公开(公告)号：US20080056964A1

公开(公告)日：2008-03-06

申请号：US11932140

申请日：2007-10-31

Applicant: SHASHI SINGH ,  David Mann ,  Anant Pisut

Inventor： SHASHI SINGH ,  David Mann ,  Anant Pisut

IPC: B01J19/00

CPC classification number: C01C1/0423 ,  B01J8/008 ,  B01J8/067 ,  B01J23/462 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00513 ,  B01J2208/00548 ,  B01J2219/00238 ,  C01C1/0441 ,  C01C1/0482 ,  Y02E60/364 ,  Y02P20/52

Abstract: An ammonia converter is disclosed. The converter can alter the conversion of ammonia by controlling the reaction temperature of the exothermic reaction along the length of the reactor to parallel the equilibrium curve for the desired product. The converter can comprise a shell 101 and internal catalyst tubes 109. The feed gas stream enters the reactor, flows through the shell 101, and is heated by indirect heat exchange with the catalyst tubes 109. The catalyst tubes 109 comprise reactive zones 122 having catalyst and reaction limited zones 124 that can comprise inert devices that function to both separate the reactive zones, increase heat transfer area, and reduce the temperature of the reaction mixture as the effluent passes through the catalyst tube 109

Abstract translation: 公开了一种氨转化器。 转化器可以通过控制沿着反应器长度的放热反应的反应温度来平行所需产物的平衡曲线来改变氨的转化率。 转化器可以包括壳体101和内部催化剂管109.进料气体流进入反应器，流过壳体101，并通过与催化剂管109的间接热交换而加热。催化剂管109包含具有催化剂的反应区域122 以及反应限制区124，其可以包括用于分离反应性区域的惰性装置，增加传热面积，并且当流出物通过催化剂管109时降低反应混合物的温度

公开(公告)号：US20080023175A1

公开(公告)日：2008-01-31

申请号：US11782741

申请日：2007-07-25

Applicant: Manfred Lehr ,  Josef Dachs ,  Wolfgang Schuster

Inventor： Manfred Lehr ,  Josef Dachs ,  Wolfgang Schuster

IPC: B01J8/06

CPC classification number: B01J8/067 ,  B01J2208/00053 ,  B01J2208/00061 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00256 ,  B01J2208/00646 ,  B01J2208/00716 ,  F28D7/16 ,  F28F27/00

Abstract: A method of varying the temperature of a tube bundle reactor for catalytic gas phase reactions upon start-up and shut-down, the tube bundle reactor comprising a major reactor portion which includes a bundle of vertically disposed reactor tubes, upper and lower tubesheets tightly connected to the upper and lower ends, respectively, of the reactor tubes, and a reactor shell enclosing the tube bundle, a heat transfer medium having a melting temperature in the range of from 100° C. to 450° C. flowing around the outer surfaces of the reactor tubes during normal operation and being circulated in at least one circuit through the major reactor portion, comprising the steps: (a) varying the heat transfer medium temperature during circulation of the heat transfer medium; and (b) passing a temperature gas through the reactor tubes at least when the heat transfer medium is not yet or no longer circulated.

Abstract translation: 一种在启动和关闭时改变用于催化气相反应的管束反应器的温度的方法，管束反应器包括主反应器部分，其包括一排垂直设置的反应器管，上管和下管紧密连接 反应器管的上端和下端以及包围管束的反应器壳体，具有在外表面流动的熔点在100℃至450℃范围内的传热介质 的反应器管，并且通过主反应器部分在至少一个回路中循环，包括以下步骤：（a）改变传热介质循环期间的传热介质温度; 和（b）至少当传热介质尚未或不再循环时，使温度气体通过反应器管。

公开(公告)号：US20080021242A1

公开(公告)日：2008-01-24

申请号：US11826630

申请日：2007-07-17

Applicant: Michio Tanimoto ,  Daisuke Nakamura ,  Nobuyuki Hakozaki

Inventor： Michio Tanimoto ,  Daisuke Nakamura ,  Nobuyuki Hakozaki

IPC: C07C45/28 ,  B01J8/04

CPC classification number: B01J8/048 ,  B01J8/0492 ,  B01J8/0496 ,  B01J8/067 ,  B01J23/002 ,  B01J23/8885 ,  B01J37/0221 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00513 ,  B01J2208/00707 ,  B01J2208/025 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/13 ,  B01J2523/54 ,  B01J2523/842 ,  B01J2523/845

