摘要:
The mutual condensation of aromatic and carbonylic compounds is carried out with zeolitic materials derived from silicalite by replacing a portion of silicon with B and Al, Al and Ti, Ti and Fe, and with ZSM-5, to yield diaryl-alkanes.
摘要:
Process for the removal in continuous of hydrogen sulfide from gaseous streams containing it, comprising: a) putting a gas containing H2S in contact with an oxidizing acid aqueous solution of ferric nitrate and containing a heteropolyacid having redox properties; b) filtrating and separating the sulfur produced by the redox reaction; c) oxidizing the ferrous nitrate to ferric nitrate with air; d) recycling the solution containing ferric nitrate and heteropolyacid to the oxidation step (a); e) subjecting the gaseous stream leaving the oxidation reactor (c) to washing with the reduced solution; and f) discharging the gaseous stream.
摘要:
Process for the removal in continuous of hydrogen sulfide from gaseous streams containing it, comprising: a) putting a gas containing H2S in contact with an oxidizing acid aqueous solution of ferric nitrate and containing a heteropolyacid having redox properties; b) filtrating and separating the sulfur produced by the redox reaction; c) oxidizing the ferrous nitrate to ferric nitrate with air; d) recycling the solution containing ferric nitrate and heteropolyacid to the oxidation step (a); e) subjecting the gaseous stream leaving the oxidation reactor (c) to washing with the reduced solution; and f) discharging the gaseous stream.
摘要:
A highly selective process is described for preparing 2,6-dimethylnaphthalene which comprises reacting a naphthalene hydrocarbon selected from naphthalene, methylnaphthalenes, dimethylnaphthalenes, trimethylnaphthalenes, polymethylnaphthalenes, and/or their mixtures with one or more benzene hydrocarbons selected from benzene, toluene, xylenes, trimethylbenzenes, tetramethylbenzenes, pentamethylbenzene and/or hexamethylbenzene, under at least partially liquid phase conditions and in the presence of a catalytic composition comprising a zeolite belonging to the MTW structural type and at least one element selected from P, B and Si. The process is preferably carried out in the presence of a methylating agent.
摘要:
A supported cobalt-based catalyst, characterized in that the carrier has an average particle diameter, measured by Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured by the B.E.T. method. The catalyst is particularly useful in the Fischer-Tropsch reaction.
摘要:
A supported cobalt-based catalyst characterized in that the carrier has an average particle diameter, measured by means of Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured with the B.E.T. method. The catalyst is useful in the Fischer-Tropsch reaction.
摘要:
The present invention relates to a process for the catalytic reduction of nitrogen oxides contained in exhaust gases from combustion, which process comprises bringing said exhaust gases into contact with a Beta Zeolite exchanged with suitable amounts of cobalt salts, in the presence of a light hydrocarbon as the reducing agent. The present invention relates also to a catalyst for such a process, which catalyst comprises a Beta Zeolite exchanged with cobalt salts, characterized by a Co:zeolite Al molar ratio of
摘要:
A porous, crystalline material, designated ERS-10 zeolite, having in its calcined and anhydrous form a molecular composition of oxides corresponding to the formula (I):mM.sub.2/n O.zX.sub.2 O.sub.3.YO.sub.2 (1)wherein m, n, M, z, X and Y are as defined herein, the crystalline material having an X-ray diffraction spectrum shown in Table 1 herein.
摘要:
A catalyst, which is active in the oligomerization of olefins is an X-ray-amorphous silica-alumina-nickel oxide gel having an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of from 30/1 to 500/1, and NiO/SiO.sub.2 molar ratio of from 0.001/1 to 0.01/1, a superficial area of from 500 m.sup.2 /g to 1.000 m.sup.2 /g, and a porosity of from 0.3 ml/g to 0.6 ml/g, the means pore diameter being 1 nm (10 Angstrom), and devoid of pores having a diameter over 3 nm (30 Angstrom). The catalyst selectively dimerizes isobutene into alpha- and beta-isobutene and oligomerizes propylene into its relative dimers and trimers. A process is described for preparing the silica-alumina-nickel oxide gel.
摘要:
An improved process for preparing a difunctional catalyst active, in the hydroisomerization of long-chain normal paraffins is disclosed, which is constituted by an amorphous silica-alumina gel and one or more metals belonging to Group VIIIIA.