公开(公告)号：US20170275219A1

公开(公告)日：2017-09-28

申请号：US15504979

申请日：2015-08-17

申请人： SABIC Global Technologies B.V.

发明人： Zeeshan Nawaz ,  Faisal Baksh ,  Adel Abdullah Al-Ghamdi

IPC分类号： C07C5/333

CPC分类号： C07C5/3337 ,  B01J23/26 ,  B01J23/42 ,  B01J23/6522 ,  B01J23/92 ,  B01J23/94 ,  B01J38/02 ,  B01J38/12 ,  C07C5/3332 ,  C07C5/3335 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/652 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/107 ,  C07C11/08 ,  C07C11/06 ,  C07C11/09 ,  C07C11/04

摘要： The presently disclosed subject matter relates to methods and systems for alkane dehydrogenation. In a particular non-limiting embodiment, the presently disclosed subject matter provides a system for the dehydrogenation of alkanes that includes two or more reactors configured to perform a dehydrogenation reaction of an alkane in the presence of a catalyst to produce an olefin and a catalyst regenerator, coupled to each of the two or more reactors through at least one transfer line to a regenerator, for the regeneration of spent catalyst.

公开(公告)号：US20170247302A1

公开(公告)日：2017-08-31

申请号：US15507985

申请日：2015-09-23

申请人： Haldor Topsøe A/S

发明人： Poul Erik Højlund Nielsen ,  John Bøgild Hansen

IPC分类号： C07C5/333

CPC分类号： C07C5/3332 ,  C07C5/46 ,  C07C2521/02 ,  C07C2521/10 ,  C07C2527/043 ,  C07C2527/047 ,  C07C2527/049 ,  C07C2527/051 ,  C07C15/46 ,  C07C11/06

摘要： Process for dehydrogenation of alkanesor alkylbenzenes by using metal sulfide catalyst under the presence of small amounts of hydrogen sulfide.

公开(公告)号：US09738570B1

公开(公告)日：2017-08-22

申请号：US15492567

申请日：2017-04-20

申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

发明人： Mohammad Ashraf Ali ,  Shakeel Ahmed

IPC分类号： B01J29/06 ,  B01J29/70 ,  B01J29/40 ,  B01J35/04 ,  B01J35/00 ,  B01J38/12 ,  C07C1/20 ,  B01J35/10 ,  B01J35/02

CPC分类号： C07C1/20 ,  B01J29/06 ,  B01J29/40 ,  B01J29/90 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0215 ,  B01J37/0246 ,  B01J37/08 ,  B01J38/12 ,  C07C2529/06 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04 ,  C07C11/08

摘要： A catalyst system and a process for methanol to light olefin conversion with enhanced selectivity towards propylene. The catalyst system comprises a honeycomb monolith catalyst support coated with aluminosilicate nanozeolite catalysts on the edges and inside the channels of the support structure. The aluminosilicate nanozeolite catalysts have not been pre-modified with a promoter metal. The catalyst system gives higher hydrothermal stability to the catalyst compared to randomly packed pellet catalysts and allows methanol to be converted to predominantly propylene at a low temperature, with decreased selectivity towards C2, higher olefins and paraffinic hydrocarbons.

公开(公告)号：US20170226028A1

公开(公告)日：2017-08-10

申请号：US15519419

申请日：2015-10-14

申请人： Gevo, Inc.

发明人： Jonathan O. SMITH ,  Nicholas MCGUIRE ,  Leo E. MANZER ,  Madeline SJODIN ,  Paul STARKEY ,  Caroline SALAZAR

IPC分类号： C07C1/24 ,  C07C2/52 ,  C08F236/08 ,  C10L1/04 ,  C07C45/00 ,  C07C67/03 ,  C07C51/16 ,  C07C2/06 ,  C07C45/51

CPC分类号： C07C1/24 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J37/0018 ,  B01J37/03 ,  B01J37/082 ,  C07C1/20 ,  C07C2/06 ,  C07C2/52 ,  C07C45/00 ,  C07C45/512 ,  C07C51/16 ,  C07C67/03 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2523/34 ,  C08F236/08 ,  C10L1/04 ,  C10L2200/04 ,  C10L2270/04 ,  Y02P20/132 ,  Y02P20/52 ,  C07C11/09 ,  C07C11/06 ,  C07C49/08

摘要： This application relates to the production of functionalized lower hydrocarbons and more particularly to the process of converting ethanol to functionalized lower hydrocarbons. In particular embodiments, the ethanol to functionalized lower hydrocarbon conversion is catalyzed by a ZnxZryAvQsMnwOz mixed oxide catalyst or a bifunctional heterogeneous catalyst. In particular embodiments, the ethanol to be converted is present at molar concentrations in the reactor feed equal to or exceeding 14%.

