PROCESS FOR THE PREPARATION OF AN OLEFINIC PRODUCT COMPRISING ETHYLENE AND/OR PROPYLENE
    31.
    发明申请
    PROCESS FOR THE PREPARATION OF AN OLEFINIC PRODUCT COMPRISING ETHYLENE AND/OR PROPYLENE 有权
    制备包含乙烯和/或丙烯的烯烃产品的方法

    公开(公告)号:US20140187824A1

    公开(公告)日:2014-07-03

    申请号:US14136047

    申请日:2013-12-20

    申请人: Shell Oil Company

    IPC分类号: C07C1/22

    摘要: An oxygenate to olefins (OTO) process, comprising the steps of: (i) purifying an oxygenate feedstream comprising one or more ionic contaminants by contacting the feedstream with a membrane, resulting in the formation of a retentate and a permeate separated by the membrane, which permeate is a purified oxygenate stream which contains a lower ionic contaminant concentration than the original oxygenate feedstream; (ii) introducing the purified oxygenate stream into an oxygenate to olefins reaction zone; and (iii) contacting the purified oxygenate stream with a molecular sieve catalyst in the oxygenate to olefins reaction zone to form a product stream comprising olefins.

    摘要翻译: 一种含氧化合物至烯烃(OTO)方法,包括以下步骤:(i)通过使进料流与膜接触,纯化含有一种或多种离子污染物的含氧物原料流,导致形成由膜分离的渗余物和渗透物, 该渗透物是纯化的含氧化合物流,其含有比原始含氧化合物进料流更低的离子污染物浓度; (ii)将纯化的含氧物流引入含氧化合物至烯烃反应区; 和(iii)将纯化的含氧物流与含氧化合物中的分子筛催化剂接触到烯烃反应区,以形成包含烯烃的产物流。

    PROCESS FOR THE PREPARATION OF OLEFINS
    32.
    发明申请
    PROCESS FOR THE PREPARATION OF OLEFINS 审中-公开
    制备油脂的方法

    公开(公告)号:US20130225894A1

    公开(公告)日:2013-08-29

    申请号:US13597451

    申请日:2012-08-29

    IPC分类号: C07C1/22

    摘要: Process for the preparation of olefins, which process comprising introducing an oxygenate and/or olefinic feed through introduction means into a reactor; reacting the oxygenate and/or olefinic feed in the reactor in the presence of a molecular sieve catalyst to form a mixture with a resulting gas superficial velocity which mixture comprises olefins and at least partially coked catalyst; separating olefins and at least partially coked catalyst; recovering olefins; and controlling the gas superficial velocity of the mixture at a predetermined level in the reactor on the basis of the inlet mass gas flow rate of the feed.

    摘要翻译: 制备烯烃的方法,该方法包括通过引入装置将含氧化合物和/或烯烃进料引入反应器中; 使反应器中的含氧化合物和/或烯烃进料在分子筛催化剂的存在下反应以形成具有所得气体空塔速度的混合物,该混合物包含烯烃和至少部分焦化的催化剂; 分离烯烃和至少部分焦化的催化剂; 回收烯烃; 并基于进料的入口质量气体流量,将反应器中混合物的气体空塔速度控制在预定水平。

    Systems including catalysts in porous zeolite materials within a reactor for use in synthesizing hydrocarbons
    33.
    发明授权
    Systems including catalysts in porous zeolite materials within a reactor for use in synthesizing hydrocarbons 有权
    包括在用于合成烃的反应器内的多孔沸石材料中的催化剂的体系

    公开(公告)号:US08226909B2

    公开(公告)日:2012-07-24

    申请号:US12970689

    申请日:2010-12-16

    IPC分类号: B01J8/02 B01J8/06

    摘要: Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

    摘要翻译: 催化结构包括设置在沸石材料内的催化材料。 催化材料可能能够催化从一氧化碳和/或二氧化碳形成甲醇,并且沸石材料可以能够催化甲醇形成烃分子。 催化材料可以包括铜和氧化锌。 沸石材料可以包括基本上由沸石材料的晶体结构限定的第一多个孔和分散在整个沸石材料中的第二多个孔。 合成烃分子的系统还包括催化结构。 合成烃分子的方法包括使氢和一氧化碳和二氧化碳中的至少一种与这种催化结构接触。 催化结构通过至少部分地围绕模板结构形成沸石材料,去除模板结构以及将催化材料引入到沸石材料中来制造。

