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92 条记录 (耗时 0.016 秒)

    Odorants
    21.
    发明授权
    Odorants 失效
    气味

    公开(公告)号：US06235943B1

    公开(公告)日：2001-05-22

    申请号：US09680818

    申请日：2000-10-05

    申请人： Jerzy A. Bajgrowicz ,  Georg Frater

    发明人： Jerzy A. Bajgrowicz ,  Georg Frater

    IPC分类号： C07C49105

    CPC分类号： C11B9/003 ,  C07C31/13 ,  C07C31/137 ,  C07C33/12 ,  C07C35/28 ,  C07C45/59 ,  C07C45/67 ,  C07C45/68 ,  C07C45/69 ,  C07C45/74 ,  C07C47/225 ,  C07C47/44 ,  C07C49/21 ,  C07C49/553 ,  C07C49/613 ,  C07C49/627 ,  C07C49/633 ,  C07C47/115

    摘要： The invention relates to compounds of the general formula in which R1 to R7 are, independently, H, methyl or ethyl, R8+R9 together form methylene (—CH2—) or a single bond, or R1+R2 together form —(CH2)n—, with n being 3 or 4, or R3+R5 or R5+R7 represent methylene or a single bond; and the presence of at least one cyclopropane ring in the molecule is compulsory and the side chain can be saturated or contains one double bond in position &agr;,&bgr; or &bgr;,&ggr;, a process for the manufacture of these compounds, compounds used to perform the process and the use of these compounds as an odorant or as an ingredient of an odorant composition.

    摘要翻译： 本发明涉及一般形式的化合物，其中R 1至R 7独立地为H，甲基或乙基，R 8 + R 9一起形成亚甲基（-CH 2 - ）或单键，或者R 1 + R 2一起形成 - （CH 2）n - ，其中n为3或4，或R3 + R5或R5 + R7表示亚甲基或单键; 并且分子中存在至少一个环丙烷环是强制性的，并且侧链可以饱和或在α，β或β位置上含有一个双键，γ是制备这些化合物的方法，用于执行 方法和这些化合物作为气味剂或作为气味组合物的成分的用途。

    Process for preparation of 1-[1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentyl]-1,5,9-triazanonane and novel intermediates
    25.
    发明授权
    Process for preparation of 1-[1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentyl]-1,5,9-triazanonane and novel intermediates 失效
    制备1- {8,5-二（3,3-二甲基降冰片基-2-基）-3-戊基{9-1,5,9-三氮杂壬烷和新中间体的方法

    公开(公告)号：US4139559A

    公开(公告)日：1979-02-13

    申请号：US869879

    申请日：1978-01-16

    申请人： Nathaniel Grier ,  Richard A. Dybas ,  Robert A. Strelitz

    发明人： Nathaniel Grier ,  Richard A. Dybas ,  Robert A. Strelitz

    IPC分类号： A01N33/04 ,  C07C31/137 ,  C07C49/115 ,  C07C53/136 ,  C07C87/40

    CPC分类号： A01N33/04 ,  C07C31/137 ,  C07C49/115 ,  C07C53/136

    摘要： A process for preparing 1-[1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentyl]-1,5,9-triazanonane from 1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentanone by reaction with ammonia to form, after reduction, 3-amino-[1,5-di-(3,3-dimethylnorborn-2-yl)pentane]. This latter compound is reacted with acrylonitrile, reduced, and the diamine product again reacted with acrylonitrile and again reduced. Alternative routes wherein the ketone is reduced to the novel alcohol and optionally the novel halide and either then reacted with 3,3'-iminobispropylamine to form the desired polyamine are also shown.

    摘要翻译： 从1,5-二（3,3-二甲基牛磺酸）制备1- [1,5-二（3,3-二甲基牛磺-2-基）-3-戊基] -1,5,9-三氮杂壬烷的方法 -2-基）-3-戊酮通过与氨反应，在还原后形成3-氨基 - [1,5-二（3,3-二甲基牛磺酸-2-基）戊烷]。 后一种化合物与丙烯腈反应，还原，二胺产物再次与丙烯腈反应并再次还原。 还示出了替代途径，其中酮被还原成新的醇和任选的新型卤化物，然后与3,3'-亚氨基双丙胺反应以形成所需的多胺。

    Sulfur-containing carboxylic acid esters
    28.
    发明授权
    Sulfur-containing carboxylic acid esters 失效
    含硫羧酸酯

    公开(公告)号：US3494947A

    公开(公告)日：1970-02-10

    申请号：US73456068

    申请日：1968-06-05

    申请人： EXXON RESEARCH ENGINEERING CO

    发明人： SCHUTZE HENRY G ,  BOWN DELOS E

    IPC分类号： C07C29/17 ,  C07C317/00 ,  C08K5/05 ,  C08K5/372 ,  C08L23/02 ,  C09B1/54 ,  C09F1/04 ,  C07C149/20 ,  C08F45/58

    CPC分类号： C07C29/172 ,  C07C323/00 ,  C07C2603/26 ,  C08K5/05 ,  C08K5/372 ,  C09B1/503 ,  C09B1/545 ,  C09F1/04 ,  C08L23/02 ,  C07C31/137

    摘要： Di-esters of thiodipropionic acid, HOOC-CH2-CH2-S-CH2-CH2-COOH, with cyclic terpene alcohols are used as costabilizers for polyolefins. Suitable cyclic terpene alcohols are, for example, tetrahydroabietyl, dihydroabietyl and dehydroabietyl alcohols, a -, b -, and g -terpinols and their hydrogenated derivatives (saturated alcohols), menthol and borneol. A mixture of esters, in particular a mixture of the esters of tetrahydroabietyl, dihydroabietyl and dehydroabietyl alcohols, may be used. The other stabilizer present in the stabilized mixture is a "hindered" phenol, i.e. a phenol having at least one C4 or higher tertiary alkyl group in the position ortho to the hydroxy group, e.g. 2,6 - di - t - butyl - 4 - methylphenol; 2-t-butylphenol; 4,41 - butylidene - bis - (3 - methyl - 6-t-butylphenol); 2,21-methylene-bis(4-methyl-6-t - butylphenol); 4,41 - methylene - bis(2,6 - di-t - butylphenol); 4,41 - (1,1 - butylidene - bis(3 - methyl - 6 - t - butylphenol a 2,a 6 - bis(3 t - butyl - 5 - methyl - 2 - hydroxyphenyl)-mesitol; 4,41 - thiobis(2 - methyl - 6 - t - butylphenol) and diterpene-diphenols. The polyolefins which may be stabilized are prepared from one or more olefins having 2-8 carbon atoms and preferably have molecular weights of 10,000-1,000,000.ALSO:The invention comprises di-esters of thiodipropionic acid, HOOC-CH2-CH2-S-CH2-CH2-COOH with a cyclic terpene alcohol. The preferred alcohols are derived from abietic acid, e.g. tetrahydro-, dihydro- and dehydro-abietyl alcohols but other suitable alcohols are a -terpiniol, b -terpiniol, g -terpiniol and their hydrogenated derivatives, borneol and menthol. The esters may be made by reacting the alcohol with the acid in the presence of a mineral acid and, if desired, a mixture of alcohols may be used.