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公开(公告)号:US09920144B2
公开(公告)日:2018-03-20
申请号:US15507998
申请日:2015-08-20
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , Brandon N. Hudder
Inventor: Arrigo Arletti , Lucia Caiazzo , Gianni Collina , Daniele Evangelisti , Ofelia Fusco , Benedetta Gaddi
IPC: C08F110/06
CPC classification number: C08F110/06 , B01J31/0204 , B01J31/0209 , B01J31/0274 , B01J31/0275 , B01J31/143 , B01J31/38 , C08F10/06 , C08F4/6543 , C08F2500/18 , C08F2500/15 , C08F2500/24
Abstract: The present disclosure relates to a porous solid adduct comprising magnesium chloride and ethanol, characterized by a relationship between the content of alcohol, average pore radius and amount of porosity deriving from pores with radii of 100-1000 nm, and catalyst components produced therefrom that are capable of producing polyolefins with increased porosity.
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公开(公告)号:US20180044511A1
公开(公告)日:2018-02-15
申请号:US15798017
申请日:2017-10-30
Applicant: EQUISTAR CHEMICALS, LP , Basell Poliolefine Italia S.r.l.
Inventor: MAGED G. BOTROS , ENRICO CONSTANTINI , CHARLES S. HOLLAND , CHUN D. LEE , ENRICO MASARATI
IPC: C08L23/10
CPC classification number: C08L23/10 , C08L23/14 , C08L23/16 , C08L51/06 , C08L2203/16 , C09J123/14 , C08L23/02
Abstract: The present disclosure provides a polyolefin-based composition suitable for use as adhesives and/or tie-layer adhesive compositions as well as a multi-layered structure made from and/or containing the polyolefin-based composition. The polyolefin-based composition is made from and/or contains (a) a grafted polyolefin composition, (b) a first polymer composition, (c) a polypropylene-containing blend composition, and (d) optionally, an additives composition having one or more additives.
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公开(公告)号:US20170291972A1
公开(公告)日:2017-10-12
申请号:US15511976
申请日:2015-09-09
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Mara DESTRO , Marco CIARAFONI , Paola MASSARI , Tiziana CAPUTO , Thomas BOHM
IPC: C08F210/06 , C08F210/08 , B65D1/02 , C08F4/646 , C08F2/00 , C08F210/16 , C08F4/654
Abstract: The present disclosure provides an article of manufacture made from or containing a propylene-based terpolymer, having (i) ethylene-derived units in the range from about 0.5 wt. % to about 1.8 wt. %; (ii) 1-butene-derived units in the range from about 1.5 wt. % to about 2.5 wt. %; (iii) a ratio of C2 wt %/C4 wt % in the range from about 0.40 to about 0.80, wherein C2 wt % is the weight percent of ethylene-derived units and C4 wt % is the weight percent of 1-butene-derived units; (iv) a melt flow rate in the range from about 30 g/10 min to about 80 g/10 min; (v) a xylene soluble fraction at 25° C. lower than about 5.0 wt. %; and (vi) a melting point higher than about 140° C. The article can be a container, which can be used for food applications.
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公开(公告)号:US20170275436A1
公开(公告)日:2017-09-28
申请号:US15591979
申请日:2017-05-10
Applicant: BASELL POLIOLEFINE ITALIA S.r.l.