Abstract: Conventional gas-phase catalytic oxidation reaction apparatus comprising two reactors for production of acrylic acid is subject to problems of high equipment costs for the reactors and piping, necessity for wide installation area and easy accumulation of carbides generated by autoxidation of acrolein. On the other hand, conventional reaction apparatus comprising a single reactor has the drawbacks that the composition of gas in the first stage reaction and in the second stage reaction cannot be optimized independently of each other, and that the allowable concentration of starting propylene is limited because of the risk of explosion. As a reaction apparatus to solve these problems, this invention provides a fixed bed shell-and-tube reaction apparatus comprising a single reactor, characterized in that the inside of the reactor is divided into two reaction zones of the first reaction zone and the second reaction zone, and that a space equipped with a mechanism for introducing a gaseous substance from outside is provided between the two reaction zones.

Abstract translation: 包括用于生产丙烯酸的两个反应器的常规气相催化氧化反应装置受到反应器和管道的高设备成本的问题的影响，需要宽的安装面积和易于积聚由丙烯醛自动氧化产生的碳化物。 另一方面，包括单个反应器的常规反应装置的缺点是第一阶段反应和第二阶段反应中的气体组成不能彼此独立地优化，并且起始丙烯的允许浓度受到限制，因为 的爆炸风险。 作为解决这些问题的反应装置，本发明提供一种包括单个反应器的固定床管壳反应装置，其特征在于，将反应器内部分成第一反应区和第二反应的两个反应区 并且在两个反应区之间设置有配备有用于从外部引入气态物质的机构的空间。

公开(公告)号：US20070217991A1

公开(公告)日：2007-09-20

申请号：US11569561

申请日：2005-05-27

Applicant: Yasuhiko Mori

Inventor： Yasuhiko Mori

IPC: C01B7/00 ,  B01J8/06

CPC classification number: B01J8/067 ,  B01J19/0013 ,  B01J19/2425 ,  B01J2208/00221 ,  B01J2208/00407 ,  B01J2208/0053 ,  B01J2219/00085 ,  B01J2219/00103 ,  C01B7/01 ,  F28D7/0066 ,  F28D7/0091

Abstract: The present invention provides a heat exchange reactor comprising a reaction tube for obtaining a product (B) by exothermic reaction while passing a starting compound (A) therethrough and a reactor shell covering the surrounding of the reaction tube and having its interior divided into a plurality of regions along the passing direction of the starting compound (A), each of which regions is filled with a heat medium for carrying out heat exchange between the inside of the reaction tube and the heat medium independently for the respective separate regions; wherein the reactor is provided with a heater for heating the heat medium charged in the most upstream region among the separate regions independently from the heat media charged in other regions.

Abstract translation: 本发明提供了一种热交换反应器，其包括用于通过放热反应同时通过其中的起始化合物（A）获得产物（B）的反应管和覆盖反应管周围并将其内部分成多个的反应器壳 沿着原料化合物（A）的通过方向的区域，每个区域填充有热介质，用于在各个分离区域内独立地进行反应管内部和热介质之间的热交换; 其特征在于，所述反应器具有加热器，用于独立于在其它区域中加载的热介质，加热在分离区域中最上游区域充电的热介质。

