摘要:
An aqueous modified acid composition for industrial activities, said composition comprising: an alkanolamine and strong acid in a molar ratio of not less than 1:15, preferably not less than 1:10; it can also further comprise a metal iodide or iodate. Said composition demonstrates advantages over known conventional acids and modified acids.
摘要:
The invention relates to phosphate compounds obtained according to a method comprising reaction of a source of insoluble phosphate with an organic source, principally of vegetable origin, optionally in the presence of a mineral acid or an organic acid, said organic source having at least 10% of complexing functional groups.The compounds of the invention are useful for preparing fertilizer.
摘要:
An ammonia and fertilizer production process is based on partial oxidation of fossil fuel, which co-produces polycarbonsuboxide. The four step process is low-cost and low-carbon-dioxide emission. It comprises the steps of reacting fossil fuel with oxygen in air and steam in an electric discharge plasma to produce a gas exit stream of polycarbonsuboxide, hydrogen with associated nitrogen (110); cooling the gas stream to condense and separate the polycarbonsuboxide as a solid polymer (120); compressing the gas stream to pressures for synthesis of ammonia (140); and, converting the gas stream to ammonia by employing a catalytic converter (150). Optional steps involve gas cleanup, which include removal of contaminants from the gas stream and adding hydrogen or nitrogen to the gas stream to adjust the ratio of hydrogen to nitrogen to three to one, respectively, prior to converting the gas stream to ammonia (130).
摘要:
This invention comprises a method for removing fluorine from natural phosphates, superphosphate materials and wet process phosphoric acids starting materials comprising(a) admixing rock phosphate having a fluorine content above that desired with an acid mixture within the range of rock:acid mixture of about 0.8 to 1 and 1:1.4 by weight;(b) said acid mixture being substantially concentrated phosphoric acid and concentrated sulfuric acid in a range of phosphoric:sulfuric of about 1:1 to 5:1 by weight;(c) said admixing being at a temperature in the range of 215.degree. to 265.degree. F. while adding water in an amount of up to about 12% by weight of the total mixture and then subjecting the above charge;(d) in a first heating stage adding (1) recycle in an amount substantially of recycle to charge of 1:1 to 10:1 by weight (2) and water while heating to a temperature in the range of 300.degree. F. to 400.degree. F. for a period of time up to about 6 minutes;(e) and in a second heating stage, maintaining the temperature in the range of 400.degree. to 600.degree. F. for a period of time of up to about 6 mimutes, and then;(f) quickly cooling the resulting product above to a temperature range below about 300.degree. F. to 200.degree. F. while neutralizing to about 1 to 6% free acid and with addition of at least sufficient amount of water to have water of hydration of substantially 2 to 9% by weight in the final product;(g) and, crushing the above resulting product to a desired granular size and separating and returning smaller fine particles as recycle.
摘要:
Potassium polyphosphate polymers having ratios of P.sub.2 O.sub.5 to K.sub.2 O which make them suitable as fertilizer products are prepared by reacting potassium fluosilicate also known as potassium silicofluoride with phosphoric acid and sulfuric acid at temperatures of about 250-500.degree. C.
摘要:
A method for converting organic waste materials into inert humus-like materials by charring the organic waste materials by heating and drying same in the presence of certain water-soluble inorganic acids, removing residual acid and other water-soluble contaminants by washing the crude char product with water, and utilizing the resulting inert material as a landfill. If desired, the humus-like char products can be reacted with an alkali at elevated temperatures, and the resulting alkali salts of humic-acid-like materials can be mixed with the soil to provide an improved and/or fertilized topsoil.
摘要:
IN THE PARTICULAR EMBODIMENTS OF THE INVENTION DESCRIBED HEREIN, GAS-LIQUID REACTIONS ARE CARRIED OUT BY CONTINUOUSLY INJECTING THE NORMALLY GASEOUS REACTANT INTO A CONFINED STREAM OF THE LIQUID REACTANT AND PASSING THE GAS-LIQUID MIXTURE THROUGH A CONFINED TORTUOUS FLOW PATH SO AS TO INDUCE TURBULENCE IN THE MIXTURE. TYPICAL REACTIONS ARE AMMONIA-PHOSPHORIC ACID REACTIONS AND CHLORINATION AND HYDROGENATION REACTIONS.