Fertilizer production from fossil fuel with minimal carbon dioxide emission
    36.
    发明授权
    Fertilizer production from fossil fuel with minimal carbon dioxide emission 失效
    来自化石燃料的肥料生产,二氧化碳排放量最小

    公开(公告)号:US07641881B2

    公开(公告)日:2010-01-05

    申请号:US11733185

    申请日:2007-04-09

    申请人: Meyer Steinberg

    发明人: Meyer Steinberg

    摘要: An ammonia and fertilizer production process is based on partial oxidation of fossil fuel, which co-produces polycarbonsuboxide. The four step process is low-cost and low-carbon-dioxide emission. It comprises the steps of reacting fossil fuel with oxygen in air and steam in an electric discharge plasma to produce a gas exit stream of polycarbonsuboxide, hydrogen with associated nitrogen (110); cooling the gas stream to condense and separate the polycarbonsuboxide as a solid polymer (120); compressing the gas stream to pressures for synthesis of ammonia (140); and, converting the gas stream to ammonia by employing a catalytic converter (150). Optional steps involve gas cleanup, which include removal of contaminants from the gas stream and adding hydrogen or nitrogen to the gas stream to adjust the ratio of hydrogen to nitrogen to three to one, respectively, prior to converting the gas stream to ammonia (130).

    摘要翻译: 氨和肥料生产过程是基于化学燃料的部分氧化,其共同生产聚碳代内酯。 四步骤是低成本和低二氧化碳排放。 它包括在放电等离子体中使化石燃料与空气中的氧气和蒸汽反应以产生聚碳氮化烃的气体出口流,具有相关氮气的氢气(110); 冷却气流以冷凝和分离作为固体聚合物(120)的聚碳氧化脲; 将气流压缩成合成氨的压力(140); 并且通过使用催化转化器(150)将气流转化成氨。 可选步骤涉及气体净化,其包括在将气流转化为氨之前分别从气流中除去污染物并向气流中加入氢气或氮气以将氢气与氮气的比例调节至三比一, 。

    Method of defluorinating phosphates
    37.
    发明授权
    Method of defluorinating phosphates 失效
    氟化磷酸盐的方法

    公开(公告)号:US4405575A

    公开(公告)日:1983-09-20

    申请号:US371333

    申请日:1982-04-23

    摘要: This invention comprises a method for removing fluorine from natural phosphates, superphosphate materials and wet process phosphoric acids starting materials comprising(a) admixing rock phosphate having a fluorine content above that desired with an acid mixture within the range of rock:acid mixture of about 0.8 to 1 and 1:1.4 by weight;(b) said acid mixture being substantially concentrated phosphoric acid and concentrated sulfuric acid in a range of phosphoric:sulfuric of about 1:1 to 5:1 by weight;(c) said admixing being at a temperature in the range of 215.degree. to 265.degree. F. while adding water in an amount of up to about 12% by weight of the total mixture and then subjecting the above charge;(d) in a first heating stage adding (1) recycle in an amount substantially of recycle to charge of 1:1 to 10:1 by weight (2) and water while heating to a temperature in the range of 300.degree. F. to 400.degree. F. for a period of time up to about 6 minutes;(e) and in a second heating stage, maintaining the temperature in the range of 400.degree. to 600.degree. F. for a period of time of up to about 6 mimutes, and then;(f) quickly cooling the resulting product above to a temperature range below about 300.degree. F. to 200.degree. F. while neutralizing to about 1 to 6% free acid and with addition of at least sufficient amount of water to have water of hydration of substantially 2 to 9% by weight in the final product;(g) and, crushing the above resulting product to a desired granular size and separating and returning smaller fine particles as recycle.

    摘要翻译: 本发明包括从天然磷酸盐,过磷酸盐材料和湿法磷酸起始材料中除去氟的方法,其包括(a)将具有高于所需值的氟含量的磷酸盐与酸混合物混合在约0.8的岩石:酸混合物的范围内 至1和1:1.4; (b)所述酸混合物是基本浓缩的磷酸和浓硫酸的重量比为约1:1至5:1的磷酸:硫酸; (c)所述混合物在215-265°F的温度范围内,同时加入最多达总混合物重量的约12%的水,然后对上述电荷进行处理; (d)在第一加热阶段中,加入(1)基本上循环量为1:1至10:1(重量)和水的循环量,同时加热到300°F的温度至 400°F,时间长达约6分钟; (e),在第二加热阶段,将温度保持在400〜600°F的范围内,时间可达6乇左右。 (f)将所得产物快速冷却至低于约300°F至200°F的温度范围,同时中和至约1至6%游离酸,并加入至少足够量的水以使水合水 在最终产品中基本上为2至9重量% (g),并将上述所得产物粉碎成所需的颗粒尺寸,并分离和返回较小的微粒作为再循环。

    Production of potassium polyphosphates from potassium silicofluorides
    38.
    发明授权
    Production of potassium polyphosphates from potassium silicofluorides 失效
    从硅酸钾生产多磷酸钾

    公开(公告)号:US4137063A

    公开(公告)日:1979-01-30

    申请号:US810002

    申请日:1977-06-24

    申请人: John B. Sardisco

    发明人: John B. Sardisco

    IPC分类号: C05B13/06 C05B21/00 C05B11/04

    CPC分类号: C05B13/06

    摘要: Potassium polyphosphate polymers having ratios of P.sub.2 O.sub.5 to K.sub.2 O which make them suitable as fertilizer products are prepared by reacting potassium fluosilicate also known as potassium silicofluoride with phosphoric acid and sulfuric acid at temperatures of about 250-500.degree. C.

    摘要翻译: 通过在约250-500℃的温度下,也称为氟硅酸钾的氟硅酸钾与磷酸和硫酸反应制备具有适合作为肥料产品的P2O5至K2O比例的聚磷酸钾聚合物。

    Landfill and soil conditioner
    39.
    发明授权
    Landfill and soil conditioner 失效
    垃圾填埋场和土壤调理剂

    公开(公告)号:US3932166A

    公开(公告)日:1976-01-13

    申请号:US470330

    申请日:1974-05-15

    摘要: A method for converting organic waste materials into inert humus-like materials by charring the organic waste materials by heating and drying same in the presence of certain water-soluble inorganic acids, removing residual acid and other water-soluble contaminants by washing the crude char product with water, and utilizing the resulting inert material as a landfill. If desired, the humus-like char products can be reacted with an alkali at elevated temperatures, and the resulting alkali salts of humic-acid-like materials can be mixed with the soil to provide an improved and/or fertilized topsoil.

    摘要翻译: 通过在某些水溶性无机酸的存在下加热和干燥有机废物来将有机废物转化为惰性腐殖质材料的方法,通过洗涤粗制焦炭产物去除残留的酸和其它水溶性污染物 并用所得到的惰性材料作为填埋场。 如果需要,腐殖质状的焦炭产物可以在升高的温度下与碱反应,并且所得到的腐殖酸类物质的碱式盐可与土壤混合以提供改良的和/或受精的表土。