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公开(公告)号：US09090835B2
公开(公告)日：2015-07-28
申请号：US13601160
申请日：2012-08-31
CPC分类号： C10G69/06
摘要： The invention relates to upgraded pyrolysis products, hydroconversion processes for upgrading products obtained from hydrocarbon pyrolysis, equipment useful for such processes. In particular the invention provides methods for reducing coke fouling in such equipment.
摘要翻译： 本发明涉及升级的热解产物，用于升级由烃热解获得的产物的加氢转化方法，用于这种方法的设备。 具体地，本发明提供了用于减少这种设备中的焦炭结垢的方法。
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公开(公告)号：US08586809B2
公开(公告)日：2013-11-19
申请号：US13183009
申请日：2011-07-14
CPC分类号： C10G25/02 , C10G29/205 , C10G45/54 , C10G45/64 , C10G59/02 , C10G65/04 , C10G2300/1096 , C10G2300/201 , C10G2300/4018 , C10G2400/02 , C10G2400/04 , C10G2400/30
摘要： A guard bed or absorber is placed upstream of a transalkylation reactor to avoid deposition of halide and/or halogen species on the catalysts in said reactor.
摘要翻译： 保护床或吸收剂放置在烷基转移反应器的上游，以避免卤化物和/或卤素物质沉积在所述反应器中的催化剂上。
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公开(公告)号：US07799118B2
公开(公告)日：2010-09-21
申请号：US11729409
申请日：2007-03-28
申请人： James H. Beech, Jr.
发明人： James H. Beech, Jr.
CPC分类号： B01J8/003 , B01J8/0055 , B01J8/0065 , B01J8/008 , B01J8/1818 , B01J8/1827 , B01J8/26 , B01J29/90 , B01J38/30 , B01J38/32 , B01J2208/00212 , B01J2208/00584 , B01J2208/0084 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G3/57 , C10G2300/308 , C10G2300/4018 , C10G2300/802 , C10G2400/02 , C10G2400/20 , Y02P20/584 , Y02P30/20 , C07C11/02
摘要： A gas-solids reaction system is provided for improving product recovery in a multiple reactor reaction system. The solids of the product gas-solids flows from the multiple reactors are separated out in a separation vessel having a baffled transition zone. Additional product vapor is stripped from the solids as the solids pass through the baffled transition zone. The solids are then returned to the multiple reactors.
摘要翻译： 提供了一种气体 - 固体反应系统，用于改善多反应器反应体系中的产物回收。 从多个反应器流出的产物气固体的固体在具有挡板过渡区的分离容器中分离出来。 当固体通过挡板过渡区时，从固体中除去附加的产物蒸气。 然后将固体返回到多个反应器。
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34.发明授权公开(公告)号：US07767870B2
公开(公告)日：2010-08-03
申请号：US11216652
申请日：2005-08-31
申请人： Rutton D. Patel , Arun K. Sharma , E. Nicholas Jones , James H. Beech, Jr. , Richard E. Walter , Donald F. Shaw , Kenneth R. Clem , Nicolas P. Coute
发明人： Rutton D. Patel , Arun K. Sharma , E. Nicholas Jones , James H. Beech, Jr. , Richard E. Walter , Donald F. Shaw , Kenneth R. Clem , Nicolas P. Coute
CPC分类号： B01J8/1827 , B01D45/12 , B01J8/0055 , B01J8/0065 , B01J8/1809 , B01J8/1872 , B01J8/26 , B01J8/28 , B01J8/34 , B01J8/388 , B01J2208/0069 , C07C1/20 , C07C2529/85 , C10G11/18 , C10G31/10 , C07C11/02
摘要： A gas-solids reaction system with termination devices to connect a riser with one or more separation devices. The termination devices have a radius of curvature that is at least 1.0 times as great as the diameter of the conduit forming the termination device. The termination devices can be openly or closely coupled to the separation devices.
摘要翻译： 一种具有终端装置的气体 - 固体反应系统，用于将提升管与一个或多个分离装置连接。 端接装置的曲率半径至少是形成端接装置的导管的直径的1.0倍。 终端设备可以公开地或紧密地耦合到分离设备。
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公开(公告)号：US07598197B2
公开(公告)日：2009-10-06
申请号：US11050574
申请日：2005-02-03
CPC分类号： B01J8/12 , B01J8/087 , B01J19/0013 , B01J29/90 , B01J38/30 , B01J38/32 , B01J2208/00123 , C07C1/20 , C07C2529/83 , C07C2529/85 , F22B1/04 , F22B21/20 , F22G1/06 , F28D7/0066 , F28D7/0083 , F28D7/06 , F28D7/12 , Y02P20/584 , Y10S502/514 , C07C11/02
摘要： This invention provides processes, systems and devices for cooling catalyst, preferably regenerated catalyst, by superheating steam and boiling water. The inventive process advantageously provides ideal cooling conditions while ensuring minimal hydrothermal deactivation of the catalyst during the cooling process. The invention is particularly well-suited for cooling catalyst in an oxygenate to olefins reaction system.
