MOISTURE CURABLE ORGANOPOLYSILOXANE COMPOSITION
    329.
    发明申请
    MOISTURE CURABLE ORGANOPOLYSILOXANE COMPOSITION 审中-公开
    水分可固化有机硅氧烷组合物

    公开(公告)号:US20150094421A1

    公开(公告)日:2015-04-02

    申请号:US14398191

    申请日:2013-03-07

    Abstract: The present invention provides curable compositions comprising non-tin metal catalysts that accelerate the condensation curing of moisture-curable silicones/non-silicones. In particular, the present composition employs a catalyst system comprising an (alkyl)acrylic acid, a salt of an (alkyl)acrylic acid, or a mixture of two or more thereof. The (alkyl)acrylic acids or their salts exhibit catalytic activity comparable or superior to organotin such as dibutyltin dilaurate (DBTDL) and exhibit certain behavior in the presence of components such as adhesion promoters that allow for tuning or adjusting the cure characteristics of the present compositions and provide good adhesion and storage stability.

    Abstract translation: 本发明提供包含非锡金属催化剂的可固化组合物,其加速湿气固化的硅酮/非硅氧烷的缩合固化。 特别地,本发明的组合物使用包含(烷基)丙烯酸,(烷基)丙烯酸的盐或其两种或更多种的混合物的催化剂体系。 (烷基)丙烯酸或其盐显示出与有机锡相当或优于例如二月桂酸二丁基锡(DBTDL)的催化活性,并且在存在可允许调节或调节本发明组合物的固化特性的组分如粘合促进剂存在下表现出某些行为 并提供良好的附着力和储存稳定性。

    SLURRY PHASE DIRECT SYNTHESIS OF ORGANOHALOSILANES FROM CYCLONE FINES
    330.
    发明申请
    SLURRY PHASE DIRECT SYNTHESIS OF ORGANOHALOSILANES FROM CYCLONE FINES 有权
    从CYCLONE FINES的浆液相直接合成有机硅烷

    公开(公告)号:US20150065740A1

    公开(公告)日:2015-03-05

    申请号:US14471625

    申请日:2014-08-28

    CPC classification number: C07F7/16 C07F7/12

    Abstract: The present invention is directed to a process for the synthesis of organohalosilane monomers, comprising the steps of (1) forming a slurry of cyclone fines, ultra fines and/or spent contact mass in a thermally stable solvent and reacting the agitated slurry with an organohalide of the formula R1X in the presence of an additive for a time and at a temperature sufficient to produce organohalosilane monomers having the formulae R1SiHX2, R12SiHX, R13SiX, R1SiX3, and R12SiX2; wherein R1 is a saturated or unsaturated aromatic group, a saturated or unsaturated aliphatic group, alkaryl group, or cycloaliphatic hydrocarbyl group, and X is a halogen; and (2) recovering said organohalosilane monomers.

    Abstract translation: 本发明涉及一种合成有机卤代硅烷单体的方法,其包括以下步骤:(1)在热稳定溶剂中形成旋风细粉,超细粉和/或废接触物料的浆料,并将搅拌的浆料与有机卤化物 在存在添加剂一段时间的条件下,并且在足以产生具有式R1SiHX2,R12SiHX,R13SiX,R1SiX3和R12SiX2的有机卤代硅烷单体的温度下, 其中R1是饱和或不饱和的芳族基团,饱和或不饱和脂族基团,烷芳基或脂环族烃基,X是卤素; 和(2)回收所述有机卤代硅烷单体。

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