B01J23/8873 , B01J27/051 , B01J27/0515 , B01J35/0073 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1095 , B01J37/20 , C10G49/04 , C10G49/06 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/301 , C10G2300/701 , C10G2300/703 , C10G2300/802
摘要： An improved process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs a polar aprotic solvent to mix with the inorganic metal precursor feed to form an oil-dispersible inorganic metal precursor, at a weight ratio of solvent to inorganic metal precursor of 1:1 to 10:1; the oil-dispersible inorganic metal precursor is subsequently sulfided forming the slurry catalyst. In one embodiment, the sulfiding is in-situ upon mixing the oil-dispersible inorganic metal precursor with a hydrocarbon diluent containing a heavy oil feedstock under in-situ sulfiding conditions.
摘要翻译： 提供了一种用于制备用于重油原料升级的浆料催化剂的改进方法。 该方法使用极性非质子溶剂与无机金属前体进料混合以形成油分散性无机金属前体，溶剂与无机金属前体的重量比为1:1至10:1; 油分散性无机金属前体随后硫化形成浆料催化剂。 在一个实施方案中，在油分散性无机金属前体与在原位硫化条件下含有重油原料的烃稀释剂混合时，将硫化原位。
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28.发明申请BULK SULFIDIC MIXED METAL CATALYST AND METHODS FOR ITS MANUFACTURE AND USE IN CONVERTING SYNGAS TO ALCOHOL 有权大容量硫化金属催化剂及其制造方法及其在酒精转化中的应用公开(公告)号：US20110319505A1
公开(公告)日：2011-12-29
申请号：US13203845
申请日：2010-03-05
申请人： Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
发明人： Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
IPC分类号： C07C27/00 , B01J27/051
CPC分类号： B01J27/0515 , B01J23/8872 , B01J37/0009 , B01J37/20 , C07C29/1518 , Y02P20/52 , C07C31/08 , C07C31/04
摘要： A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.
摘要翻译： 硫化钴 - 钼体积催化剂前体以形成本体硫化醇合成催化剂的方法。 所述方法步骤包括使氧化体钴钴钼催化剂前体与一定量的含硫化合物接触，所述含硫化合物的量在约或约10摩尔硫/每摩尔金属的一个或多个温度下或过量 在基本上不加入氢气的介质中约300℃，以便形成硫化体积的钴 - 钼催化剂产物。 还描述了形成催化剂前体的方法，使用催化剂产物和催化剂产物本身生产醇的方法。
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29.发明申请公开(公告)号：US20110306490A1
公开(公告)日：2011-12-15
申请号：US12813060
申请日：2010-06-10
IPC分类号： B01J27/051 , B01J21/04 , B01J23/887 , B01J23/28 , B01J23/881
CPC分类号： B01J21/04 , B01J23/28 , B01J23/881 , B01J27/0515 , B01J37/0201
摘要： A composition is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising molybdenum supported on a base, such as boehmite or pseudo-boehmite alumina. Iron oxide may also be in the base. The base is preferably bauxite. The heavy hydrocarbon slurry is hydrocracked in the presence of the catalyst to produce lighter hydrocarbons.
摘要翻译： 公开了用于将重质烃进料转化为较轻质烃产品的组合物。 重烃进料用包含负载在基底上的钼的勃姆石或假勃姆石氧化铝的催化剂制浆。 氧化铁也可以在碱中。 基体优选为铝土矿。 在催化剂存在下，将重质烃浆料加氢裂解以产生较轻质的烃。
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公开(公告)号：US20110190557A1
公开(公告)日：2011-08-04
申请号：US12967354
申请日：2010-12-14
IPC分类号： C07C5/02 , B01J27/051 , B01J37/20 , B01J37/04
CPC分类号： C10G45/08 , B01J23/8885 , B01J27/0515 , B01J33/00 , B01J35/002 , B01J35/0046 , B01J37/04 , B01J37/10 , B01J37/14 , B01J37/20 , C10G45/10 , C10G49/04 , C10G49/06 , C10G2300/202 , C10G2300/70
摘要： In a process for producing a hydroprocessing catalyst, a particulate metal oxide composition comprising an oxide of at least one first metal selected from Group 6 of the Periodic Table of the Elements can be mixed with particles of a sulfide of at least one second metal selected from Groups 8 to 10 of the Periodic Table of the Elements to produce a particulate catalyst precursor. The particulate catalyst precursor can then be sulfided under conditions sufficient to at least partially convert the particulate catalyst precursor into a layered metal sulfide having defect sites associated with the second metal sulfide.
摘要翻译： 在制备加氢处理催化剂的方法中，包含选自元素周期表第6族的至少一种第一金属的氧化物的颗粒状金属氧化物组合物可与选自以下的至少一种第二金属的硫化物颗粒混合： 元素周期表第8至10族，以产生颗粒催化剂前体。 然后可以在足以至少部分地将颗粒状催化剂前体转化成具有与第二金属硫化物相关的缺陷位点的层状金属硫化物的条件下将颗粒状催化剂前体硫化。
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