Inventor: GIUSEPPE FERRARA , ENRICO COSTANTINI , MARCO CONSALVI
CPC classification number: C08K3/26 , C08L23/20 , C08L51/06 , Y10T428/139 , Y10T442/60 , C08L23/02 , C08L2666/24
Abstract: A polyolefin nanocomposite material comprising the following components: (A) a crystalline or semi-crystalline polyolefin resin; and (B) a nanosized mineral filler comprising or substantially consisting of a hydrotalcite, wherein the amount of the hydrotalcite is from 0.02 to 6 parts by weight per 100 parts by weight of the nanocomposite material, and the ratio MFR (1)/MFR (2) of the melt flow rate value MFR (1) of component (A) to the melt flow rate value MFR (2) of the polyolefin nanocomposite material is of at least 1.02, characterized in that the said polyolefin nanocomposite material includes a compatibilizer the dispersion of the mineral filler (B) and compatibilizer in the polyolefin resin is produced at shear mixing rates from 30 to 300 sec−1,
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公开(公告)号:US09676883B2
公开(公告)日:2017-06-13
申请号:US15309042
申请日:2015-05-06
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Fabrizio Piemontesi , Caroline Cathelin , Simona Guidotti , Dario Liguori , Giampiero Morini , Davide Tartari , Gianni Vitale
IPC: C08L23/00 , C08F2/00 , C08F210/00 , C08F210/06
CPC classification number: C08F210/06 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/26 , C08F4/6574
Abstract: The present disclosure relates to propylene-ethylene copolymers comprising an ethylene content of 0.1-10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 3.0 and a xylene soluble (XS) fraction content defined by values that fall below the line given by the equation XS=1.0296·e0.435C2. The propylene-ethylene copolymers advantageously exhibit high transparency and low melting temperatures.
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公开(公告)号:US09650505B2
公开(公告)日:2017-05-16
申请号:US14357503
申请日:2012-10-30
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Fabiana Fantinel , Sander Willems , Michele Grazzi , Giampaolo Pellegatti , Jurgen Rohrmann , Shahram Mihan
CPC classification number: C08L23/12 , C08L23/06 , C08L23/0807 , C08L23/10 , C08L23/16 , C08L2205/02 , C08L23/0815 , C08L23/142
Abstract: Polyolefin compositions suitable for injection molded items e.g. for impact bumpers and car interiors comprising from 30% to 90% by weight of an heterophasic propylene polymer composition (A); and from 10% to 70% by weight of a multimodal ethylene/butene-1 copolymer (B); having density from 0.850 to 0.935 g/cm3, total comonomer content from 6% to 30% by weight, Mw/Mn from 4 to 20; intrinsic viscosity in decalin at 135° C. from 1.0 to 4.0 dL/g, and comprising an HDPE fraction (HDPE % wt) up to 30% wt; further comprising from 0 to 50% by weight of a filler (C) and optionally, in amount up to 10% by weight with respect to the overall composition, an impact modifier masterbatch component D consisting of an ultra-soft heterophasic copolymer component.
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公开(公告)号:US09650458B2
公开(公告)日:2017-05-16
申请号:US14774591
申请日:2014-03-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Monica Galvan , Andreas Neumann , Tiziana Caputo , Stefano Squarzoni , Antonio Mazzucco , Ofelia Fusco , Benedetta Gaddi , Gianni Collina , Gisella Biondini , Claudio Cavalieri , Roberto Pantaleoni
IPC: C08F210/06 , C08F4/646 , C08F4/649 , C08F4/654
CPC classification number: C08F210/06 , C08F4/6543 , C08F4/651 , C08F110/06 , C08F4/6492 , C08F210/16 , C08F210/08 , C08F2500/12 , C08F2500/26
Abstract: Propylene terpolymers are prepared by polymerizing propylene, ethylene and an alpha-olefin selected from the group of C4-C8 alpha-olefins in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.
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公开(公告)号:US09567418B2
公开(公告)日:2017-02-14
申请号:US15032694
申请日:2014-09-24
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Monica Galvan , Andreas Neumann , Caroline Cathelin , Francesca Tisi , Giampaolo Pellegatti
IPC: C08F210/06 , C08J5/18 , C08L23/14
CPC classification number: C08F210/06 , C08J5/18 , C08J2323/14 , C08L23/14 , C08F210/14 , C08F2500/05 , C08F2500/12 , C08F2500/20
Abstract: The present disclosure relates to a propylene-1-hexene copolymer having: i) a content of 1-hexene derived units ranging from 0.6 wt % to 3.0 wt %; ii) a melt flow rate (MFR) measured according to the method ISO 1133 (230° C., 5 kg) ranging from 0.5 g/10 min to 5.0 g/10 min; iii) a polydispersity (PI) ranges from 4.5 to 10 and the distribution of molecular weight is of multimodal type; iv) a melting point ranging from 160° C. to 145° C.; and v) a differential scanning calorimetry (DSC) curve (temperature/heat of fusion) that shows at least two peaks.
