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    Terminal cluster vinyl silicones and acrylate cluster silicones therefrom
    2.
    发明授权
    Terminal cluster vinyl silicones and acrylate cluster silicones therefrom 失效
    端基聚乙烯基硅氧烷和丙烯酸酯簇硅氧烷

    公开(公告)号：US4728709A

    公开(公告)日：1988-03-01

    申请号：US807933

    申请日：1986-03-10

    申请人： Philip Klemarczyk ,  Samuel Q. S. Lin

    发明人： Philip Klemarczyk ,  Samuel Q. S. Lin

    IPC分类号： C07F7/08 ,  C07F7/18 ,  C08C19/25 ,  C08F290/12 ,  C08F299/00 ,  C08G77/50 ,  C08F230/08 ,  C08F275/00 ,  C08G77/20

    CPC分类号： C08G77/50 ,  C07F7/0818 ,  C07F7/0896 ,  C07F7/1868 ,  C08C19/25 ,  C08F290/128 ,  C08F299/00 ,  Y10S528/901

    摘要： A polyorganosiloxane polymer having a structure represented by one of the formulas(AB).sub.m C or [(AB).sub.m ].sub.n SiR.sub.(4-n)where the R groups are the same or different organic groups other than acrylic groups or groups co-curable therewith; A is a linear polyorganosiloxane segment containing between 3 and about 50 siloxane repeat units at least 3 of which are acrylic group containing repeat units represented by the formula ##STR1## where R.sup.1 is lower alkyl, the R.sup.2 groups are the same or different alkylene, alkyleneoxy or alkenylene groups, and y is 0-4; B is a polyorganosiloxane segment represented by the formula ##STR2## where x is an integer of at least 100; C is A or a triorganosilyl group; m is an integer of 1 or more; and n is 3 or 4.

    摘要翻译： 具有由式（AB）mC或[（AB）m] nSiR（4-n）之一表示的结构的聚有机硅氧烷聚合物，其中R基团是与丙烯酸基团或其可共同固化的基团以外的相同或不同的有机基团 ; A是包含3至约50个硅氧烷重复单元的线性聚有机硅氧烷链段，其中至少3个是由下式表示的含有丙烯酸基的重复单元：其中R1是低级烷基，R2基团是相同或不同的亚烷基，亚烷氧基 或亚烯基，y为0-4; B是由式表示的聚有机硅氧烷链段，其中x是至少100的整数; C是A或三有机甲硅烷基; m为1以上的整数， n为3或4。

    Silicone polyphotoinitiators
    6.
    发明授权
    Silicone polyphotoinitiators 失效
    硅胶聚光引发剂

    公开(公告)号：US4666953A

    公开(公告)日：1987-05-19

    申请号：US717253

    申请日：1985-03-28

    申请人： Philip Klemarczyk ,  Steven T. Nakos ,  Samuel Q. S. Lin

    发明人： Philip Klemarczyk ,  Steven T. Nakos ,  Samuel Q. S. Lin

    IPC分类号： C08F2/50 ,  C08G77/38 ,  C08L83/04 ,  G03F7/075 ,  C08F30/08 ,  C08G77/20 ,  C08G77/40

    CPC分类号： G03F7/0757 ,  C08F2/50 ,  C08G77/38 ,  C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/20 ,  C08G77/28 ,  C08G77/70 ,  Y10S522/904

    摘要： Polyorganosiloxanes having an average of more than two siloxane repeat units, at least one of which repeat units includes a photoinitiating group bound to the silicon atom thereof, the photoinitiating group having the formula ##STR1## where R.sup.1 and R.sup.2 are the same or different alkyl groups or R.sup.1 and R.sup.2 are alkylene groups linked to each other so that R.sup.1 and R.sup.2 together with the carbon atom to which both are attached comprise a cycloalkyl group, and R.sup.3 is H or hydrocarbyl.Compositions of these polyorganosiloxanes and silicones or organic monomers with free radical curable groups are readily cured by irradiation with UV light.

