公开(公告)号：US5415854A

公开(公告)日：1995-05-16

申请号：US81064

申请日：1993-06-22

Applicant: Serge Forestier ,  Gerard Lang ,  Herve Richard

Inventor： Serge Forestier ,  Gerard Lang ,  Herve Richard

IPC: A61K8/55 ,  A61K8/00 ,  A61K8/34 ,  A61K8/37 ,  A61K8/58 ,  A61K8/72 ,  A61K8/89 ,  A61K8/891 ,  A61K8/893 ,  A61K8/92 ,  A61Q1/00 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/10 ,  A61Q17/04 ,  C07F7/08 ,  C08G77/14 ,  C08G77/22 ,  C08G77/38 ,  C08L83/04 ,  C08L83/06 ,  C08L83/08 ,  A61K7/42 ,  A61K7/06

CPC classification number: A61Q17/04 ,  A61K8/893 ,  C08G77/38 ,  A61K2800/57 ,  Y10S424/05 ,  Y10S514/937 ,  Y10S514/944

Abstract: The cosmetic use is described, in particular for use as a UV filter, of benzalmalonate diorganopolysiloxanes having either formula: ##STR1## where R is C.sub.1 -C.sub.10 alkyl, phenyl or 3,3,3-trifluoropropyl, B is R or A, r=0-200, s=0-50, or formula: ##STR2## where u=1-20, t=0-20 and t+u.gtoreq.3. A and/or B represent an alkylene or alkyleneoxy benzalmalonate which may be substituted.

Abstract translation: 描述了特别用作UV过滤器的具有下式的苯甲丙二酸二有机聚硅氧烷的化妆品用途：其中R是C1-C10烷基，苯基或3,3,3-三氟丙基，B是R或 A，r = 0-200，s = 0-50或式：A和/或B表示可被取代的亚烷基或亚烷基氧基亚丙基丙二酸酯。

公开(公告)号：USRE34300E

公开(公告)日：1993-07-06

申请号：US566109

申请日：1990-08-13

Applicant: Alex Junino ,  Jean J. Vandenbossche ,  Herve Borowiak ,  Gerard Lang

Inventor： Alex Junino ,  Jean J. Vandenbossche ,  Herve Borowiak ,  Gerard Lang

IPC: A61K8/00 ,  A61K20060101 ,  A61K8/41 ,  A61Q5/10 ,  C07C20060101 ,  C07C215/20 ,  C07C217/84 ,  C09B53/02 ,  D06P1/32 ,  D06P3/04 ,  D06P3/14

CPC classification number: A61K8/411 ,  A61Q5/10

Abstract: New chloro-meta-phenylenediamines, their use as couplers in the oxidation dyeing of keratinous fibres, dyeing compositions for hair containing these compounds and dyeing process using the said compositions.The invention relates to the compounds of formula: ##STR1## in which Z and Z' denote, independently of one another, an alkyl radical having from 1 to 4 carbon atoms or a hydroxyalkyl radical having from 2 to 4 carbon atoms, andR.sub.1 and R.sub.2 denote, independently of one another, a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms or a mono- or polyhydroxyalkyl radical having 2 or 3 carbon atoms, to their addition salts with an acid, and to their use by way of couplers for the oxidation dyeing of keratinous fibres, especially human hair.These compounds, when they are combined with paraphenylenediamines, surprisingly give beige to light brown hues or purple hues of greater of lesser redness, depending on the substitution of the 5-amino group of the chlorobenzene.

公开(公告)号：US5191110A

公开(公告)日：1993-03-02

申请号：US871710

申请日：1992-04-21

Applicant: Guy Solladie ,  Serge Forestier ,  Gerard Lang

Inventor： Guy Solladie ,  Serge Forestier ,  Gerard Lang

IPC: C07C67/02 ,  C07F7/18

CPC classification number: C07C403/08 ,  C07C403/10 ,  C07C403/14 ,  C07C403/20 ,  C07F7/1856 ,  C07B2200/09 ,  C07C2101/16

Abstract: According to this process, one effects a stereospecific reduction of the two hydroxyl groups of an ether-diol by a mixture (titanium trichloride, lithium aluminum hydride) at a temperature between 5.degree. C. and about 40.degree. C. and that optionally, one converts the resulting ether into vitamin A, retinol or retinoic acid.Application to the synthesis of all-trans compounds selected from the group consisting of vitamin A and its ethers, retinol and retinoic acid, and their 13-cis isomers.

