Bridged ketones and process for preparing same
    31.
    发明授权
    Bridged ketones and process for preparing same 失效
    桥接酮及其制备方法

    公开(公告)号:US4250338A

    公开(公告)日:1981-02-10

    申请号:US95149

    申请日:1979-11-16

    摘要: Described are compounds covered by the generic structure; ##STR1## where one, two or all of R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents hydrogen or lower alkyl of from 1 up to 3 carbon atoms; a process for preparing same using compounds having the generic structure; ##STR2## where one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines represents carbon-carbon single bonds and organoleptic uses thereof in perfumes, colognes, perfumed articles such as anionic, cationic and non-ionic detergents, cosmetic powders and dryer-added fabric softener articles, as well as in smoking tobaccos and smoking tobacco articles, e.g., the body of smoking tobacco, the wrapper or the filter therefor. Thus, the tricyclic ketone compounds of our invention, having the generic structure: ##STR3## impart, augment or enhance low-keyed oily, woody, amber, leathery, warm spice, earthy camphoraceous, patchouli-like, balsamic-like, green, cardamom-like, vetiver-like, sweet woody or minty nuances in or to perfumed compositions or perfumed articles or colognes. The tricyclic ketones of our invention further augment, enhance or impart sweet, floral, woody, spicy, leathery and amber aroma nuances to smoking tobacco prior to smoking and sweet aromas with natural tobacco taste and aroma nuances on smoking in the main stream and in the side stream.

    摘要翻译: 描述的是通用结构覆盖的化合物; 其中R1,R2和R3中的一个,两个或全部相同或不同,并且各自表示氢或1至3个碳原子的低级烷基; 使用具有通式结构的化合物制备方法; 其中虚线之一是碳 - 碳双键,虚线中的另一条代表香烟,古龙水,香料制品如阴离子,阳离子和非离子洗涤剂中的碳 - 碳单键和感官用途 ,化妆品粉末和干燥剂添加的织物柔软剂制品,以及吸烟烟草和烟草制品,例如吸烟烟草,包装物或其过滤器。 因此,本发明的三环酮化合物具有通用结构:赋予,增强或增强低调油性,木质,琥珀色,革质,温香料,樟脑酸,广藿香样,香脂状,绿色, 香草类似,香甜的,甜的木质或细小的或在加香的组合物或香水制品或古龙水中的细微差别。 本发明的三环酮在吸烟之前进一步增强,增强或赋予吸烟烟草中甜,香,木质,辛辣,革质和琥珀香气的细微差别,并且具有天然烟草味道和香味在主流和吸烟中的细微差别 侧流。

    Process for enhancing the organoleptic properties of perfumed articles
using alkyl esters of 1-alkanolyl cycloalkanols
    36.
    发明授权
    Process for enhancing the organoleptic properties of perfumed articles using alkyl esters of 1-alkanolyl cycloalkanols 失效
    使用1-链烷酰基环烷醇的烷基酯增强香料制品的感官特性的方法

    公开(公告)号:US4359395A

    公开(公告)日:1982-11-16

    申请号:US314003

    申请日:1981-10-22

    IPC分类号: A24B15/34 C11D3/50 D06M13/00

    CPC分类号: D06M13/005 A24B15/34 C11D3/50

    摘要: Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanolates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures. The compounds so produced are useful for their organoleptic properties in consumable materials, such as foodstuffs, foodstuff flavorants, chewing gums, chewing gum flavorants, toothpastes, toothpaste flavorants, medicinal products, medicinal product flavorants, chewing tobaccos, chewing tobacco flavorants, smoking tobaccos, smoking tobacco flavorants, perfume compositions, perfumed articles, such as cationic, anionic, nonionic and zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, textile sizing agents and optical brighteners for textiles as well as colognes.

