摘要:
A thermoplastic resin composition comprise 99.9.about.50 parts by weight of one or more thermoplastic resin selected from the group consisting of aromatic polyimide, aromatic polyetherimide, aromatic polyamideimide, aromatic polyethersulfone and aromatic polyether ketone and 0.1.about.50 parts by weight of one or more liquid crystal type aromatic polyimide having recurring structural units represented by the formula (1): ##STR1## wherein R.sub.1 .about.R.sub.5 is a hydrogen atom, fluorine atom, trifluoromethyl, methyl, ethyl or cyano and may be the same or different, and R is a tetravalent radical having 6.about.27 carbon atoms and being selected from the group consisting of a monoaromatic radical, condensed polyaromatic radical and noncondensed aromatic radical connected each other with a direct bond or a bridge member.The present invention can provide thermoplastic resin compositions which have remarkably good processability and excellent thermal stability in addition to essentially excellent properties of each resin.
摘要:
Disclosed herein is a polypropylene resin composition of a high syndiotacticity comprising a substantial homopolymer of propylene, in which the ratio of the intensity of the peak attributable to the syndiotactic pentad bonds to the sum of the intensities of all the peaks attributable to the methyl groups in the spectrum of the methyl groups measured by .sup.13 C-NMR is 0.7 or more, and a copolymer of ethylene and propylene, and a preparation process thereof.
摘要:
The heat resistant adhesive of the invention comprises polyamic acid and/or polyimide which are prepared by using 1,3-bis(3-aminophenoxy)benzene as an aromatic diamine component and 3,3', 4,4'-biphenyltetracarboxylic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic dianhydride and/or 3,3',4,4'-diphenylethertetracarboxylic dianhydride as tetracarboxylic acid dianhydrides, and further by blocking the polymer chain end with dicarboxylic anhydride or a monoamine compound; or comprises a polyimide solution containing the polyimide in a good solvent.The adhesive of the invention is a heat-resistant adhesive capable of adhering under mild temperature/mild pressure conditions. The adhesive of polyimide solution can provide desired adhesion by simple procedures such as applying to the adherend and heating under pressure and exhibits excellent adhesive strength. Consequently, the heat-resistant adhesive of the invention is very useful for the adhesion of structural and electronic materials and other industrial materials.
摘要:
A block copolymer of propylene can be obtained with its quality controlled uniform by conducting at first continuous polymerization of propylene in a polymerization system, receiving a polymer slurry, which has been discharged continuously from the polymerization system, in a batchwise polymerization tank, feeding ethylene to the tank to conduct batchwise polymerization of ethylene and propylene. Upon discharge of a copolymer slurry formed by the preceding batchwise polymerization, at least a predetermined amount of unreacted ethylene is left over in the tank. Into the tank with the unreacted ethylene still left over therein, there are simultaneously charged the polymer slurry from the polymerization system and a deactivator. During this charging, ethylene is not supplied. The charging rate of the deactivator is controlled in such a way that the partial pressure of ethylene in the vapor phase of the tank always reaches a predetermined value at the time point of completion of reception of the polymer slurry therein.
摘要:
Disclosed herein is a method for controlling the polymerization temperature in a polymerization apparatus equipped with a cooling system in which steam, which has occurred in the presence of a volatile liquid medium in a reaction system, is condensed in a reflux condenser and the resulting noncondensable gas and condensate are then returned to the reaction system, thereby removing the polymerization heat. A portion of the noncondensable gas is recirculated to the cooling system. The flow rate of the noncondensable gas to be recirculated and the flow rate of a cooling medium to be introduced into the reflux condenser are controlled in accordance with the temperature of the reaction system.
摘要:
A fiber excellent in strength and having an average size of 10,000-0.1 denier can be obtained by extruding a new material composed mainly of a polypropylene having a syndiotactic pentad fraction of 0.7 or more and optionally stretching the resulting extruded material. By using as the raw material a composition consisting of two kinds of polypropylenes each having an intrinsic viscosity .eta..sub.1 or .eta..sub.2, the log(.eta..sub.2 /.eta..sub.1) being more than 0.05 or less than -0.05, and a syndiotactic pentad traction of 0.7 or more at a weight ratio of 95:5-5:95 or a composition consisting of at least 50 parts by weight of a syndiotactic polypropylene having the intrinsic viscosity .eta..sub.1 and a syndiotactic pentad fraction of 0.7 or above and at most 50 parts by weight of an isotactic polypropylene having the intrinsic viscosity .eta..sub.2, the extrudability is improved and the fiber stretching conditions are broadened.
摘要翻译:通过挤出主要由间同立构五单元组分为0.7以上的聚丙烯组成的新材料,并任选地拉伸所得的挤出材料,可以获得强度优异且平均尺寸为10,000-0.1旦尼尔的纤维。 通过使用由具有特性粘度eta 1或eta 2的两种聚丙烯组成的组合物,log(eta 2 / eta 1)大于0.05或小于-0.05,间同立构五单元牵引力 0.7重量%以上,重量比为95:5.5:95的组合物或由至少50重量份的特性粘度η1和间同立构五单元组分数为0.7以上至多50份的间同立构聚丙烯组成的组合物 的特性粘度等于2的全同立构聚丙烯,可挤出性提高,纤维拉伸条件变宽。
摘要:
A polyimide comprising a requisite structural unit having one or more recurring structural units of the formula: ##STR1## such as the structural units of the formula ##STR2## The polyimide can have an extremely low dielectric constant and is colorless, transparent and excellent in processability and heat resistance, and also provides an aromatic diamine which is useful as a raw material monomer of the polyimide or a raw material of other various engineering plastics.
摘要:
An .alpha.-olefin-alkenylsilane copolymer having steric regularity in which the side chains in the .alpha.-olefin unit substantially have the steric regularity, the content of alkenylsilane units is from 0.01 to 50% by weight, and the intrinsic viscosity measured in a tetralin solution at 135.degree. C. is 0.01 or higher. A method for preparing the above copolymer comprises the step of copolymerizing an .alpha.-olefin having 3 to 25 carbon atoms with an alkenylsilane in the presence of a catalyst comprising an aluminoxane and a transition metal compound containing a cyclopentadiene group or its derivative as a ligand.
摘要:
There is disclosed a homoplymer of an alkenylsilane having a syndiotactic structure and a copolymer of the alkenylsilane and an .alpha.-olefin. The polymer and the copolymer can be prepared by subjecting the alkenylsilane or the alkenylsilane and the .alpha.-olefin to addition polymerization in the presence of a transition metal compound having asymmetirically interconnected ligands or preferably in the presence of the transition metal compound and aluminoxane. The polymer and the copolymer can be used as a nucleating agent for a crystalline polypropylene.
摘要:
The invention relates to a block copolymer of propylene and a process for preparing the same comprising (a) polymerizing propylene or .alpha.-olefins mainly comprising propylene in the presence of a catalyst comprising a transition metal catalyst and an organometal compound; (b) copolymerizing .alpha.-olefins mainly comprising propylene and ethylene, wherein in at least one of steps (a) and (b) copolymerization is carried out with an alkenylsilane compound.