公开(公告)号：US06790904B2

公开(公告)日：2004-09-14

申请号：US10160888

申请日：2002-06-03

申请人： Daniela White ,  James B. O'Dwyer ,  Michael A. Mayo ,  Laura E. Poindexter ,  John R. Schneider ,  Michael L. White ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Joseph M. Carney ,  Lawrence G. Anderson ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Daniela White ,  James B. O'Dwyer ,  Michael A. Mayo ,  Laura E. Poindexter ,  John R. Schneider ,  Michael L. White ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Joseph M. Carney ,  Lawrence G. Anderson ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： C08K322

CPC分类号： C09D7/69 ,  C08K3/22 ,  C08K3/28 ,  C08K3/36 ,  C08K9/06 ,  C09D7/62 ,  C09D7/67 ,  C09D7/68 ,  Y10T428/31511

摘要： Liquid coating compositions having improved mar and scratch resistance are disclosed. The coatings generally comprise one or more particles that have been modified to render the particles more surface active. The improved resistance is achieved without affecting the appearance or mechanical performance of the coatings. Methods for using the coatings, and the substrates coated therewith, are also disclosed.

摘要翻译： 公开了具有改善的耐擦伤和耐划伤性的液体涂料组合物。 涂料通常包含一种或多种已被改性以使颗粒更具表面活性的颗粒。 在不影响涂层的外观或机械性能的情况下实现改进的电阻。 还公开了使用涂层的方法及其涂覆的基材。

公开(公告)号：US06759478B2

公开(公告)日：2004-07-06

申请号：US10456552

申请日：2003-06-09

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06610777B1

公开(公告)日：2003-08-26

申请号：US09629420

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/62 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04 ,  C08L2666/28

摘要： Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

摘要翻译： 提供涂料组合物，其包括包含至少一个反应性官能团的聚硅氧烷和至少一种包含至少一个反应性官能团的材料。 还提供了由从着色涂料组合物沉积的底涂层和涂覆在底涂层上的顶涂层，由上述涂料组合物沉积的面漆形成的多层复合涂层。 还提供了一种用于改善涂覆基材的耐擦伤性的方法以及涂覆的基材。 本发明的组合物提供高度耐刮擦的涂层，特别是高度耐刮擦的彩色 - 透明涂层。

公开(公告)号：US06593417B1

公开(公告)日：2003-07-15

申请号：US09629443

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06541119B2

公开(公告)日：2003-04-01

申请号：US09844535

申请日：2001-04-27

申请人： Richard J. Sadvary ,  Lawrence G. Anderson ,  Dennis A. Simpson ,  Thomas R. Hockswender ,  Masayuki Nakajima ,  Truman F. Wilt

发明人： Richard J. Sadvary ,  Lawrence G. Anderson ,  Dennis A. Simpson ,  Thomas R. Hockswender ,  Masayuki Nakajima ,  Truman F. Wilt

IPC分类号： B32B2728

CPC分类号： C09D183/08 ,  C08G77/388 ,  C08L63/00 ,  C08L67/02 ,  C08L83/04 ,  C09D5/448 ,  C09D133/066 ,  C09D183/06 ,  Y10T428/31663 ,  C08L2666/14 ,  C08L2666/04 ,  C08L2666/36 ,  C08L2666/34

摘要： Multi-component composite coating compositions are provided which comprise a base coat deposited from a pigmented film-forming composition and a transparent top coat applied over the base coat in which the transparent top coat is deposited from a film-forming composition comprising one ore more ungelled chain-extended organic polysiloxanes having reactive functional groups, and one or more curing agents having functional groups reactive with the functional groups of the polysiloxane. Additionally provided is a process for applying the multi-component composite coatings described above to a substrate. Substrates coated with the above-described multi-component composite coating compositions are also provided.

摘要翻译： 提供了多组分复合涂料组合物，其包含从着色成膜组合物沉积的底涂层和施加在底涂层上的透明顶涂层，其中透明顶涂层由成膜组合物沉积，所述成膜组合物包含一个或多个未凝胶 具有反应性官能团的链延伸的有机聚硅氧烷，以及具有与聚硅氧烷的官能团反应的官能团的一种或多种固化剂。 另外提供了将上述多组分复合涂层应用于基材的方法。 还提供了涂覆有上述多组分复合涂料组合物的基材。

公开(公告)号：US20090286978A1

公开(公告)日：2009-11-19

申请号：US12120725

申请日：2008-05-15

申请人： Britt A. Minch ,  Charles R. Hickenboth ,  Richard F. Karabin ,  Steven R. Zawacky ,  Thomas R. Hockswender ,  Gregory J. McCollum

发明人： Britt A. Minch ,  Charles R. Hickenboth ,  Richard F. Karabin ,  Steven R. Zawacky ,  Thomas R. Hockswender ,  Gregory J. McCollum

IPC分类号： C07D253/08

CPC分类号： C07D487/04

摘要： The present invention is directed to a method producing bicyclic guanidine comprising heating a cyclic thiourea to a temperature ranging from ≧140° C. in a substantially non-hydrocarbon solvent to form the bicyclic guanidine.