    摘要翻译： 具有平均多于两个硅氧烷重复单元的聚有机硅氧烷，其中至少一个重复单元包括与其硅原子键合的光引发基团，具有式（II）的光引发基团，其中R 1和R 2相同或 不同的烷基或R 1和R 2是彼此连接的亚烷基，使得R 1和R 2与两个连接的碳原子一起包含环烷基，并且R 3是H或烃基。 这些聚有机硅氧烷和硅氧烷或具有自由基可固化基团的有机单体的组合物通过用UV光照射容易固化。

    Process for using bridged ketones in augmenting or enhancing the organoleptic properties of consumable materials
    8.
    发明授权
    Process for using bridged ketones in augmenting or enhancing the organoleptic properties of consumable materials 失效
    使用桥连酮增强或增强消耗材料的感官特性的方法

    公开(公告)号：US4293453A

    公开(公告)日：1981-10-06

    申请号：US200060

    申请日：1980-10-23

    申请人： Mark A. Sprecker ,  James M. Sanders ,  William L. Schreiber ,  Hugh Watkins ,  Joaquin F. Vinals ,  Edward J. Shuster ,  Thomas J. O'Rourke ,  Myrna L. Hagedorn ,  Philip Klemarczyk

    发明人： Mark A. Sprecker ,  James M. Sanders ,  William L. Schreiber ,  Hugh Watkins ,  Joaquin F. Vinals ,  Edward J. Shuster ,  Thomas J. O'Rourke ,  Myrna L. Hagedorn ,  Philip Klemarczyk

    IPC分类号： A24B15/30 ,  A24B15/34 ,  C07C45/00 ,  C07C45/67 ,  C07C47/445 ,  C07C49/453 ,  C11B9/00 ,  C11D3/50 ,  D06M13/00 ,  C07C13/30

    CPC分类号： D06M13/005 ,  A24B15/30 ,  A24B15/345 ,  C07C403/02 ,  C07C45/00 ,  C07C45/67 ,  C07C47/445 ,  C07C49/453 ,  C11B9/0042 ,  C11D3/50 ,  C07C2101/16 ,  C07C2103/66

    摘要： Described are compounds covered by the generic structure: ##STR1## where one, two or all of R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents hydrogen or lower alkyl of from 1 up to 3 carbon atoms; a process for preparing same using compounds having the generic structure: ##STR2## where one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines represents carbon-carbon single bonds and organoleptic uses thereof in perfumes, colognes, perfumed articles such as anionic, cationic and non-ionic detergents, cosmetic powders and dryer-added fabric softener articles, as well as in smoking tobaccos and smoking tobacco articles, e.g., the body of smoking tobacco, the wrapper or the filter therefor. Thus, the tricyclic ketone compounds of our invention, having the generic structure: ##STR3## impart, augment or enhance low-keyed oily, woody, amber, leathery, warm spice, earthy camphoraceous, patchouli-like, balsamic-like, green, cardamom-like, vetiver-like, sweet woody or minty nuances in or to perfumed compositions or perfumed articles or colognes. The tricyclic ketones of our invention further augment, enhance or impart sweet, floral, woody, spicy, leathery and amber aroma nuances to smoking tobacco prior to smoking and sweet aromas with natural tobacco taste and aroma nuances on smoking in the main stream and in the side stream.

    摘要翻译： 描述的是由通式结构覆盖的化合物：其中R 1，R 2和R 3中的一个，两个或全部相同或不同并且各自表示氢或1至3个碳原子的低级烷基; 使用具有以下通用结构的化合物制备方法：其中虚线中的一条是碳 - 碳双键，虚线中的另一条代表香料，古龙水，香水等中的碳 - 碳单键和感官用途， 加香制品如阴离子，阳离子和非离子洗涤剂，化妆品粉末和干燥剂添加织物柔软剂制品，以及吸烟烟草和烟草制品，例如吸烟烟草，包装物或其过滤器。 因此，本发明的三环酮化合物具有通用结构：赋予，增强或增强低调油性，木质，琥珀色，革质，温香料，樟脑酸，广藿香样，香脂状，绿色， 香草类似，香甜的，甜的木质或细小的或在加香的组合物或香水制品或古龙水中的细微差别。 本发明的三环酮在吸烟之前进一步增强，增强或赋予吸烟烟草中甜，香，木质，辛辣，革质和琥珀香气的细微差别，并且具有天然烟草味道和香味在主流和吸烟中的细微差别 侧流。