公开(公告)号：US07220392B2

公开(公告)日：2007-05-22

申请号：US10443397

申请日：2003-05-22

Applicant: Xiaoyang Rong ,  Brian E. Cheadle

Inventor： Xiaoyang Rong ,  Brian E. Cheadle

IPC: F28D21/00 ,  B01J8/00 ,  B01J19/00 ,  B01J10/00

CPC classification number: B01J8/0242 ,  B01J8/008 ,  B01J8/0278 ,  B01J8/0285 ,  B01J8/0453 ,  B01J8/048 ,  B01J8/0492 ,  B01J8/0496 ,  B01J8/067 ,  B01J2208/00194 ,  B01J2208/00221 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2208/00849 ,  B01J2208/025 ,  C01B3/382 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/00 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0288 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0844 ,  C01B2203/0883 ,  C01B2203/1023 ,  C01B2203/1082 ,  C01B2203/1217 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1276 ,  C01B2203/1288 ,  C01B2203/142 ,  C01B2203/1604 ,  C01B2203/1685 ,  C01B2203/169 ,  C01B2203/82 ,  F28D7/1607 ,  F28D7/1669 ,  F28F9/0236 ,  F28F9/0241 ,  F28F9/22 ,  H01M8/0618 ,  H01M8/0668

Abstract: A fuel conversion reactor includes a shell-and-tube heat exchanger for controlling the temperature of a hot gaseous mixture produced by catalytic or non-catalytic reaction of a fuel with a gaseous fluid, and for controlling the temperature of the gaseous fluid and/or the fuel prior to the reaction. The reactor is either a catalytic or non-catalytic burner, or a fuel reformer for converting a fuel to hydrogen. A preferred reactor includes an outer shell having first and second ends and an inner surface, a primary inner shell extending into the outer shell, the primary inner shell defining a heat exchanging chamber and having primary and secondary ends, and a secondary inner shell having a first end located adjacent the secondary end of the primary inner shell. One or more outlet apertures are formed between the two inner shells for passage of the gaseous fluid out of the heat exchanging chamber. There are also a plurality of heat exchange tubes extending through the heat exchanging chamber between first and second tube sheets and connected to same. The first tube sheet is mounted in the primary inner shell while the second tube sheet is connected to the secondary inner shell. The tubes form passages for flow of the hot gaseous mixture in heat exchange contact with the gaseous fluid through the heat exchanging chamber, thereby preheating the gaseous fluid prior to reaction with the fuel. The adjacent ends of the inner shells form a disconnected joint and the secondary inner shell is free to move relative to the primary inner shell upon thermal expansion of the tubes.

Abstract translation: 燃料转化反应器包括管壳式热交换器，用于控制通过燃料与气体流体的催化或非催化反应产生的热气体混合物的温度，并用于控制气态流体的温度和/或 在反应之前的燃料。 反应器是催化或非催化燃烧器，或用于将燃料转化为氢的燃料重整器。 优选的反应器包括具有第一和第二端和内表面的外壳，延伸到外壳中的主内壳，限定热交换室并具有主端和次端的主内壳，以及具有 第一端位于主内壳的次级端附近。 在两个内壳之间形成一个或多个出口孔，用于使气态流体从热交换室通过。 还有多个热交换管，其延伸穿过第一和第二管板之间的热交换室并与之连接。 第一管板安装在主内壳中，而第二管板连接到副内壳。 管形成用于热气体混合物的流动的通道，其与气态流体通过热交换室进行热交换接触，从而在与燃料反应之前预热气态流体。 内壳的相邻端形成断开的接头，并且辅管内壳在管的热膨胀时相对于主内壳自由移动。

公开(公告)号：US20070092436A1

公开(公告)日：2007-04-26

申请号：US11523805

申请日：2006-09-20

Applicant: Alexandre Rojey ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Eric Lenglet

Inventor： Alexandre Rojey ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Eric Lenglet

IPC: C01B3/26

CPC classification number: C01B3/384 ,  B01J8/067 ,  B01J2208/00221 ,  C01B3/382 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/0805 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0844 ,  C01B2203/1241 ,  C01B2203/1294 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  Y02P20/128

Abstract: The invention concerns a process for producing synthesis gas, SG, from hydrocarbons and/or recycled compounds, in which: a stream comprising a first feed F1 supplemented with steam undergoes steam reforming in a multi-tube reactor-exchanger R with reaction tubes (38) containing a steam reforming catalyst, and with a shell; the reaction tubes are heated by convection by circulating in the shell, in overall counter-current mode, a heating fluid HF external to said tubes, which fluid comprises a first combustion gas stream of a second feed F2, then said fluid HF is mixed in a complementary combustion zone (32, 34) internal to the shell with a third feed F3 and a gas comprising oxygen, to increase the temperature of the HF, then the stream of mixture obtained circulates in R to heat the reaction tubes in a complementary manner; SG is produced from the steam reforming effluent from F1 and optionally part or all of the HF.

