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43 条记录 (耗时 0.035 秒)

    Organoborane amine complex polymerization initiators and polymerizable compositions
    31.
    发明授权
    Organoborane amine complex polymerization initiators and polymerizable compositions 失效
    有机硼烷胺络合物聚合引发剂和可聚合组合物

    公开(公告)号：US06762260B2

    公开(公告)日：2004-07-13

    申请号：US10095326

    申请日：2002-03-05

    申请人： Mark F. Sonnenschein ,  Steven P. Webb ,  Benjamin L. Wendt ,  Daniel D. Harrington

    发明人： Mark F. Sonnenschein ,  Steven P. Webb ,  Benjamin L. Wendt ,  Daniel D. Harrington

    IPC分类号： C08G452

    CPC分类号： C08G61/12 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31928 ,  Y10T428/31935

    摘要： The invention is a two part polymerizable composition comprising in one part an organoborane amine complex and one or more compounds containing ring opening heterocyclic moieties, and in a second part, compounds capable of being polymerized by free radical polymerization, a catalyst capable of polymerizing compounds containing ring opening heterocyclic moieties and optionally a component that will decomplex the organoborane amine complex. In one embodiment the invention is a two phase system comprising a first phase containing one or more polymers prepared from the compounds which polymerize by free radical polymerization and a second phase comprising polymerized or partially polymerized compounds derived from one or more compounds containing ring opening heterocyclic moieties. In one embodiment the polymer prepared from compounds containing heterocyclic ring opening moieties is not miscible with the polymer prepared by free radical polymerization and thus the resulting polymerized composition has at least two regions each rich in one of the two polymers formed. In another embodiment the polymerizable compositions of the invention can be formulated into adhesive compositions. Adhesive compositions of the present formulation provide excellent adhesion to low surface energy plastics from room temperature to temperatures over 125° C.

    摘要翻译： 本发明是两部分可聚合组合物，其一部分包含有机硼烷胺络合物和一种或多种含开环杂环部分的化合物，第二部分是能够通过自由基聚合聚合的化合物，能够聚合含有 开环杂环部分和任选的将使有机硼烷胺络合物分解的组分。 在一个实施方案中，本发明是两相体系，其包含第一相，其含有由通过自由基聚合聚合的化合物制备的一种或多种聚合物，第二相包含衍生自一种或多种含有开环杂环部分的化合物的聚合或部分聚合的化合物 。 在一个实施方案中，由含有杂环开环部分的化合物制备的聚合物与通过自由基聚合制备的聚合物不混溶，因此所得的聚合组合物具有至少两个各自富含形成的两种聚合物之一的区域。 在另一个实施方案中，本发明的可聚合组合物可以配制成粘合剂组合物。 本发明配方的粘合剂组合物对室温至125℃以上的低表面能塑料提供优异的附着力。

    Amine organoborane complex polymerization initiators and polymerizable compositions
    32.
    发明授权
    Amine organoborane complex polymerization initiators and polymerizable compositions 有权
    胺有机硼烷络合物聚合引发剂和可聚合组合物

    公开(公告)号：US06730759B2

    公开(公告)日：2004-05-04

    申请号：US09881980

    申请日：2001-06-15

    申请人： Mark F. Sonnenschein ,  Steven P. Webb ,  Nelson G. Rondan

    发明人： Mark F. Sonnenschein ,  Steven P. Webb ,  Nelson G. Rondan

    IPC分类号： C08F452

    CPC分类号： C08F4/52 ,  C07F5/027 ,  C09J4/06 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31909 ,  C08F265/06

    摘要： The invention is polymerizable composition comprising a) an organoborane/amine complex wherein the organoborane is a trialkyl borane or an alkyl cycloalkyl borane and the amine is selected from the group of amines having an amidine structural component; aliphatic heterocycles having at least one nitrogen in the heterocyclic ring; an alicyclic compound having bound to the ring a substituent having an amine moiety; primary amines which in addition to a primary amine have one or more hydrogen bond accepting groups of an ether, polyether, thioether or halogen wherein there is an alkylene chain of at least two carbon atoms between the primary amine and the hydrogen bond accepting group, and conjugated imines; and, b) one or more of monomers, oligomers or polymers having olefinic unsaturation; and optionally c) an effective amount of a compound which causes the complex to disassociate wherein the compound which causes disassociation of the complex is kept separate from the complex until initiation of polymerization is desired.