摘要翻译： 本发明涉及一种产生双环胍的方法，其包括在基本上非烃溶剂中加热环状硫脲至> 140℃的温度以形成双环胍。

公开(公告)号：US07053149B2

公开(公告)日：2006-05-30

申请号：US10795216

申请日：2004-03-09

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04

摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种包含至少一种与聚硅氧烷（a）的任何反应性官能团反应的官能团的固化剂。 另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。 还提供了制备涂料组合物的方法。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06592999B1

公开(公告)日：2003-07-15

申请号：US09919200

申请日：2001-07-31

申请人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： B32B904

CPC分类号： B05D7/57 ,  B05D7/574 ,  C08J5/12 ,  C08K3/38 ,  C08K5/55 ,  C09D7/60 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

摘要： The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

公开(公告)号：US4029621A

公开(公告)日：1977-06-14

申请号：US680935

申请日：1976-04-28

申请人： Marvis E. Hartman ,  Thomas R. Hockswender ,  Rostyslaw Dowbenko ,  Roger M. Christenson

发明人： Marvis E. Hartman ,  Thomas R. Hockswender ,  Rostyslaw Dowbenko ,  Roger M. Christenson

IPC分类号： C08G59/14 ,  C08G59/42 ,  C08G59/66 ,  C08G59/16

CPC分类号： C08G59/66 ,  C08G59/1483 ,  C08G59/4207

摘要： Aqueous coating compositions which may be applied by conventional coating techniques as well as by electrodeposition are provided by reacting an epoxy-containing organic material with a compound containing a mercaptan group and at least one group hydrolyzable to a carboxyl group. Examples of such hydrolyzable groups include ester groups, amide groups and nitrile groups. The resultant product is then hydrolyzed and solubilized using hydrolyzing agents such as aqueous alkali metal hydroxides and aqueous solutions of various amines.

摘要翻译： 可以通过常规涂布技术和电沉积施用的水性涂料组合物通过使含环氧基的有机材料与含有硫醇基团的化合物和至少一个可水解成羧基的基团反应来提供。 这些可水解基团的实例包括酯基，酰胺基和腈基。 然后使用水解剂如碱金属氢氧化物水溶液和各种胺的水溶液将所得产物水解和溶解。

公开(公告)号：US20100003493A1

公开(公告)日：2010-01-07

申请号：US12507192

申请日：2009-07-22

申请人： Shan Cheng ,  Thomas R. Hockswender

发明人： Shan Cheng ,  Thomas R. Hockswender

IPC分类号： B32B27/40 ,  B05D3/06 ,  C08K5/09

CPC分类号： C08F283/00 ,  C08F220/36 ,  C08F222/1006 ,  C08F230/08 ,  C08F283/006 ,  C08F290/00 ,  C08F290/06 ,  C08F290/061 ,  C08F299/00 ,  C08K3/36 ,  C09D4/00 ,  C09D7/61 ,  C09D7/67 ,  C09D133/14 ,  C09D175/16 ,  Y10T428/264 ,  Y10T428/31551

摘要： Radiation curable coating compositions are disclosed. The radiation curable coating composition comprises a) an organic film-forming binder comprising (i) a urethane (meth)acrylate comprising the reaction product of reactants comprising a polyol and a polyisocyanate comprising at least two (meth)acrylate functional groups per molecule; and (ii) a highly functional (meth)acrylate; and b) a (meth)acrylate functional silsesquioxane dispersed in the binder. Also disclosed are related methods for coating a substrate, coated substrates and cured coatings formed from the radiation curable coating compositions.

摘要翻译： 公开了可辐射固化涂料组合物。 所述可辐射固化涂料组合物包含a）有机成膜粘合剂，其包含（i）包含每分子包含至少两个（甲基）丙烯酸酯官能团的多元醇和多异氰酸酯的反应物的反应产物的氨基甲酸酯（甲基）丙烯酸酯; 和（ii）高官能度（甲基）丙烯酸酯; 和b）分散在粘合剂中的（甲基）丙烯酸酯官能的倍半硅氧烷。 还公开了用于涂覆基材，涂布的基材和由可辐射固化涂料组合物形成的固化涂层的相关方法。