公开(公告)号：US5321183A

公开(公告)日：1994-06-14

申请号：US939752

申请日：1992-09-02

Applicant: Clarence D. Chang ,  Paul G. Rodewald

Inventor： Clarence D. Chang ,  Paul G. Rodewald

IPC: B01J29/06 ,  B01J29/40 ,  B01J29/44 ,  B01J31/02 ,  B01J31/12 ,  C07B61/00 ,  C07C1/20 ,  C07C2/12 ,  C07C2/66 ,  C07C2/84 ,  C07C2/86 ,  C07C5/22 ,  C07C5/27 ,  C07C5/41 ,  C07C5/52 ,  C07C6/12 ,  C07C11/02 ,  C07C15/02 ,  C07C15/08 ,  C07C45/51 ,  C07C45/54 ,  C07C49/825 ,  C10G45/64 ,  C10G50/00 ,  C10G50/02 ,  C10G73/02 ,  C07C2/00 ,  C07C4/00 ,  C07C6/00

CPC classification number: B01J31/124 ,  B01J29/40 ,  B01J29/44 ,  B01J31/0274 ,  B01J31/125 ,  C07C1/20 ,  C07C2/12 ,  C07C2/66 ,  C07C45/54 ,  C07C5/2708 ,  C07C5/41 ,  C07C6/123 ,  C07C6/126 ,  C10G45/64 ,  C10G50/00 ,  B01J2229/12 ,  B01J2229/42 ,  C07C2529/40 ,  Y02P20/52

Abstract: Processes for converting a wide variety of aromatic hydrocarbons, such as polyalkylaromatics, into commercially useful para-substituted aromatics such as para-xylene are disclosed. The aromatic hydrocarbon feed stream is first partially converted into toluene which is then subjected to a highly para-selective methylation process. The present invention therefore provides novel processes and catalysts for increasing the para-selectivity in the selective production of para-substituted aromatic compounds. From the description provided herein, those skilled in the art will appreciate that the catalysts and processes of the present invention provide greater para-selectivity at conversion rates unattained by previously known methods.

Abstract translation: 公开了将各种芳烃如聚烷基芳烃转化成商业上有用的对位取代的芳族化合物如对二甲苯的方法。 首先将芳烃进料流部分转化成甲苯，然后进行高度对位选择性甲基化处理。 因此，本发明提供用于增加选择性生产对位取代的芳族化合物中的对选择性的新方法和催化剂。 根据本文提供的描述，本领域技术人员将理解，本发明的催化剂和方法在转化率下提供了通过先前已知的方法获得的较高的对选择性。

公开(公告)号：US5068048A

公开(公告)日：1991-11-26

申请号：US476079

申请日：1990-02-07

Applicant: Catherine S. H. Chen ,  Paul G. Rodewald

Inventor： Catherine S. H. Chen ,  Paul G. Rodewald

IPC: C10M105/18 ,  C10M107/02 ,  C10M129/18 ,  C10M143/00

CPC classification number: C10M129/18 ,  C10M105/18 ,  C10M107/02 ,  C10M143/00 ,  C10M2207/042

Abstract: Oligomers produced from lower olefins by acidic zeolite catalyzed oligomerization can be converted to useful lubricant additives or lubricants by epoxidation of olefinic bonds in the oligomers, whereby oligomers containing oxirane ring structures are produced. The epoxided products so produced exhibit high viscosity index and low pour points. The discovery is particularly applicable to the epoxidation of oligomers produced from lower olefins such as propylene by oligomerization using ZSM-5 catalyst which has been surface deactivated.

Abstract translation: 通过酸性沸石催化低聚产生的低级烯烃的低聚物可以通过低聚物中的烯键的环氧化转化为有用的润滑剂添加剂或润滑剂，由此制备含有环氧乙烷环结构的低聚物。 如此生产的环氧化产物具有高粘度指数和低倾点。 该发现特别适用于使用已经表面失活的ZSM-5催化剂通过低聚而由低级烯烃如丙烯生产的低聚物的环氧化。

公开(公告)号：US4751341A

公开(公告)日：1988-06-14

申请号：US97374

申请日：1987-09-16

Applicant: Paul G. Rodewald

Inventor： Paul G. Rodewald

IPC: B01J29/40 ,  C07C1/20 ,  C07C2/12 ,  C07C5/27 ,  C07C6/12 ,  C07C2/02

CPC classification number: C07C6/123 ,  B01J29/40 ,  C07C1/20 ,  C07C2/12 ,  C07C5/2718 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2527/1213 ,  C07C2529/40 ,  Y02P30/42

Abstract: A modified ZSM-5 type zeolite is provided by treatment of a ZSM-5 type zeolite with BF.sub.3. The novel product is characterized by reduced pore size and enhanced shape-selectivity, or by enhanced activity, or by both. This invention also provides a process for catalytically converting organic compounds by use of the novel composition, an illustrative conversion being the catalytic conversion of methanol to hydrocarbons and C.sub.2 -C.sub.7 olefins to gasoline components.

