公开(公告)号：US09435589B2

公开(公告)日：2016-09-06

申请号：US14398439

申请日：2013-05-02

Applicant: STAMICARBON B.V.

Inventor： Alexander Aleida Antonius Scheerder

IPC: F28F9/18 ,  B01J19/02 ,  B21D53/08 ,  B23K31/02 ,  F28F19/06 ,  F28F21/08 ,  F28D7/06 ,  B01J19/00 ,  B01J19/24 ,  B01J3/04 ,  F28D21/00

CPC classification number: F28F9/18 ,  B01J3/04 ,  B01J19/0013 ,  B01J19/006 ,  B01J19/02 ,  B01J19/24 ,  B01J2219/00081 ,  B01J2219/00256 ,  B01J2219/00768 ,  B01J2219/024 ,  B01J2219/0286 ,  B01J2219/182 ,  B01J2219/192 ,  B21D53/08 ,  B23K31/027 ,  B23K2101/14 ,  B23K2103/04 ,  B23K2103/05 ,  B23K2103/18 ,  F28D7/06 ,  F28D2021/0022 ,  F28F9/185 ,  F28F19/06 ,  F28F21/083 ,  Y02P20/142 ,  Y10T29/49373 ,  Y10T29/49968

Abstract: The present application relates to a method of manufacturing a tube sheet (7) and heat exchanger assembly for a pool reactor or pool condenser for use in the production of urea from ammonia and carbon dioxide, wherein the method comprises manufacturing of the tube sheet (7) from a carbon steel material grade and providing said tube sheet (7) with corrosion protective layers (8, 9) of an austenitic-ferritic duplex stainless steel grade, wherein the heat exchanger comprises at least one U-shaped tube (13) of an austenitic-ferritic duplex stainless steel grade, the method further comprises inserting at least two sleeves (11) of an austenitic-ferritic duplex stainless steel grade through the tube sheet (7) such that both ends of the sleeve (11) extend in a direction away from the tube sheet (7), the method further comprises connecting the sleeves (11), at least the opposing ends thereof, to at least the protective layers (8,9) of the tube sheet (7) and finally, connecting both ends of the at least one U-shaped tube (13) to the respective sleeves (11).

Abstract translation: 本申请涉及制造管板（7）和用于从氨和二氧化碳生产尿素的池式反应器或池式冷凝器的热交换器组件的方法，其中该方法包括制造管板（7 ），并且为所述管板（7）提供具有奥氏体 - 铁素体双相不锈钢等级的腐蚀保护层（8,9），其中所述热交换器包括至少一个U形管（13），所述U形管 奥氏体 - 铁素体双相不锈钢级，该方法还包括通过管板（7）插入至少两个奥氏体 - 铁素体双相不锈钢级的套筒（11），使得套筒（11）的两端在 远离管板（7）的方向，该方法还包括至少将套管（11）的相对端部连接到管板（7）的至少保护层（8,9）上，最后连接 的两端 至少一个U形管（13）到相应的套筒（11）。

公开(公告)号：US09394219B2

公开(公告)日：2016-07-19

申请号：US14354531

申请日：2012-10-25

Applicant: STAMICARBON B.V.

Inventor： Gaetano Iaquaniello ,  Barbara Cucchiella ,  Elena Antonetti

IPC: C07C29/48 ,  C01B3/38 ,  C01B3/48 ,  C07C29/151 ,  C01B3/32

CPC classification number: C07C29/48 ,  C01B3/323 ,  C01B3/386 ,  C01B3/48 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/061 ,  C01B2203/1235 ,  C01B2203/1258 ,  C01B2203/142 ,  C07C29/1518 ,  C07C31/04

Abstract: Method for producing synthesis gas for methanol production The present invention relates to a method for producing synthesis gas from a hydrocarbon containing feed, which synthesis gas is particularly suitable for subsequent use in methanol production. In this method, a hydrocarbon containing feed, particularly natural gas (100), is subjected to catalytic partial oxidation (CPO) (2), followed by the water gas shift (WGS) (4) reaction of a part of the reformed feed. At least part of the shifted feed is then subjected to hydrogen purification, preferably by pressure swing adsorption (PSA) (5) to obtain pure hydrogen (108), which hydrogen is subsequently combined with the remaining parts of the feeds to yield synthesis gas particularly suitable for methanol synthesis. The recombined stream preferably has an R ratio, being the molar ratio (H2−CO2)/(CO+CO2), in the range 1.9-2.2 and preferably about 2. The invention further relates to a method for producing methanol from a hydrocarbon containing feed, wherein first synthesis gas is obtained according to the method of the invention, which synthesis gas is further used to produce methanol.