    Bridged ketones and process for preparing same
    10.
    发明授权
    Bridged ketones and process for preparing same 失效
    桥接酮及其制备方法

    公开(公告)号：US4250338A

    公开(公告)日：1981-02-10

    申请号：US95149

    申请日：1979-11-16

    申请人： Mark A. Sprecker ,  James M. Sanders ,  William L. Schreiber ,  Hugh Watkins ,  Joaquin F. Vinals ,  Edward J. Shuster ,  Thomas J. O'Rourke ,  Myrna L. Hagedorn ,  Philip Klemarczyk

    发明人： Mark A. Sprecker ,  James M. Sanders ,  William L. Schreiber ,  Hugh Watkins ,  Joaquin F. Vinals ,  Edward J. Shuster ,  Thomas J. O'Rourke ,  Myrna L. Hagedorn ,  Philip Klemarczyk

    IPC分类号： A24B15/30 ,  A24B15/34 ,  C07C45/00 ,  C07C45/67 ,  C07C47/445 ,  C07C49/453 ,  C11B9/00 ,  C11D3/50 ,  D06M13/00

    CPC分类号： D06M13/005 ,  A24B15/30 ,  A24B15/345 ,  C07C403/02 ,  C07C45/00 ,  C07C45/67 ,  C07C47/445 ,  C07C49/453 ,  C11B9/0042 ,  C11D3/50 ,  C07C2101/16 ,  C07C2103/66

    摘要： Described are compounds covered by the generic structure; ##STR1## where one, two or all of R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents hydrogen or lower alkyl of from 1 up to 3 carbon atoms; a process for preparing same using compounds having the generic structure; ##STR2## where one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines represents carbon-carbon single bonds and organoleptic uses thereof in perfumes, colognes, perfumed articles such as anionic, cationic and non-ionic detergents, cosmetic powders and dryer-added fabric softener articles, as well as in smoking tobaccos and smoking tobacco articles, e.g., the body of smoking tobacco, the wrapper or the filter therefor. Thus, the tricyclic ketone compounds of our invention, having the generic structure: ##STR3## impart, augment or enhance low-keyed oily, woody, amber, leathery, warm spice, earthy camphoraceous, patchouli-like, balsamic-like, green, cardamom-like, vetiver-like, sweet woody or minty nuances in or to perfumed compositions or perfumed articles or colognes. The tricyclic ketones of our invention further augment, enhance or impart sweet, floral, woody, spicy, leathery and amber aroma nuances to smoking tobacco prior to smoking and sweet aromas with natural tobacco taste and aroma nuances on smoking in the main stream and in the side stream.

    摘要翻译： 描述的是通用结构覆盖的化合物; 其中R1，R2和R3中的一个，两个或全部相同或不同，并且各自表示氢或1至3个碳原子的低级烷基; 使用具有通式结构的化合物制备方法; 其中虚线之一是碳 - 碳双键，虚线中的另一条代表香烟，古龙水，香料制品如阴离子，阳离子和非离子洗涤剂中的碳 - 碳单键和感官用途 ，化妆品粉末和干燥剂添加的织物柔软剂制品，以及吸烟烟草和烟草制品，例如吸烟烟草，包装物或其过滤器。 因此，本发明的三环酮化合物具有通用结构：赋予，增强或增强低调油性，木质，琥珀色，革质，温香料，樟脑酸，广藿香样，香脂状，绿色， 香草类似，香甜的，甜的木质或细小的或在加香的组合物或香水制品或古龙水中的细微差别。 本发明的三环酮在吸烟之前进一步增强，增强或赋予吸烟烟草中甜，香，木质，辛辣，革质和琥珀香气的细微差别，并且具有天然烟草味道和香味在主流和吸烟中的细微差别 侧流。