    摘要翻译： 本发明是包含a）有机硼烷/胺络合物的可聚合组合物，其中有机硼烷是三烷基硼烷或烷基环烷基硼烷，并且胺选自具有脒结构组分的胺; 在杂环中具有至少一个氮的脂族杂环; 与环结合的具有胺部分的取代基的脂环化合物; 除伯胺之外的伯胺具有一个或多个醚，聚醚，硫醚或卤素的氢键接受基团，其中在伯胺和氢键接受基团之间存在至少两个碳原子的亚烷基链，以及 共轭亚胺 和b）一种或多种具有烯属不饱和键的单体，低聚物或聚合物; 和任选地c）有效量的使络合物解离的化合物，其中使需要使复合物分解的化合物与络合物分离直到聚合开始。

    Immediate write, read, and erase optical storage medium and method of marking and erasing
    34.
    发明授权
    Immediate write, read, and erase optical storage medium and method of marking and erasing 失效
    立即写入，读取和擦除光存储介质和标记和擦除方法

    公开(公告)号：US4975358A

    公开(公告)日：1990-12-04

    申请号：US422723

    申请日：1989-10-17

    申请人： Mark F. Sonnenschein ,  Charles M. Roland

    发明人： Mark F. Sonnenschein ,  Charles M. Roland

    IPC分类号： G11B7/245 ,  G11B7/253 ,  G11B7/254

    CPC分类号： G11B7/253 ,  G11B7/245 ,  G11B7/254 ,  Y10S430/146

    摘要： An optical data storage medium comprises a substrate layer, a recording medium and an optional protective layer. The substrate layer supports the recording medium. The recording medium comprises a polymer having stable amorphous and crystalline states under human operating conditions which states have different optical properties. The recording medium is optionally covered and protected by a protective layer. The substrate, recording medium and protective layer can be formed from the same or different polymers. The data is stored by exposing the recording medium to patterned infra-red radiation. The radiation can be patterned by a mask, movement of the radiation beam or by other means to imprint the data on the recording medium.

    摘要翻译： 光学数据存储介质包括基底层，记录介质和任选的保护层。 基底层支撑记录介质。 记录介质包括在人类操作条件下具有稳定的非晶态和结晶状态的聚合物，其状态具有不同的光学性质。 记录介质任选被保护层覆盖和保护。 基材，记录介质和保护层可以由相同或不同的聚合物形成。 通过将记录介质暴露于图案化的红外辐射来存储数据。 可以通过掩模，辐射束的移动或通过其他方式将辐射图案化以将数据压印在记录介质上。

    Thermoplastic polyurethane containing structural units of polyester and polyether diols
    36.
    发明授权
    Thermoplastic polyurethane containing structural units of polyester and polyether diols 有权
    含聚酯和聚醚二醇结构单元的热塑性聚氨酯

    公开(公告)号：US08296974B2

    公开(公告)日：2012-10-30

    申请号：US11991832

    申请日：2006-09-22

    申请人： Mark F. Sonnenschein ,  J. Mark Cox ,  Hanno R. Van der Wal ,  Benjamin L. Wendt

    发明人： Mark F. Sonnenschein ,  J. Mark Cox ,  Hanno R. Van der Wal ,  Benjamin L. Wendt

    IPC分类号： A43B5/04 ,  C08G18/00

    CPC分类号： C08G18/4837 ,  C08G18/10 ,  C08G18/4018 ,  C08G18/664 ,  C08G18/6674 ,  C08G18/3206

    摘要： The present invention is a transparent thermoplastic polyurethane (TPU) comprising structural units of: a.) a diisocyanate; b.1) a polyester diol and b.2) a specific polyether diol and c.) a chain extender. The TPU has good combinations of light transmission and clarity, tensile strength, low temperature flexibility, and high moisture vapor transition rates compared to other commercial or known TPUs. A preferred example composition is a TPU that is based on MDI as the diisocyanate monomer, polycaprolactone as a polyester diol, an EO capped EO/PO polyether diol containing less than 20% EO, and butanediol as chain extender. These composition have good combinations of clarity, tensile strength, hydrolytic stability and processability compared to TPUs prepared using either polyester or polyether diols alone or the combination with a higher EO polyether diol.

    摘要翻译： 本发明是一种透明热塑性聚氨酯（TPU），其包含以下结构单元：a。）二异氰酸酯; b.1）聚酯二醇和b.2）特定的聚醚二醇和c。）扩链剂。 与其他商业或已知的TPU相比，TPU具有良好的透光性和透明度，拉伸强度，低温柔韧性和高水蒸汽转变速率的组合。 优选的实施例组合物是基于MDI作为二异氰酸酯单体的TPU，作为聚酯二醇的聚己内酯，含有少于20％EO的EO封端的EO / PO聚醚二醇和作为扩链剂的丁二醇。 与单独使用聚酯或聚醚二醇或与较高EO聚醚二醇的组合制备的TPU相比，这些组合物具有良好的透明度，拉伸强度，水解稳定性和加工性能的组合。