Abstract translation: 用于生产甲醇生产合成气的方法本发明涉及一种由含烃进料生产合成气的方法，该合成气特别适用于随后用于甲醇生产。 在该方法中，将含烃进料，特别是天然气（100）进行催化部分氧化（CPO）（2），然后进行部分重整进料的水煤气变换（WGS）（4）反应。 然后至少部分转移的进料进行氢气净化，优选通过变压吸附（PSA）（5）进行氢气净化，以获得纯氢气（108），该氢气随后与进料的剩余部分组合以产生合成气，特别是 适合甲醇合成。 重组流优选具有在1.9-2.2范围内，优选约2的摩尔比（H 2 -CO 2）/（CO + CO 2）的R比。本发明还涉及一种由含烃的 进料，其中根据本发明的方法获得第一种合成气，该合成气被进一步用于生产甲醇。

公开(公告)号：US20160115026A1

公开(公告)日：2016-04-28

申请号：US14989696

申请日：2016-01-06

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： Fabio ANGELINI ,  Lucia BARBATO

IPC: C01B17/04 ,  B01J8/00 ,  C01B3/04

CPC classification number: C01B17/0495 ,  B01D53/8612 ,  B01D2251/102 ,  B01D2256/16 ,  B01J8/00 ,  C01B3/02 ,  C01B3/04 ,  C01B17/0404 ,  C01B17/0408 ,  C01B17/0426 ,  Y02E60/364 ,  Y02P20/129

Abstract: Disclosed is a process for the concurrent production of hydrogen and sulphur from a H2S-containing gas stream, with reduced, and preferably zero, emissions. The method comprises the catalytic oxidative cracking of H2S so as to form H2 and S2. Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The process is conducted in a reaction chamber comprising a bifunctional catalyst material, so as to favor both the partial oxidation of H2S and the dissociation thereof.

Abstract translation: 公开了一种从含H 2 S的气流同时生产氢和硫的方法，具有减少的，优选为零的排放。 该方法包括H2S的催化氧化裂化，形成H2和S2。 优选地，使用富氧空气，优选纯氧进行氧化。 该方法在包含双官能催化剂材料的反应室中进行，以有利于H2S的部分氧化和其解离。

公开(公告)号：US09102532B2

公开(公告)日：2015-08-11

申请号：US14354536

申请日：2012-10-26

Applicant: STAMICARBON B.V.

Inventor： Gaetano Iaquaniello ,  Elena Antonetti ,  Palma Contaldo

IPC: C01B3/26 ,  C01B3/30 ,  C07C29/151 ,  C07C29/00

CPC classification number: C01B3/26 ,  C01B3/30 ,  C01B3/38 ,  C01B3/386 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/061 ,  C01B2203/1235 ,  C01B2203/141 ,  C01B2203/142 ,  C07C29/00 ,  C07C29/1518

Abstract: Method for producing synthesis gas for methanol production The present invention relates to a method for producing synthesis gas from a hydrocarbon containing feed, which synthesis gas is particularly suitable for subsequent use in methanol production. In this method, a feed (100) is divided into two streams, wherein one stream is subjected to catalytic partial oxidation (CPO) (2) and the other stream is subjected to steam reforming (5) followed by a water gas shift reaction (51). The two streams are then recombined and can be used further in methanol synthesis (6). The recombined stream preferably has an R ratio, being a molar ratio (H2−C02)/(CO+C02), in the range of 1.9-2.2 and preferably about 2. The invention further relates to a method for producing methanol from a hydrocarbon containing feed, wherein first synthesis gas is obtained according to the method of the invention, which synthesis gas is further used to produce methanol. Also, the invention relates to a method of adapting an existing methanol plant to the methanol production process of the invention.