    Dual-zeolite catalyst for production of ethylbenzene
    35.
    发明申请
    Dual-zeolite catalyst for production of ethylbenzene 有权
    用于生产乙苯的双沸石催化剂

    公开(公告)号:US20110201864A1

    公开(公告)日:2011-08-18

    申请号:US12656905

    申请日:2010-02-18

    IPC分类号: C07C1/20 B01J29/06

    摘要: The dual-zeolite catalyst for production of ethylbenzene is formed by mixing at least two different zeolites selected from mordenite, beta, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, SAPO-5, SAPO-34, SAPO-11 and MAPO-36 zeolites and an inactive alumina binder. The two zeolites have different topology and possess dissimilar and unique physical and chemical characteristics, including particle size, surface area, pore size and acidity. The preferred amount of the two zeolites may range from 10 to 90 wt % of the total catalyst amount in the final dried and calcined form, preferably the zeolites are in equal parts by weight.

    摘要翻译: 用于生产乙苯的双沸石催化剂是通过混合选自丝光沸石,β,ZSM-5,ZSM-11,ZSM-12,ZSM-22,ZSM-23,MFI拓扑沸石,NES拓扑的至少两种不同的沸石形成的 沸石,EU-1,SAPO-5,SAPO-34,SAPO-11和MAPO-36沸石和无活性氧化铝粘合剂。 两种沸石具有不同的拓扑结构,具有不同和独特的物理化学特性,包括粒度,表面积,孔径和酸度。 两种沸石的优选量可以是最终干燥和煅烧形式的总催化剂量的10至90重量%,优选沸石的重量百分比相等。

    Hydrocarbon separation
    36.
    发明授权
    Hydrocarbon separation 有权
    烃分离

    公开(公告)号:US07777089B2

    公开(公告)日:2010-08-17

    申请号:US11634070

    申请日:2006-12-06

    IPC分类号: C07C7/12

    摘要: Process for the separation of close boiling isomeric compounds comprising distilling a dilute solution of isomers in a high boiling compound in the presence of a solid adsorbent. Multi and/or monobranched as well as cyclic isomers are withdrawn at the top of the distillation column, while straight chain and/or mono branched isomers are retained within the solid adsorbent. The diluent solution of the high boiling compound is withdrawn from the bottom of the distillation column and recycled, where it may be combined with the feed isomer mixture or recycled straight to the top of the adsorption column.

    摘要翻译: 分离近沸异构体化合物的方法,包括在固体吸附剂存在下在高沸点化合物中蒸馏出各种异构体的稀溶液。 多个和/或单链和环状异构体在蒸馏塔的顶部排出,而直链和/或单支链异构体保留在固体吸附剂内。 将高沸点化合物的稀释溶液从蒸馏塔的底部排出并再循环,其中可与进料异构体混合物混合或直接再循环至吸附塔的顶部。

    Method of fabricating a catalytic structure
    38.
    发明授权
    Method of fabricating a catalytic structure 有权
    制造催化结构的方法

    公开(公告)号:US07592291B2

    公开(公告)日:2009-09-22

    申请号:US11688930

    申请日:2007-03-21

    IPC分类号: B01J23/06 B01J23/72 B01J35/08

    摘要: A precursor to a catalytic structure comprising zinc oxide and copper oxide. The zinc oxide has a sheet-like morphology or a spherical morphology and the copper oxide comprises particles of copper oxide. The copper oxide is reduced to copper, producing the catalytic structure. The catalytic structure is fabricated by a hydrothermal process. A reaction mixture comprising a zinc salt, a copper salt, a hydroxyl ion source, and a structure-directing agent is formed. The reaction mixture is heated under confined volume conditions to produce the precursor. The copper oxide in the precursor is reduced to copper. A method of hydrogenating a carbon oxide using the catalytic structure is also disclosed, as is a system that includes the catalytic structure.

    摘要翻译: 包含氧化锌和氧化铜的催化结构的前体。 氧化锌具有片状形态或球形形态,氧化铜包含氧化铜颗粒。 氧化铜被还原成铜,产生催化结构。 催化结构通过水热法制备。 形成包含锌盐,铜盐,羟基离子源和结构导向剂的反应混合物。 将反应混合物在有限体积条件下加热以产生前体。 前体中的氧化铜还原成铜。 还公开了使用催化结构使碳氧化物氢化的方法,以及包括催化结构的体系。