Abstract translation: 本公开内容涉及丙烯-1-己烯共聚物,其具有:i)1-己烯衍生单元的含量范围为0.6重量%至3.0重量%; ii)根据ISO 1133(230℃,5kg)测量的熔体流动速率(MFR)为0.5g / 10min至5.0g / 10min; iii)多分散性(PI)为4.5〜10,分子量分布为多峰型; iv)熔点范围为160℃至145℃; 和v)显示至少两个峰的差示扫描量热法(DSC)曲线(温度/融合热)。
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公开(公告)号:US20170002114A1
公开(公告)日:2017-01-05
申请号:US15106766
申请日:2014-12-15
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: TIZIANO DALL'OCCO , DARIO LIGUORI , GIAMPIERO MORINI , GIANNI VITALE
IPC: C08F10/02
CPC classification number: C08F10/02 , C08F10/00 , C08F4/6494 , C08F4/651 , C08F4/6545 , C08F110/02 , C08F2500/12 , C08F2500/18
Abstract: The present disclosure relates to catalyst systems for the polymerization of olefins of the general formula CH2═CHR that show improved polymerization activity, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising (A) a solid catalyst component comprising Ti, Mg, and halogen, (B) an aluminum alkyl compound, and (C) a halogenated cyclic ether compound.
Abstract translation: 本公开涉及用于聚合具有改进的聚合活性的通式CH 2 = CHR的烯烃的催化剂体系,其中R是具有1-12个碳原子的烷基,环烷基或芳基,其包含(A)固体催化剂组分 包括Ti,Mg和卤素,(B)烷基铝化合物和(C)卤代环醚化合物。
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公开(公告)号:US20160319118A1
公开(公告)日:2016-11-03
申请号:US15105492
申请日:2014-12-15
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PAOLA MASSARI , MARCO CIARAFONI , SANDER WILLEMS , JURGEN ROHRMANN
IPC: C08L23/12
CPC classification number: C08L23/12 , B29C45/0001 , C08K3/34 , C08L23/0815 , C08L23/16 , C08L2205/025 , C08L2207/02
Abstract: The present disclosure relates to a polypropylene composition for the production of molded articles, such as finished parts for the automotive industry, has melt flow rate (230° C., 2.16 kg) of at least 25 g/10 min and comprising: (A) 50-95% of a composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. of 3.0-5.0 dl/g; and (A1) 70-95% of a propylene homopolymer having a polydispersity index (PI) of 4.3-10, a fraction insoluble in xylene at 25° C. higher than 90% and an MFR (230° C., 2.16 kg) of 100-250 g/10 min; (A2) 5-30% of a copolymer of propylene with 36-44% of ethylene-derived units; (B) optionally up to 45% of a heterophasic propylene polymer, having an MFR (230° C., 2.16 kg) of 10-25 g/10 min, a flexural modulus higher than 1400 MPa, comprising 5-20% of a copolymer rubber component and 80-95% of a matrix propylene polymer component; (C) 2-10% of an ethylene based elastoplastic copolymer; and (D) optionally up to 20% of talc.
Abstract translation: 用于生产模制品的聚丙烯组合物,例如用于汽车工业的成品,其熔体流动速率(230℃,2.16Kg)为至少25g / 10min,包括:(A)50-95% 在25℃下可溶于二甲苯的级分的特性粘度为3.0-5.0dl / g的组合物,其组成为:(Al)70-95%的多分散指数(PI)为4.3〜10的丙烯均聚物, 在25℃下不溶于二甲苯的馏分高于90%,MFR(230℃,2.16Kg)为100-250g / 10min; (A2)5-30%丙烯与36-44%乙烯衍生单元的共聚物; (B)任选多达45%的多相丙烯聚合物,MFR(230℃,2.16Kg)为10-25g / 10min,弯曲模量高于1400MPa,并且包含5-20%的共聚物橡胶 组分和80-95%的基质丙烯聚合物组分; (C)2-10%的乙烯基弹性共聚物; 和(D)任选地最多20%的滑石。
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