公开(公告)号：US09707533B2

公开(公告)日：2017-07-18

申请号：US14955344

申请日：2015-12-01

申请人： Dow Global Technologies LLC

发明人： Matthew T. Pretz

IPC分类号： B01J8/34

CPC分类号： B01J8/34 ,  B01J8/0055 ,  B01J2208/00991 ,  C07C5/333 ,  C10G11/08 ,  C07C11/06

摘要： A fluidized catalyst stripping unit for displacing entrained gas from catalyst particles comprising: a vessel housing a two stage cyclonic separation section which comprises one or more primary cyclonic separation devices and one or more secondary cyclones; a stripping section which comprises internals; and an inlet in fluid communication with a catalytic reactor to feed a particulate-fluid suspension to the two stage cyclonic separation section; wherein each primary cyclonic separation device comprises an internal cylindrical surface to separate a major fraction of the particulates from the suspension and form a vortex of reduced particulate content; a particulate discharge outlet from each secondary cyclone to the stripping section; wherein the particulate discharge outlet of the secondary cyclone is submerged in a catalyst bed located above the stripper internals, and wherein the stripping section comprises one or more bubble breaking grids within the catalyst bed and above the stripping internals is provided.

公开(公告)号：US09682367B2

公开(公告)日：2017-06-20

申请号：US14520978

申请日：2014-10-22

申请人： King Fahd University of Petroleum and Minerals

发明人： Mohammad Ashraf Ali ,  Shakeel Ahmed

IPC分类号： B01J35/04 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  B01J29/06 ,  B01J29/70 ,  B01J29/76 ,  B01J29/78 ,  C07C1/20

CPC分类号： B01J29/78 ,  B01J23/74 ,  B01J29/072 ,  B01J29/076 ,  B01J29/46 ,  B01J29/76 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0246 ,  B01J37/08 ,  C07C1/20 ,  C07C2529/46 ,  C07C2529/48 ,  C07C2529/76 ,  C07C2529/78 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/06

摘要： A catalyst system and a process for methanol to light olefin conversion with enhanced selectivity towards propylene. The catalyst system comprises a honeycomb monolith catalyst support coated with nanozeolite catalysts on the edges and inside the channels of the support structure. The nanozeolite catalysts have been pre-modified with metal. The catalyst system gives higher hydrothermal stability to the catalyst compared to randomly packed pellet catalyst and allows methanol to be converted to predominantly propylene at a low temperature, with decreased selectivity towards C2, higher olefins and paraffinic hydrocarbons.

公开(公告)号：US20170136445A1

公开(公告)日：2017-05-18

申请号：US15252733

申请日：2016-08-31

申请人： Saudi Arabian Oil Company

发明人： Michele L. Ostraat ,  Brian S. Hanna

IPC分类号： B01J23/30 ,  B01J21/08 ,  C07C5/22 ,  B01J35/10 ,  B01J37/08 ,  C07C6/04 ,  B01J21/12 ,  B01J37/02

CPC分类号： B01J23/30 ,  B01J21/08 ,  B01J21/12 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/08 ,  B01J2229/42 ,  C07C5/2213 ,  C07C5/2512 ,  C07C6/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/30 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08

摘要： Embodiments of a method of synthesizing a metathesis and isomerization catalyst or metathesis catalyst or isomerization catalyst comprises forming a catalyst precursor solution comprising a diluent and a catalyst precursor where the catalyst precursor comprises at least one of a silica precursor and an alumina precursor for the isomerization catalyst and additionally an oxometallate precursor or metal oxide precursor for the metathesis catalyst or the metathesis and isomerization catalyst, where the catalyst precursor solution is absent a surfactant; aerosolizing the catalyst precursor solution; drying the aerosolized catalyst precursor mixture to form a dried catalyst precursor; and reacting the dried catalyst precursor to yield the metathesis and isomerization catalyst or the metathesis catalyst or the isomerization catalyst, the metathesis and isomerization catalyst comprising a silica and alumina support with an oxometallate or a metal oxide distributed within the silica and alumina support.