Abstract translation: 本发明涉及从烃和/或再循环化合物生产合成气SG的方法，其中：包含补充有蒸汽的第一进料F 1的流在具有反应管的多管反应器 - 交换器R中进行蒸汽重整 38），其含有蒸汽重整催化剂和壳; 反应管通过在外壳中以总体逆流模式循环加热，在所述管外部的加热流体HF，该流体包括第二进料F 2的第一燃烧气体流，然后将所述流体HF混合 在具有第三进料F 3和包含氧的气​​体的壳体内部的互补燃烧区域（32,34）中，为了增加HF的温度，则获得的混合物流在R中循环以在反应管中加热 互补的方式 SG由来自F 1的蒸汽重整流出物和可选的部分或全部HF产生。

公开(公告)号：US20070036697A1

公开(公告)日：2007-02-15

申请号：US10482398

申请日：2003-12-31

Applicant: Friedrich Gutlhuber ,  Manfred Lehr ,  Gunnar Heydrich ,  Gunther Windecker ,  Stephan Schlitter ,  Michael Hesse ,  Markus Rosch ,  Alexander Weck ,  Rolf Fischer

Inventor： Friedrich Gutlhuber ,  Manfred Lehr ,  Gunnar Heydrich ,  Gunther Windecker ,  Stephan Schlitter ,  Michael Hesse ,  Markus Rosch ,  Alexander Weck ,  Rolf Fischer

IPC: B01J19/00 ,  F28D21/00

CPC classification number: B01J8/067 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/0053 ,  B01J2208/00849 ,  B01J2219/00259 ,  F28D7/0066 ,  F28D7/0091 ,  F28F9/22

Abstract: A multi-zone jacketed pipe reactor (2; 60; 90; 130) for carrying out exothermic gaseous phase reactions and with at least one reaction zone (I) working with vaporisation cooling, at least one reaction zone (II) working with circulation cooling and, possibly, with additional zones (III, IV) is characterised in that one reaction zone (I) working with vaporisation cooling forms the first reaction zone to which is connected an additional reaction zone (II) working with circulation cooling. In this way there occurs at the beginning of the reaction, when the latter is most violent, very intensive cooling at a precisely controllable temperature and especially as well a temperature that is constant across the entire cross-section of the reactor while subsequently in a subsequent reaction zone working with circulating cooling by means of global counter-flow guidance of the heat transfer agent a constant cooling of the reaction gas is achieved.

Abstract translation: 用于进行放热气相反应的多区夹套管式反应器（2; 60; 90; 130）和至少一个用蒸发冷却工作的反应区（I），至少一个循环冷却工作的反应区（II） 并且可能地具有另外的区域（III，IV），其特征在于用蒸发冷却工作的一个反应区域（I）形成连接有循环冷却工作的附加反应区域（II）的第一反应区域。 以这种方式，在反应开始时发生，当后者在精确控制的温度下是最猛烈的，非常强烈的冷却，特别是在反应器的整个横截面上恒定的温度，随后在随后的 反应区域通过传热剂的全局逆流引导进行循环冷却，实现了反应气体的恒定冷却。

公开(公告)号：US20070000172A1

公开(公告)日：2007-01-04

申请号：US11167590

申请日：2005-06-28

Applicant: Michael Boe ,  John Hansen

Inventor： Michael Boe ,  John Hansen

IPC: B01J8/00

CPC classification number: C01B3/384 ,  B01J8/0242 ,  B01J8/0285 ,  B01J8/0446 ,  B01J8/0453 ,  B01J8/0469 ,  B01J8/048 ,  B01J8/0492 ,  B01J8/0496 ,  B01J8/06 ,  B01J8/065 ,  B01J8/067 ,  B01J19/2495 ,  B01J19/26 ,  B01J2208/00106 ,  B01J2208/00132 ,  B01J2208/00185 ,  B01J2208/00203 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00274 ,  B01J2208/00283 ,  B01J2208/00309 ,  B01J2208/00495 ,  B01J2208/00504 ,  B01J2208/0053 ,  C01B3/505 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0405 ,  C01B2203/041 ,  C01B2203/043 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0833 ,  C01B2203/0866 ,  C01B2203/1217 ,  F28D15/0266 ,  Y02P20/128