摘要翻译： 本发明提供了通过过热蒸汽和沸水来冷却催化剂，优选再生催化剂的方法，系统和装置。 本发明的方法有利地提供理想的冷却条件，同时确保在冷却过程中催化剂的最小水热失活。 本发明特别适用于在含氧化合物至烯烃反应体系中冷却催化剂。
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公开(公告)号：US07223714B2
公开(公告)日：2007-05-29
申请号：US10981269
申请日：2004-11-04
IPC分类号： B01J27/182
CPC分类号： B01J8/18 , B01J8/0015 , B01J8/02 , B01J2208/00548 , B01J2208/00752 , B01J2208/00769 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： The invention is directed to methods of transfering catalyst particles into and within reaction systems. The reaction systems are those that use catalysts that comprise molecular sieves, particularly metalloaluminophosphate molecular sieves, especially metalloaluminophosphate molecular sieves which are susceptible to loss of catalytic activity due to contact with water molecules. The transfer methods provide appropriate mechanisms for transporting catalyst into and within a reactor to protect against loss of catalytic activity that can occur due to contact with water molecules.
摘要翻译： 本发明涉及将催化剂颗粒转移到反应体系内和在反应体系内的方法。 反应体系是使用包含分子筛的催化剂，特别是金属铝磷酸盐分子筛，特别是金属铝磷酸盐分子筛，它们由于与水分子接触而易于损失催化活性。 转移方法提供用于将催化剂输送到反应器内部和内部的适当机制，以防止由于与水分子接触而可能发生的催化活性的损失。
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公开(公告)号：US06965057B2
公开(公告)日：2005-11-15
申请号：US10807818
申请日：2004-03-24
CPC分类号： C07C1/20 , B01J38/30 , B01J38/32 , C10G3/49 , C10G3/62 , C10G2300/4093 , C10G2300/708 , C10G2300/802 , C10G2300/805 , C10G2400/20 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The invention relates to a process for converting an oxygenate feedstock into an olefin product stream comprising (a) contacting an oxygenate feedstock with a molecular sieve catalyst in a reactor under conditions effective to convert the feedstock into an olefin product stream and to form carbonaceous deposits on the catalyst; (b) contacting at least a portion of the catalyst having said carbonaceous deposits with an oxygen containing gas under conditions effective to obtain a regenerated catalyst having a reduced carbonaceous deposit level and having an increased molecular oxygen content; (c) removing at least 60% by volume of said molecular oxygen from the regenerated catalyst based upon the total volume of molecular oxygen; (d) returning said regenerated catalyst to said reactor; and (e) repeating steps (a)–(d).
摘要翻译： 本发明涉及一种将含氧化合物原料转化成烯烃产物流的方法，该方法包括（a）在有效将原料转化成烯烃产物流并形成碳质沉积物的条件下，使反应器中的含氧化合物原料与分子筛催化剂接触 催化剂; （b）在有效获得具有降低的碳沉积物水平并且具有增加的分子氧含量的再生催化剂的条件下使至少一部分具有所述碳质沉积物的催化剂与含氧气体接触; （c）基于分子氧的总体积从再生催化剂中除去至少60体积％的所述分子氧; （d）将所述再生催化剂返回到所述反应器; 和（e）重复步骤（a） - （d）。
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公开(公告)号：US5986148A
公开(公告)日：1999-11-16
申请号：US101111
申请日：1993-08-02
CPC分类号： C07C41/05 , Y02P20/582
摘要： An improved process for production of diisopropyl ether by conversion of hydrocarbon feedstock containing propene, propane and C.sub.2 -- light gas components. The overall process steps include, (optionally) prefractionating fresh feedstock containing propene, propane and C.sub.2 -- light gas components to provide a reactor feedstream rich in propene; contacting the feedstock and water in a catalytic reactor with acidic catalyst under olefin hydration and etherification conditions; and recovering from the catalytic reactor a liquid reactor effluent stream containing diisopropyl ether, isopropanol, water, unreacted propene, propane, oligomer and C.sub.2 -- light gas components. DIPE product containing C.sub.6 + oligomer is recovered by separating the liquid effluent stream in a stripper column, and extracting the DIPE-rich liquid with water. An improved separation process is employed for removing water to provide DIPE liquid product substantially free of water.
