摘要:
A unique design for a mobile system that reforms flare gas or natural gas, using air without steam, to directly produce dimethyl ether (DME), a diesel substitute, is disclosed. The system first reforms the air-methane mixture at ambient atmospheric pressures, and then compresses the resulting CO-hydrogen-nitrogen gas mixture to up to 600 psi, and feeds it through a combined reactor which reacts the gas mixture directly into dimethyl ether. The nitrogen is returned by the system back to the atmosphere. DME is an excellent diesel fuel, and can be used to displace significantly costlier and dirtier petroleum-based diesel fuel, while solving a critical problem with flaring. For example, the over 120 billion cubic feet per year that is currently flared in North Dakota could be converted into over 3 million tons of DME.
摘要:
Disclosed is a process and system to convert acyclic C5 feedstock to non-aromatic, cyclic C5 hydrocarbon. A furnace and reactor tubes comprising a catalyst compound are disclosed. A process involving contacting acyclic C5 feedstock with catalyst composition and obtaining cyclic C5 hydrocarbon is also disclosed.
摘要:
Processes and systems for making cyclopentadiene and/or dicyclopentadiene include converting acyclic C5 hydrocarbon(s) into CPD in a first reactor to obtain a first reactor hydrocarbon effluent, which is processed in an eductor to obtain an eductor effluent at higher total pressure than atmospheric pressure, separating the eductor effluent in a separator such as compression train to obtain a C5-rich fraction comprising CPD, dimerizing the C5-rich fraction in a second reactor to obtain a product effluent comprising DCPD, which is separated to obtain a DCPD-rich fraction. Multiple-stage of dimerization and separation steps can be optionally used to obtain multiple DCPD-rich fractions of various degrees of purity and quantity. C5-rich fractions from various stages of the process may be recycled to the first reactor, or converted into mogas components after selective hydrogenation. C5-rich fractions and mogas components may be optionally separated to produce value-adding chemicals.
摘要:
A catalyst reactor basket is provided that includes an outer side wall extending along the outer circumferential periphery and an inner side wall disposed within the outer side wall. An aperture is sized and shaped to allow a fluid to flow axially with respect to the basket. First and second covers are disposed on opposite ends of the outer side wall and inner side wall and a dividing wall is disposed between the first and second covers. The dividing wall defines a first and second chamber within the inner volume of the basket. A plurality of partitions are disposed within the first and second chambers. The plurality of partitions define a plurality of compartments within the first and second chambers, each compartment being sized and shaped to receive a catalyst.
摘要:
The present invention relates to a reactor and to a process for synthesis of hydrogen sulphide from elemental sulphur and hydrogen at elevated pressure and elevated temperature. The invention further relates to the use of the reactor for preparation of hydrogen sulphide in high yield and with a low H2SX content.
摘要:
A distributor tray for a gas and a liquid circulating as a co-current, said tray comprising a plate perforated by orifices and supporting hollow chimneys extending perpendicularly to said plate, each orifice of the plate being surmounted by a chimney of identical cross section to said orifice, characterized in that the plate is equipped with a plurality of openings arranged on the periphery of each chimney inside a circumscribed circle, the center of which coincides with the center of the chimney, and the radius of which is less than or equal to ⅓ of the shortest distance separating two adjacent chimneys, and in that a single deflector element is arranged beneath each chimney, the openings and the deflector element associated with each of the chimneys being so arranged as to impart a rotating movement to the gas/liquid mixture under each chimney.
摘要:
The present invention relates to a composition comprising: a) at least one support material; b) at least one metal selected from transition group VIII of the Periodic Table of the Elements and c) at least one compound of the formula (I) R′-A-R″ (I), where A, R′ and R″ are each an organic radical, where R′ and R″ have the structural element —O—P(—O—)2 with trivalent P and are bonded covalently to the A radical via the latter, with the proviso that R′≠R″, to a process for producing such a composition, to the use of the composition and to a process and an apparatus for hydroformylation in which the composition is used.
摘要:
An exemplary hydrogen production apparatus 100 according to the present invention includes a grinding unit 10 configured to grind a silicon chip or a silicon grinding scrap 1 to form silicon fine particles 2, and a hydrogen generator 70 configured to generate hydrogen by causing the silicon fine particles 2 to contact with as well as disperse in, or to contact with or dispersed in water or an aqueous solution. The hydrogen production apparatus 100 can achieve reliable production of a practically adequate amount of hydrogen from a start material of silicon chips or silicon grinding scraps that are ordinarily regarded as waste. The hydrogen production apparatus thus effectively utilizes the silicon chips or the silicon grinding scraps so as to contribute to environmental protection as well as to significant reduction in cost for production of hydrogen that is utilized as an energy source in the next generation.
摘要:
Processes and systems for producing olefins, including: dehydrogenating a first n-alkane to produce a first effluent; and dehydrogenating at least one of a first isoalkane or a second n-alkane to produce a second effluent. The first and second effluents may be compressed and fed to a common separation train to separate the effluents into two or more fractions. In some embodiments, each of the first and second dehydrogenation reaction zones may include two reactors, one reactor in each of the reaction zones operating in a dehydrogenation cycle, one operating in a regeneration cycle, and one operating in a purge or evacuation/reduction cycle. Operation of the reactors in the dehydrogenation cycle is staggered, such that the purge cycle, regeneration cycle, or evacuation/reduction cycle of the reactors may not overlap.
摘要:
The present invention relates to a reactor (201) for preparing hydrogen cyanide by the Andrussow process, to an equipment (200) comprising said reactor and to a process for preparing hydrogen cyanide by the Andrussow process. The reactor (201) comprising at least one gas inlet (I) for reactant gases mixture, a catalyst (203), a porous support for the catalyst (204), a porous sub support (205, 206) and at least one outlet (P8) for the reaction products. According to the invention, said reactor has a cone frustum shaped metallic casing (210) and comprises inside the metallic casing, a gas distributor (202) located between the gas inlet and the catalyst, said distributor comprising at least one cone frustum element (D1, . . . Dn) having an upper base directed towards the gas inlet (I).