    摘要翻译: 描述了根据以下通用结构定义的几种取代或未取代的环烷基酰基链烷醇酯的方法:其中R1和R2一起完成环烷基部分或含有5或6个碳原子的甲基,二甲基或三甲基取代的环烷基部分 环,其中R 3是C 1 -C 3低级烷基,R 4是甲基或氢,通过使具有通式结构的化合物:在高温下具有弱酸性pH的含水银离子溶液中。 如此生产的化合物可用于消费材料如食品,食品香料,口香糖,口香糖调味剂,牙膏,牙膏调味剂,药用产品,药用香料,咀嚼烟草,咀嚼烟草香料,烟草烟草, 吸烟烟草调味剂,香料组合物,香料制品,例如阳离子,阴离子,非离子和两性离子洗涤剂,织物柔软剂组合物,干燥剂添加的织物柔软剂制品,纺织品上浆剂和用于纺织品的荧光增白剂以及古龙水。

    Alkyl esters of 1-alkanoyl cycloalkanols, process for preparing same and
organoleptic uses thereof
    37.
    发明授权
    Alkyl esters of 1-alkanoyl cycloalkanols, process for preparing same and organoleptic uses thereof 失效
    1-烷酰基环烷醇的烷基酯,其制备方法及其感官用途

    公开(公告)号:US4327749A

    公开(公告)日:1982-05-04

    申请号:US133828

    申请日:1980-03-25

    IPC分类号: A24B15/34 A24B15/30

    CPC分类号: A24B15/34

    摘要: Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanoates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures. The compounds so produced are useful for their organoleptic properties in consumable materials, such as foodstuffs, foodstuff flavorants, chewing gums, chewing gum flavorants, toothpastes, toothpaste flavorants, medicinal products, medicinal product flavorants, chewing tobaccos, chewing tobacco flavorants, smoking tobaccos, smoking tobacco flavorants, perfume compositions, perfumed articles, such as cationic, anionic, nonionic and zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, textile sizing agents and optical brighteners for textiles as well as colognes.

    摘要翻译: 描述了根据通用结构定义的若干取代或未取代的环烷基酰基链烷酸酯的方法:其中R 1和R 2一起完成环烷基部分或含有5或6个碳原子的甲基,二甲基或三甲基取代的环烷基部分 环,其中R 3是C 1 -C 3低级烷基,R 4是甲基或氢,通过使具有通式结构的化合物:在高温下具有弱酸性pH的含水银离子溶液中。 如此生产的化合物可用于消费材料如食品,食品香料,口香糖,口香糖调味剂,牙膏,牙膏调味剂,药用产品,药用香料,咀嚼烟草,咀嚼烟草香料,烟草烟草, 吸烟烟草调味剂,香料组合物,香料制品,例如阳离子,阴离子,非离子和两性离子洗涤剂,织物柔软剂组合物,干燥剂添加的织物柔软剂制品,纺织品上浆剂和用于纺织品的荧光增白剂以及古龙水。

    Alkyl esters of 1-alkanoyl cycloalkanols and organoleptic uses thereof
    38.
    发明授权
    Alkyl esters of 1-alkanoyl cycloalkanols and organoleptic uses thereof 失效
    1-烷酰基环烷醇的烷基酯及其感官用途

    公开(公告)号:US4374055A

    公开(公告)日:1983-02-15

    申请号:US314002

    申请日:1981-10-22

    CPC分类号: A24B15/34 C11B9/0026 C11D3/50

    摘要: Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanoates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures. The compounds so produced are useful for their organoleptic properties in consumable materials, such as foodstuffs, foodstuff flavorants, chewing gums, chewing gum flavorants, toothpastes, toothpaste flavorants, medicinal products, medicinal product flavorants, chewing tobaccos, chewing tobacco flavorants, smoking tobaccos, smoking tobacco flavorants, perfume compositions, perfumed articles, such as cationic, anionic, nonionic and zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, textile sizing agents and optical brighteners for textiles as well as colognes.

    摘要翻译: 描述了根据通用结构定义的若干取代或未取代的环烷基酰基链烷酸酯的方法:其中R 1和R 2一起完成环烷基部分或含有5或6个碳原子的甲基,二甲基或三甲基取代的环烷基部分 环,其中R 3是C 1 -C 3低级烷基,R 4是甲基或氢,通过使具有通式结构的化合物:在高温下具有弱酸性pH的含水银离子溶液中。 如此生产的化合物可用于消费材料如食品,食品香料,口香糖,口香糖调味剂,牙膏,牙膏调味剂,药用产品,药用香料,咀嚼烟草,咀嚼烟草香料,烟草烟草, 吸烟烟草调味剂,香料组合物,香料制品,例如阳离子,阴离子,非离子和两性离子洗涤剂,织物柔软剂组合物,干燥剂添加的织物柔软剂制品,纺织品上浆剂和用于纺织品的荧光增白剂以及古龙水。