Abstract translation: 通过用BF 3处理ZSM-5型沸石提供改性的ZSM-5型沸石。 该新产品的特征在于减小的孔径和增强的形状选择性，或通过增强的活性，或由两者。 本发明还提供了一种通过使用新组合物催化转化有机化合物的方法，一种说明性的转化是将甲醇催化转化为烃和C2-C7烯烃至汽油组分。

公开(公告)号：US4709114A

公开(公告)日：1987-11-24

申请号：US905996

申请日：1986-09-11

Applicant: Paul G. Rodewald ,  Ernest W. Valyocsik

Inventor： Paul G. Rodewald ,  Ernest W. Valyocsik

IPC: B01J29/70 ,  C01B39/48 ,  C07C1/20 ,  C07C2/66 ,  C07C5/27 ,  C07C6/12 ,  C07C1/00 ,  C07C11/20

CPC classification number: C07C6/126 ,  B01J29/70 ,  C01B39/48 ,  C07C1/20 ,  C07C2/66 ,  C07C5/271 ,  C07C6/123 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/70 ,  Y02P30/42

Abstract: A process is provided for converting feedstock comprising oxygenates to product comprising hydrocarbons over a catalyst comprising zeolite ZSM-58.

Abstract translation: 提供了一种方法，用于将包含含氧化合物的原料转化为包含沸石ZSM-58的催化剂的包含烃的产物。

公开(公告)号：US4683051A

公开(公告)日：1987-07-28

申请号：US860362

申请日：1986-05-06

Applicant: Paul G. Rodewald

Inventor： Paul G. Rodewald

IPC: B01J29/40 ,  C07C1/20 ,  C07C2/12 ,  C07C5/27 ,  C07C6/12 ,  C10G11/05 ,  C10G45/64 ,  C10G47/20

CPC classification number: C07C6/123 ,  B01J29/40 ,  C07C1/20 ,  C07C2/12 ,  C07C5/2718 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2527/1213 ,  C07C2529/40

Abstract: A modified ZSM-5 type zeolite is provided by treatment of a ZSM-5 type zeolite with BF.sub.3. The novel product is characterized by reduced pore size and enhanced shape-selectivity, or by enhanced activity, or by both. This invention also provides a process for catalytically converting organic compounds by use of the novel composition, an illustrative conversion being the catalytic conversion of methanol to hydrocarbons.

公开(公告)号：US4465886A

公开(公告)日：1984-08-14

申请号：US502868

申请日：1983-06-09

Applicant: Paul G. Rodewald

Inventor： Paul G. Rodewald

IPC: B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C07C2/66 ,  C07C2/86 ,  C07C6/12 ,  C07C3/52 ,  C07C3/62

CPC classification number: C07C6/126 ,  B01J29/40 ,  C07C2/66 ,  C07C2/861 ,  C07C2/864 ,  C07C2/865 ,  C07C2/868 ,  C07C6/123 ,  B01J2229/12 ,  B01J2229/32 ,  B01J29/65 ,  B01J29/70 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70

Abstract: The present invention relates to selective conversion of certain hydrocarbon feedstocks to product rich in para-dialkyl substituent benzenes over a catalyst composition comprising a crystalline zeolite having deposited thereon a coating of silica which extensively covers and resides substantially exclusively on the external surface thereof.

Abstract translation: 本发明涉及某些烃原料选择性转化成富含对二烷基取代苯的产物，其催化剂组合物包含沉积在其上沉积有二氧化硅涂层的结晶沸石，其基本上完全覆盖在其外表面上。

公开(公告)号：US4379761A

公开(公告)日：1983-04-12

申请号：US223878

申请日：1981-01-09

Applicant: David H. Olson ,  Paul G. Rodewald

Inventor： David H. Olson ,  Paul G. Rodewald

IPC: B01J21/08 ,  B01J27/16 ,  B01J29/40 ,  C07C2/66 ,  B01J27/14 ,  B01J29/06

CPC classification number: B01J29/40 ,  B01J21/08 ,  B01J27/16 ,  C07C2/66 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2529/40

Abstract: Disclosed is a zeolite base catalyst useful particularly for the selective production of para-dialkylsubstituted benzene. The catalyst comprises a porous crystalline zeolite having silica deposited thereon and having incorporated therein phosphorous. Described also in the process for making the catalyst and the parameters for the use of the catalyst in dialkylation processes.