公开(公告)号：US09643897B2

公开(公告)日：2017-05-09

申请号：US14636718

申请日：2015-03-03

申请人： UOP LLC

发明人： Deng-Yang Jan ,  Nicholas J. Schoenfeldt ,  Jaime G. Moscoso

IPC分类号： C07C1/20 ,  B01J29/40 ,  C07C4/02 ,  C07C6/04 ,  C01B39/36 ,  B01J29/90 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10

CPC分类号： C07C1/20 ,  B01J29/40 ,  B01J29/90 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1057 ,  B01J35/1061 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/42 ,  C01B39/36 ,  C07C4/02 ,  C07C6/04 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06

摘要： A process for oxygenate conversion using a family of crystalline aluminosilicate zeolites that is a layered pentasil zeolite with a silica or fluorine modified surface. These zeolites are represented by the empirical formula: Mmn+Rrp+Al1-xExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as sodium or potassium, R can be a mixture of organoammonium cations and E is a framework element such as gallium, iron, boron, or indium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out oxygenate conversion processes.

公开(公告)号：US09643167B2

公开(公告)日：2017-05-09

申请号：US14628179

申请日：2015-02-20

申请人： ASAHI KASEI CHEMICALS CORPORATION

发明人： Kenji Akagishi ,  Hiroyuki Yano ,  Ryusuke Miyazaki

IPC分类号： B01J29/06 ,  C07C1/20 ,  C07C2/00 ,  C07C4/00 ,  C07C5/00 ,  B01J29/70 ,  B01J21/08 ,  B01J29/40 ,  B01J35/02 ,  B01J37/00 ,  C07C6/04

CPC分类号： B01J29/70 ,  B01J21/08 ,  B01J29/06 ,  B01J29/40 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/42 ,  C07C2/00 ,  C07C6/04 ,  C07C2521/08 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  C07C11/06

摘要： The present invention provides a zeolite-containing catalyst having excellent shape, fluidity and mechanical strength as a catalyst for a fluidized bed reaction. The present invention provides a zeolite-containing catalyst which is a particulate catalyst containing zeolite and silica, wherein the catalyst has an average particle diameter of 20 to 300 μm and the ratio of the void area in the cross-section of the particle is 30% or less relative to the cross-section area of the particle.

公开(公告)号：US09643164B2

公开(公告)日：2017-05-09

申请号：US14894561

申请日：2014-06-25

申请人： Dow Global Technologies LLC

发明人： Thomas Davidian ,  Matthijs Ruitenbeek ,  Adrianus Koeken ,  Marjolein Vos ,  Marco F. Wielemaker

IPC分类号： B01J37/18 ,  B01J27/22 ,  B01J23/78 ,  C07C1/04 ,  C10G2/00 ,  B01J37/08 ,  B01J37/02 ,  B01J35/00 ,  B01J35/02

CPC分类号： B01J27/22 ,  B01J23/78 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0205 ,  B01J37/084 ,  B01J37/18 ,  C07C1/0445 ,  C07C2521/04 ,  C07C2523/745 ,  C10G2/332 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06

摘要： A Fischer-Tropsch catalyst, useful for conversion of synthesis gas to olefins, is prepared from a catalyst precursor composition including iron oxide and an alkali metal on a substantially inert support, and then treated by a process including as ordered steps (1) reduction in a hydrogen-containing atmosphere at a pressure of 0.1 to 1 M Pa and a temperature from 280° C. to 450° C.; (2) carburization in a carbon monoxide-containing atmosphere at a pressure from 0.1 to 1 M Pa and a temperature from 200° C. to less than 340° C.; and (3) conditioning in a hydrogen- and carbon monoxide-containing atmosphere at a pressure from 0.1 to 2 MPa and a temperature from 280° C. to 340° C. The resulting catalyst exhibits at least one improvement selected from (1) increased overall activity; (2) reduced break-in time; (3) slowed rate of deactivation; and (4) increased time to onset of deactivation; when compared to an otherwise identical catalyst precursor composition treated by one or some, but not all, of the given steps and/or under different conditions.