Abstract translation: 用于生产甲醇生产合成气的方法本发明涉及一种由含烃进料生产合成气的方法，该合成气特别适用于随后用于甲醇生产。 在该方法中，将进料（100）分成两股料流，其中一条料流进行催化部分氧化（CPO）（2），另一条料流进行蒸汽重整（5），随后进行水煤气变换反应 51）。 然后将两种物流重组，并可以进一步用于甲醇合成（6）。 重组流优选具有在1.9-2.2，优选约2的范围内的摩尔比（H 2 -CO 2）/（CO + CO 2）的R比。本发明还涉及一种从烃生产甲醇的方法 其中根据本发明的方法获得第一合成气，该合成气被进一步用于生产甲醇。 本发明还涉及使现有的甲醇装置适应本发明的甲醇生产方法。

公开(公告)号：US20150133690A1

公开(公告)日：2015-05-14

申请号：US14398433

申请日：2013-05-02

Applicant: STAMICARBON B.V.

Inventor： Johannes Henricus Mennen ,  Jozef Hubert Meessen

IPC: C07C273/04 ,  B01D47/00 ,  B23P15/26 ,  B01D5/00

CPC classification number: C07C273/04 ,  B01D5/006 ,  B01D5/009 ,  B01D47/00 ,  B01J10/00 ,  B23P15/26 ,  Y10T29/49352

Abstract: Disclosed is a plant for the production of urea. The plant comprises conventional sections for synthesis and recovery, for evaporation and condensation, for urea finishing, and for dust scrubbing. According to the invention, an additional evaporation and condensation loop is introduced from and to the dust scrubbing section. This loop results in a more favorable energy consumption of the plant.

Abstract translation: 公开了一种用于生产尿素的设备。 该设备包括用于合成和回收的常规部分，用于蒸发和冷凝，用于尿素整理和用于灰尘洗涤。 根据本发明，从灰尘洗涤部分引入附加的蒸发和冷凝环路。 该循环导致植物更有利的能量消耗。

公开(公告)号：US20150119603A1

公开(公告)日：2015-04-30

申请号：US14398425

申请日：2013-05-02

Applicant: STAMICARBON B.V.

Inventor： Johan Albert Arno Van Den Tillaart ,  Jozef Hubert Meessen

IPC: C07C273/04 ,  B01J19/00

CPC classification number: C07C273/04 ,  B01J10/00 ,  B01J19/0013 ,  B01J2219/00051 ,  Y02P20/142

Abstract: Method for the production of urea from ammonia and carbon dioxide in a urea plant containing a high-pressure synthesis section with a horizontal pool condenser, wherein the method comprises exchanging heat from a high pressure process medium received in a shell section of the pool condenser to a medium pressure urea containing solution received in a first heat exchanging section provided in the pool condenser to at least decompose ammonium carbamate into NH3 and CO2, wherein the method further comprises exchanging heat from the high pressure process medium to a low pressure steam condensate received in a second heat exchanging section provided in the pool condenser to produce low pressure steam. The invention also relates to an apparatus for the production of urea from ammonia and carbon dioxide.

Abstract translation: 在含有具有水平冷凝器的高压合成部分的尿素装置中由氨和二氧化碳生产尿素的方法，其中所述方法包括将从所述池冷凝器的壳部分中接收的高压处理介质的热交换到 容纳在所述池冷凝器中的第一热交换部分中的中压含尿素溶液以至少将氨基甲酸铵分解成NH 3和CO 2，其中所述方法还包括将热量从所述高压处理介质交换到低压蒸汽冷凝物 设置在池冷凝器中以产生低压蒸汽的第二热交换部分。 本发明还涉及一种用于从氨和二氧化碳生产尿素的设备。

公开(公告)号：US20140170052A1

公开(公告)日：2014-06-19

申请号：US14118182

申请日：2012-06-25

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： Gaetano Iaquaniello ,  Barbara Cucchiella ,  Elena Antonetti

IPC: C01C1/04

CPC classification number: C01C1/04 ,  C01B3/025 ,  C01B3/386 ,  C01B3/48 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0288 ,  C01B2203/043 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/068 ,  C01B2203/1241 ,  C01B2203/127 ,  C01B2203/148 ,  C07C273/04

Abstract: Disclosed is a process for the production of ammonia comprising a step wherein synthesis gas is formed by catalytic partial oxidation. Also disclosed is a process of producing urea, wherein ammonia is formed in a process involving a step of catalytic partial oxidation, and carbon dioxide formed in the same process is reacted with said ammonia so as to form urea.