Abstract translation: 公开了一种特别用于选择性制备对二烷基取代的苯的沸石碱催化剂。 催化剂包括其上沉积有二氧化硅并且掺入磷中的多孔结晶沸石。 还描述了制备催化剂的方法和在二烷基化方法中使用催化剂的参数。

公开(公告)号：US4060568A

公开(公告)日：1977-11-29

申请号：US672194

申请日：1976-03-31

Applicant: Paul G. Rodewald

Inventor： Paul G. Rodewald

IPC: B01J29/08 ,  B01J29/00 ,  B01J29/06 ,  B01J29/16 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J29/65 ,  B01J29/70 ,  C01B33/40 ,  C01B39/00 ,  C01B39/10 ,  C01B39/12 ,  C01B39/36 ,  C01B39/38 ,  C01B39/42 ,  C01B39/44 ,  C07B61/00 ,  C07C1/00 ,  C07C2/00 ,  C07C2/02 ,  C07C2/66 ,  C07C2/76 ,  C07C2/86 ,  C07C4/00 ,  C07C5/41 ,  C07C6/12 ,  C07C15/02 ,  C07C15/08 ,  C07C67/00 ,  C07C1/20 ,  C07C1/24

CPC classification number: B01J29/40 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y10S423/22 ,  Y10S423/23 ,  Y10S423/29 ,  Y10S423/33 ,  Y10S585/906

Abstract: A catalyst is provided, which is especially applicable for the selective production of certain desired hydrocarbons, comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12, a constraint index, as hereinafter defined, within the approximate range of 1 to 12 and having contained within the interior crystalline structure thereof added amorphous silica in an amount of at least about 0.1 and preferably between about 2 and about 10 weight percent. The invention described herein also encompasses synthesis of the specified catalyst and use of the same in selectively producing low molecular weight olefins and/or para-xylene from appropriate charge stocks.

Abstract translation: 提供了一种催化剂，其特别适用于某些所需烃的选择性生产，其包含二氧化硅与氧化铝之比至少约为12的结晶铝硅酸盐沸石，约定指数如下所定义，在约1至 12并且其内部结晶结构中含有至少约0.1，优选约2至约10重量％的量的无定形二氧化硅。 本文描述的发明还包括合成特定的催化剂及其在合适的电荷原料中选择性地生产低分子量烯烃和/或对二甲苯的用途。

公开(公告)号：US3962133A

公开(公告)日：1976-06-08

申请号：US532146

申请日：1974-12-12

Applicant: Paul G. Rodewald

Inventor： Paul G. Rodewald

IPC: B01J27/12 ,  C01B31/00 ,  C07C2/20 ,  C07C2/68 ,  C07C2/86 ,  C07C5/27 ,  C07C6/10

CPC classification number: C07C6/10 ,  B01J27/12 ,  C01B31/0415 ,  C07C2/20 ,  C07C2/68 ,  C07C2/861 ,  C07C5/2786 ,  C07C2521/18 ,  C07C2527/1213 ,  C07C2527/133 ,  C07C2527/14 ,  Y02P20/52 ,  Y02P20/582

Abstract: Intercalation of a Lewis acid fluoride in graphite is effected in the presence of gaseous fluorine. The reaction results in new compositions useful as catalysts and as atmospheric pressure containers for normally gaseous Lewis acid fluorides.

公开(公告)号：US5571768A

公开(公告)日：1996-11-05

申请号：US306567

申请日：1994-09-15

Applicant: Clarence D. Chang ,  Paul G. Rodewald

Inventor： Clarence D. Chang ,  Paul G. Rodewald

IPC: B01J29/40 ,  B01J29/44 ,  B01J31/02 ,  B01J31/12 ,  B01J31/40 ,  C07C1/20 ,  C07C2/12 ,  C07C2/66 ,  C07C5/27 ,  C07C5/41 ,  C07C6/12 ,  C07C45/54 ,  C10G45/64 ,  C10G50/00 ,  B01J29/26

CPC classification number: B01J31/125 ,  B01J29/40 ,  B01J29/44 ,  B01J31/0274 ,  B01J31/40 ,  C07C1/20 ,  C07C2/12 ,  C07C2/66 ,  C07C45/54 ,  C07C5/2708 ,  C07C5/41 ,  C07C6/123 ,  C07C6/126 ,  C10G45/64 ,  C10G50/00 ,  B01J2229/12 ,  B01J2229/42 ,  C07C2529/40 ,  Y02P20/584

Abstract: There is provided a zeolite, such as ZSM-5, which is functionalized with at least one organosiliceous group of the formula, SiR.sub.n (OX).sub.4-n, where R is at least one hydrocarbyl group, n is 1 or 2 and X is Si or H. There is also provided a method for functionalizing a zeolite by treatment with a silicone compound, such as hexamethyldisiloxane, under vapor phase conditions. This contacting may take place in the presence of hydrogen and an organic carrier. The functionalized zeolites may provide a catalyst which is both highly active and highly selective for converting aromatic hydrocarbons, especially alkylbenzene compounds, to products comprising the para-isomer of dialkylbenzenes. The disproportionation of toluene is an example of such a reaction.

Abstract translation: 提供沸石，例如ZSM-5，其用至少一种下式的有机硅基团SiRn（OX）4-n官能化，其中R是至少一个烃基，n是1或2，X是 Si或H.还提供了一种通过在气相条件下用硅氧烷化合物如六甲基二硅氧烷处理来官能化沸石的方法。 该接触可以在氢和有机载体的存在下进行。 官能化沸石可以提供对于将芳族烃，特别是烷基苯化合物转化成包含二烷基苯的对位异构体的产物，其具有高活性和高度选择性的催化剂。 甲苯的歧化是这种反应的一个例子。