Process for the preparation of 4,4'-diaminodiphenyl-methane and its
derivatives
    32.
    发明授权
    Process for the preparation of 4,4'-diaminodiphenyl-methane and its derivatives 失效
    4,4'-二氨基二苯基甲烷及其衍生物的制备方法

    公开(公告)号:US5241119A

    公开(公告)日:1993-08-31

    申请号:US595665

    申请日:1990-10-11

    IPC分类号: B01J29/04

    CPC分类号: B01J29/04 Y02P20/582

    摘要: Process for the preparation of 4,4'-diaminodiphenylmethane and its derivatives.4,4'-diaminodiphenylmethane and its derivatives are prepared by the condensation of aniline, or its derivative, and aldehyde, or its precursor and/or isomerization of appropriate intermediate products. The reaction proceeds with zeolites acting as catalysts; these catalysts, which are selected in accordance with the reaction to be effected, are preferably zeolites based on Si, Al and B; Si, Al and Ti; Ti and Fe; ZSM-5; or Y zeolites.

    摘要翻译: 制备4,4'-二氨基二苯甲烷及其衍生物的方法。 4,4'-二氨基二苯基甲烷及其衍生物通过苯胺或其衍生物与醛或其前体的缩合和/或合适的中间产物的异构化来制备。 反应进行作为催化剂的沸石; 根据要进行的反应选择的这些催化剂优选基于Si,Al和B的沸石; Si,Al和Ti; Ti和Fe; ZSM-5; 或Y沸石。

    Process for the continuous removal of hydrogen sulfide from gaseous streams
    35.
    发明授权
    Process for the continuous removal of hydrogen sulfide from gaseous streams 失效
    从气流中连续除去硫化氢的工艺

    公开(公告)号:US07608231B2

    公开(公告)日:2009-10-27

    申请号:US12065909

    申请日:2006-08-31

    IPC分类号: B01D53/48 C01B17/16 C01B17/04

    摘要: Process for the removal in continuous of hydrogen sulfide from gaseous streams containing it, comprising: a) putting a gas containing H2S in contact with an oxidizing acid aqueous solution of ferric nitrate and containing a heteropolyacid having redox properties; b) filtrating and separating the sulfur produced by the redox reaction; c) oxidizing the ferrous nitrate to ferric nitrate with air; d) recycling the solution containing ferric nitrate and heteropolyacid to the oxidation step (a); e) subjecting the gaseous stream leaving the oxidation reactor (c) to washing with the reduced solution; and f) discharging the gaseous stream.

    摘要翻译: 用于从含有它的气流中连续除去硫化氢的方法,包括:a)将含有H 2 S的气体与硝酸铁的氧化酸性水溶液接触并含有具有氧化还原性质的杂多酸; b)过滤和分离由氧化还原反应产生的硫; c)用空气将硝酸亚铁氧化成硝酸铁; d)将含有硝酸铁和杂多酸的溶液循环到氧化步骤(a)中; e)使离开氧化反应器(c)的气流经还原溶液洗涤; 和f)排出气流。

    Process for the Removal in Continuous of Hydrogen Sulfide From Gaseous Streams
    36.
    发明申请
    Process for the Removal in Continuous of Hydrogen Sulfide From Gaseous Streams 失效
    从气态物流中连续除去硫化氢的方法

    公开(公告)号:US20080299026A1

    公开(公告)日:2008-12-04

    申请号:US12065909

    申请日:2006-08-31

    IPC分类号: B01D53/52

    摘要: Process for the removal in continuous of hydrogen sulfide from gaseous streams containing it, comprising: a) putting a gas containing H2S in contact with an oxidizing acid aqueous solution of ferric nitrate and containing a heteropolyacid having redox properties; b) filtrating and separating the sulfur produced by the redox reaction; c) oxidizing the ferrous nitrate to ferric nitrate with air; d) recycling the solution containing ferric nitrate and heteropolyacid to the oxidation step (a); e) subjecting the gaseous stream leaving the oxidation reactor (c) to washing with the reduced solution; and f) discharging the gaseous stream.

    摘要翻译: 用于从含有它的气流中连续除去硫化氢的方法,包括:a)将含有H 2 S的气体与硝酸铁的氧化酸性水溶液接触并含有具有氧化还原性质的杂多酸; b)过滤和分离由氧化还原反应产生的硫; c)用空气将硝酸亚铁氧化成硝酸铁; d)将含有硝酸铁和杂多酸的溶液循环到氧化步骤(a)中; e)使离开氧化反应器(c)的气流经还原溶液洗涤; 和f)排出气流。

    Process for the preparation of 2,6-dimethylnaphthalene
    37.
    发明授权
    Process for the preparation of 2,6-dimethylnaphthalene 失效
    2,6-二甲基萘的制备方法

    公开(公告)号:US07241931B2

    公开(公告)日:2007-07-10

    申请号:US11333201

    申请日:2006-01-18

    IPC分类号: C07C5/22 C07C5/27

    摘要: A highly selective process is described for preparing 2,6-dimethylnaphthalene which comprises reacting a naphthalene hydrocarbon selected from naphthalene, methylnaphthalenes, dimethylnaphthalenes, trimethylnaphthalenes, polymethylnaphthalenes, and/or their mixtures with one or more benzene hydrocarbons selected from benzene, toluene, xylenes, trimethylbenzenes, tetramethylbenzenes, pentamethylbenzene and/or hexamethylbenzene, under at least partially liquid phase conditions and in the presence of a catalytic composition comprising a zeolite belonging to the MTW structural type and at least one element selected from P, B and Si. The process is preferably carried out in the presence of a methylating agent.

    摘要翻译: 描述了用于制备2,6-二甲基萘的高选择性方法,其包括将选自萘,甲基萘,二甲基萘,三甲基萘,聚甲基萘和/或其混合物的萘烃与一种或多种选自苯,甲苯,二甲苯, 三甲基苯,四甲基苯,五甲基苯和/或六甲基苯,在至少部分液相条件下和在包含属于MTW结构类型的沸石和选自P,B和Si中的至少一种元素的催化组合物存在下进行。 该方法优选在甲基化剂的存在下进行。