Abstract translation: 公开了一种生产氨的方法，包括通过催化部分氧化形成合成气的步骤。 还公开了生产尿素的方法，其中在涉及催化部分氧化步骤的方法中形成氨，并且将在相同方法中形成的二氧化碳与所述氨反应以形成尿素。

公开(公告)号：US3929911A

公开(公告)日：1975-12-30

申请号：US10695871

申请日：1971-01-18

Applicant: STAMICARBON

Inventor： VAN DIERENDONCK LAURENTIUS L ,  VON DEN HOFF JOHAN P H

IPC: C07C37/56 ,  C07C37/00

CPC classification number: C07C37/56 ,  Y02P20/52 ,  C07C39/04

Abstract: An improved process for continuous production of a phenol by pyrolytic oxidation and decarboxylation of a benzenemonocarboxylic acid in the presence of dissolved copper followed by hydrolysis of the intermediate reaction mixture from the oxidation and decarboxylation step, wherein the intermediate reaction mixture from the oxidation and decarboxylation step is fed together with steam and a sufficient quantity of molecular oxygen to a hydrolysis zone whereby the copper in the reaction mixture is maintained in solution during the hydrolysis step by maintaining the copper in a bivalent oxidation state.

Abstract translation: 一种改进的方法，用于在溶解的铜存在下，通过苯甲酰羧酸的热解氧化和脱羧连续生产苯酚，随后中间体反应混合物从氧化和脱羧步骤水解，其中来自氧化和脱羧步骤的中间反应混合物 与蒸汽和足够量的分子氧一起加入水解区，由此通过将铜保持在二价氧化态，在水解步骤期间将反应混合物中的铜保持在溶液中。

公开(公告)号：US3925512A

公开(公告)日：1975-12-09

申请号：US24223472

申请日：1972-04-07

Applicant: STAMICARBON

Inventor： ROEST BERNARD C ,  SCHEPERS HERMAN A J

IPC: C08F297/04 ,  C08L9/06 ,  C08L25/10 ,  C08L25/16

CPC classification number: C08F297/046

Abstract: A process for preparing block copolymers is disclosed, wherein a living polymer of a diene is formed which carries at least one negatively charged diene unit in the end position, from 1 to 100 monomer units of styrene or a ring-substituted styrene derivative is polymerized on each living polymer anion site, and then a polymer block of Alpha -methylstyrene units is formed by polymerization of Alpha -methylstyrene. The cross-over reaction from the polymer block having the dienyl anion in the end position to the Alpha -methylstyrene is facilitated by the presence of the styrene or styrene derivative. The block copolymers can be employed for numerous applications wherein synthetic rubber is used, such as in bicycle tires, footwear, flooring, adhesives, coatings and elastomeric fibers.

Abstract translation: 公开了制备嵌段共聚物的方法，其中形成二烯的活性聚合物，其在末端位置带有至少一个带负电荷的二烯单元，苯乙烯的1至100个单体单元或环取代的苯乙烯衍生物在 每个活性聚合物阴离子部位，然后通过α-甲基苯乙烯的聚合形成α-甲基苯乙烯单元的聚合物嵌段。 苯乙烯或苯乙烯衍生物的存在促进了从末端位置具有二烯阴离子的聚合物嵌段到α-甲基苯乙烯的交叉反应。

公开(公告)号：US3925422A

公开(公告)日：1975-12-09

申请号：US33624373

申请日：1973-02-27

Applicant: STAMICARBON

Inventor： SCHAAFSMA SIJBRANDUS E ,  DEUMENS JOHANNES J M

IPC: C07D311/74

CPC classification number: C07D311/74

Abstract: A process for preparing 3,4,5,6,7,8-hexahydrocoumarin is disclosed, wherein 2-( Beta -carboxyethyl)-cyclohexanone is heated in the presence of catalytic amount of a strong acid having a atmospheric boiling point above 200*C at a temperature of 140*-245*C and a pressure of 6-200 mm Hg. The hexahydrocoumarin product may be dehydrogenated to form dihydrocoumarin which is used in the perfume industry.

Abstract translation: 公开了一种制备3,4,5,6,7,8-六氢香豆素的方法，其中2-（β-羧乙基） - 环己酮在催化量的常压沸点高于200℃的强酸存在下被加热 温度为140〜-245℃，压力为6〜200mmHg。