Abstract: Reforming reactor for the conversion of a process fluid into hydrogen comprising: a reforming section which is contained within a closed volume, a boiler section and a combustion section, in which said reforming section contains one or more catalyst tubes filled with reforming catalyst, said boiler section is provided with one or more flow channels for the passage of flue gas from the combustion section and said combustion section is provided with at least one burner, wherein the heat exchanging medium required for the reforming of said process fluid in the one or more catalyst tubes is a gas-liquid mixture that self-circulates and is encapsulated inside said closed volume and wherein at least a portion of said closed volume protrudes inside said boiler section.

公开(公告)号：US20060230680A1

公开(公告)日：2006-10-19

申请号：US11453001

申请日：2006-06-15

Applicant: Thomas Rostrup-Nielsen ,  Erik Logsted-Nielsen

Inventor： Thomas Rostrup-Nielsen ,  Erik Logsted-Nielsen

IPC: C01B3/24

CPC classification number: C01B3/501 ,  B01J8/009 ,  B01J8/067 ,  B01J2208/00212 ,  B01J2208/00221 ,  C01B3/16 ,  C01B2203/0283 ,  C01B2203/041 ,  C01B2203/0475 ,  C01B2203/0888 ,  C01B2203/0894 ,  F28D3/02 ,  F28D3/04 ,  Y02P20/52

Abstract: Process and reaction unit for isothermal shift conversion of a carbon monoxide containing feed gas, the process comprising the steps of introducing the feed gas in a reaction unit into reactor tubes with a fixed bed of a shift conversion catalyst in a reaction zone; contacting the feed gas with the catalyst at conditions being effective in carbon monoxide shift conversion reaction with steam reactant to hydrogen and cooling the reaction by indirect heat exchange with a cooling agent by passing the cooling agent in a falling film along shell side of the reactor tubes and removing heated cooling agent from the falling film; passing hydrogen when it is formed by the shift conversion reaction through a hydrogen selective membrane to a permeate zone; withdrawing hydrogen from the permeate zone and carbon monoxide depleted feed gas from the reaction zone.

公开(公告)号：US07067695B2

公开(公告)日：2006-06-27

申请号：US11064020

申请日：2005-02-23

Applicant: Shuhei Yada ,  Hirochika Hosaka ,  Kimikatsu Jinno

Inventor： Shuhei Yada ,  Hirochika Hosaka ,  Kimikatsu Jinno

IPC: C07C51/21

CPC classification number: C07C51/215 ,  B01J8/067 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/0023 ,  C07C45/33 ,  C07C45/35 ,  C07C51/00 ,  C07C51/252 ,  C07C47/22 ,  C07C57/04

Abstract: An object of the present invention is to provide a method of vapor phase catalytic oxidation which is capable of: efficiently removing heat of reaction; preventing the formation of hot spots; and efficiently providing a desired product. The invention provides a method of vapor phase catalytic oxidation of a substance to be oxidized with a gas containing molecular oxygen by means of a multitubular reactor, wherein the method comprises: performing a reaction of vapor phase catalytic oxidation under such conditions that a heat transfer coefficient of the heat medium is 1,000 W/(m2·K) or higher.

Abstract translation: 本发明的目的是提供一种气相催化氧化方法，其能够有效地除去反应热; 防止热点形成; 并有效地提供期望的产品。 本发明提供了一种通过多管反应器的含有分子氧气体进行氧化的物质的气相催化氧化方法，其中所述方法包括：在这样的条件下进行气相催化氧化反应：传热系数 的热介质为1000W /（m 2·2K）以上。