摘要翻译： 通过转化含有丙烯，丙烷和C2轻质气体成分的烃原料来改进制备二异丙醚的方法。 总体工艺步骤包括（任选地）预分馏含有丙烯，丙烷和C 2-轻质气体成分的新鲜原料，以提供富含丙烯的反应器进料流; 在烯烃水合和醚化条件下，用酸性催化剂在催化反应器中使原料和水接触; 并从催化反应器中回收含有二异丙基醚，异丙醇，水，未反应的丙烯，丙烷，低聚物和C2轻质气体组分的液体反应器流出物流。 通过分离汽提塔中的液体流出物流，并用水萃取富含DIPE的液体，回收含有C6 +低聚物的DIPE产物。 采用改进的分离方法去除水以提供基本上不含水的DIPE液体产物。
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公开(公告)号：US5324865A
公开(公告)日：1994-06-28
申请号：US20964
申请日：1993-02-22
CPC分类号： C07C41/05 , C07C41/06 , Y02P20/582
摘要： A process for production of diisopropyl ether by conversion of hydrocarbon feedstock containing propene, propane and C.sub.2 - light gas components, including the steps of: optionally, prefractionating fresh feedstock containing propene, propane and C.sub.2 - light gas components to provide a reactor feedstream rich in propene; contacting the feedstock and water in a catalytic reactor with acidic catalyst under olefin hydration and etherification conditions; and recovering from the catalytic reactor a liquid reactor effluent stream containing diisopropyl ether, isopropanol, water, unreacted propene, propane and C.sub.2 - light gas components. Improved operation is achieved by separating the liquid effluent stream in a vertical stripper column; recovering an overhead vapor stream containing propene, propane and C.sub.2 - light gas components from the stripper column; cooling the overhead vapor stream to provide a reflux stream rich in condensed propene and propane; removing the C.sub.2 - light gas components from condensed; recycling the reflux stream to an upper contact portion of the stripper column; and recovering a predominantly C3 recycle stream from the upper contact portion of the stripper column. Optionally, the C3 recycle stream may be passed to the to the prefractioning step for propene enrichment with fresh feedstock.
摘要翻译： 通过转化含有丙烯，丙烷和C2轻质气体组分的烃原料来生产二异丙醚的方法，包括以下步骤：任选地，将含有丙烯，丙烷和C2-轻质气体组分的新鲜原料预分馏，从而提供富含 丙烯 在烯烃水合和醚化条件下，用酸性催化剂在催化反应器中使原料和水接触; 并从催化反应器中回收含有二异丙基醚，异丙醇，水，未反应的丙烯，丙烷和C2-轻质气体组分的液体反应器流出物流。 通过在垂直汽提塔中分离液体流出物流来实现改进的操作; 从汽提塔回收含有丙烯，丙烷和C2轻质气体组分的塔顶蒸气流; 冷却塔顶蒸气流以提供富含缩合丙烯和丙烷的回流; 将C2轻质气体组分从冷凝中除去; 将回流流循环到汽提塔的上接触部分; 并从汽提塔的上部接触部分回收主要为C3的循环物流。 任选地，可以将C3循环流传递至用于用新鲜原料进行丙烯富集的预分馏步骤。
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40.发明授权
公开(公告)号：US4849186A
公开(公告)日：1989-07-18
申请号：US935374
申请日：1986-11-26
CPC分类号： C07C2/12 , C10G29/16 , C07C2529/40 , F02B3/06 , Y10S203/06
摘要： An oligomerization system is provided for upgrading lower olefins to distillate hydrocarbons, especially useful as high quality jet or diesel fuels. Thye olefinic feedstock is reacted over a shape selective acid zeolite, such as ZSM-5, to oligomerize feedstock olefins and further convert recycled hydrocarbons. Reactor effluent is fractionated to recover a light-middle distillate range product stream and to obtain gasoline and heavy hydrocarbon streams for recycle.
摘要翻译： 提供了一种低聚体系，用于将低级烯烃升级成馏分烃，特别适用于高质量的喷气或柴油燃料。 烯烃原料在形状选择性酸性沸石（如ZSM-5）上反应，使原料烯烃低聚并进一步转化回收的烃。 将反应器流出物分馏以回收轻 - 中馏分范围的产物流并获得用于再循环的汽油和重烃流。
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