    Organoborane amine complex polymerization initiators and polymerizable compositions
    37.
    发明授权
    Organoborane amine complex polymerization initiators and polymerizable compositions 失效
    有机硼烷胺络合物聚合引发剂和可聚合组合物

    公开(公告)号：US07235617B2

    公开(公告)日：2007-06-26

    申请号：US10827671

    申请日：2004-04-19

    申请人： Steven P. Webb ,  Mark F. Sonnenschein

    发明人： Steven P. Webb ,  Mark F. Sonnenschein

    IPC分类号： C08F4/52

    CPC分类号： C08G18/3268 ,  C08G18/8038 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31913

    摘要： The invention is a two part composition useful for initiating cure of one or more polymerizable monomers which cure when exposed to free radicals comprising in one part an organoboraneamine complex and in a second part an isocyanate which is capable of decomplexing the organoborane complex wherein the ratio of amine nitrogen atoms to boron atoms is greater than 4.0:1.0. In another embodiment the invention is a two part polymerizable composition comprising part 1, a) an organoborane amine complex; and part 2, b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization c) an effective amount of a compound which causes the complex to disassociate thereby freeing the borane to initiate polymerization of the one or more monomers, oligomers or polymers having olefinic unsaturation wherein the compound which causes disassociation of the complex is kept separate from the complex until initiation of polymerization is desired; and d) a material which manages the heat of the polymerization reaction such that adhesion to the substrate is maintained, which material can be located in either part 1, part 2 or both parts.

    摘要翻译： 本发明是用于引发一种或多种可聚合单体的起始固化的两部分组合物，其当暴露于包含一部分有机硼烷胺络合物的自由基时固化，在第二部分中是能够使有机硼烷络合物分解的异氰酸酯，其中， 胺氮原子与硼原子的比例大于4.0：1.0。 在另一个实施方案中，本发明是两部分可聚合组合物，其包含部分1，a）有机硼烷胺络合物; 和第2部分，b）一种或多种具有烯属不饱和键的单体，低聚物或聚合物，其能够通过自由基聚合进行聚合; c）有效量的化合物，其导致络合物脱离，从而释放硼烷以引发 一种或多种具有烯属不饱和键的单体，低聚物或聚合物，其中引起复合物分解的化合物与络合物分离直到需要聚合开始; 和d）管理聚合反应的热量的材料，使得保持对基材的粘附，哪种材料可以位于部分1，部分2或两部分中。

    Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components
    38.
    发明授权
    Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components 有权
    胺有机硼烷络合物引发含有硅氧烷可聚合组分的可聚合组合物

    公开(公告)号：US07157399B2

    公开(公告)日：2007-01-02

    申请号：US10864668

    申请日：2004-06-09

    申请人： Mark F. Sonnenschein ,  Steven P. Webb ,  Benjamin L. Wendt ,  Daniel R. Harrington

    发明人： Mark F. Sonnenschein ,  Steven P. Webb ,  Benjamin L. Wendt ,  Daniel R. Harrington

    IPC分类号： B01J31/00 ,  C08F5/02

    CPC分类号： C08L83/04 ,  C08G77/00 ,  C08G77/045 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/20 ,  C08K5/55 ,  C09J4/00 ,  C08L83/00

    摘要： In one embodiment the invention is a polymerizable composition comprising a) an organoborane amine complex; b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization; c) one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization; and d) a catalyst for the polymerization of the one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization. This composition may further comprise a compound which causes the organoborane amine complex to disassociate. In a preferred embodiment, the two part composition further comprises a compound which is reactive with both the b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization; and the c) one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization. This composition can be polymerized by contacting the two parts of the composition. In another embodiment the invention is an organoborane amine complex comprising an alkyl borane having ligands which are alkyl, cycloalkyl or both and an amino siloxane.

    摘要翻译： 在一个实施方案中，本发明是一种可聚合组合物，其包含a）有机硼烷胺络合物; b）一种或多种能够通过自由基聚合聚合的具有烯属不饱和键的单体，低聚物或聚合物; c）一种或多种具有硅氧烷主链和能聚合的反应性部分的化合物，低聚物或预聚物; 和d）用于聚合具有硅氧烷骨架的一种或多种化合物，低聚物或预聚物和能聚合的反应性部分的催化剂。 该组合物还可以包含使有机硼烷胺络合物脱离的化合物。 在优选的实施方案中，两部分组合物还包含与b）一种或多种具有烯属不饱和键的能够通过自由基聚合聚合的单体，低聚物或聚合物反应的化合物; 和c）一种或多种具有硅氧烷主链和能聚合的反应性部分的化合物，低聚物或预聚物。 该组合物可以通过使组合物的两个部分接触来聚合。 在另一个实施方案中，本发明是一种有机硼烷胺络合物，其包含具有烷基，环烷基或两者的氨基硅氧烷的配体的烷基硼烷。