Abstract translation: 根据该方法，通过混合物（三氯化钛，氢化铝锂）在5℃至40℃之间的温度下，可以使醚 - 二醇的两个羟基的立体特异性还原，并且任选地，一个 将所得的醚转化为维生素A，视黄醇或视黄酸。 用于合成选自维生素A及其醚，视黄醇和视黄酸的全反式化合物及其13-顺式异构体的应用。

公开(公告)号：US5114716A

公开(公告)日：1992-05-19

申请号：US385878

申请日：1989-07-28

Applicant: Quang L. N'Guyen ,  Jacqueline Griat ,  Francois Millecamps ,  Gerard Lang ,  Serge Forestier

Inventor： Quang L. N'Guyen ,  Jacqueline Griat ,  Francois Millecamps ,  Gerard Lang ,  Serge Forestier

IPC: C09K3/20 ,  A61K8/00 ,  A61K8/04 ,  A61K8/33 ,  A61K8/36 ,  A61K8/365 ,  A61K8/41 ,  A61K8/46 ,  A61K8/64 ,  A61K8/67 ,  A61Q17/00 ,  A61Q19/00 ,  C09K15/00 ,  C09K15/04 ,  C09K15/08 ,  C09K15/20 ,  C11B5/00

CPC classification number: C11B5/0092 ,  A61K8/64 ,  A61K8/676 ,  A61K8/678 ,  A61Q19/00 ,  C09K15/04 ,  A61K2800/522 ,  Y10S514/844

Abstract: An anti-oxidant system contains, in combination, at least one stabilized ascorbyl ester, at least one tocopherol or a mixture of tocopherols, or cafeic acid or a derivative thereof, at least one complexing agent and at least one non-thiol polypeptide. The anti-oxidant system is employed to stabilize fatty bodies and cosmetic compositions.

Abstract translation: 抗氧化系统组合包含至少一种稳定的抗坏血酸酯，至少一种生育酚或生育酚或咖啡酸或其衍生物，至少一种络合剂和至少一种非硫醇多肽的混合物。 抗氧化系统用于稳定脂肪体和化妆品组合物。

公开(公告)号：US5102707A

公开(公告)日：1992-04-07

申请号：US389868

申请日：1989-08-04

Applicant: Edith Canivenc ,  Serge Forestier ,  Michel Gay ,  Gerard Lang ,  Herve Richard

Inventor： Edith Canivenc ,  Serge Forestier ,  Michel Gay ,  Gerard Lang ,  Herve Richard

IPC: C08G77/38 ,  C08G77/388

CPC classification number: C08G77/388 ,  Y10T428/16

Abstract: Linear and cyclic diorganopolysiloxanes containing benzotriazole functional groups are well suited for the coating of optical fibers and for lubricating plastics, e.g., PVC.

Abstract translation: 含有苯并三唑官能团的线性和环状二有机聚硅氧烷非常适用于光纤的涂层和润滑塑料，例如PVC。

公开(公告)号：US5089250A

公开(公告)日：1992-02-18

申请号：US479478

申请日：1990-02-13

Applicant: Serge Forestier ,  Gerard Lang ,  Herve Richard ,  Jean C. Grognet

Inventor： Serge Forestier ,  Gerard Lang ,  Herve Richard ,  Jean C. Grognet

IPC: A61K8/55 ,  A61K8/00 ,  A61K8/34 ,  A61K8/37 ,  A61K8/49 ,  A61K8/58 ,  A61K8/72 ,  A61K8/89 ,  A61K8/891 ,  A61K8/898 ,  A61K8/92 ,  A61Q1/00 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/10 ,  A61Q17/04 ,  C07F7/08 ,  C07F7/21 ,  C08G77/14 ,  C08L83/04 ,  C08L83/06

CPC classification number: A61K8/496 ,  A61K8/898 ,  A61Q17/04 ,  C07F7/0847 ,  C07F7/0854 ,  C07F7/21 ,  A61K2800/57 ,  Y10S424/01 ,  Y10S424/05 ,  Y10S514/844 ,  Y10S514/937 ,  Y10S514/943 ,  Y10S514/944 ,  Y10S514/972

Abstract: The cosmetic use is described, in particular for use as a UV filter, of benzotriazole diorganopolysiloxanes having either formula: ##STR1## where R is C.sub.1 -C.sub.10 alkyl, phenyl or 3,3,3-trifluoropropyl, B is R or A, r=0-200, s=0-50, or formulas: ##STR2## where u=1-20, t=0-20 and t+u.gtoreq.3.A and/or B represent a benzotriazole C.sub.3 -C.sub.12 alkylene which may be substituted.

Abstract translation: 描述了特别是用作UV过滤器的具有下式的苯并三唑二有机聚硅氧烷的化妆品用途：其中R是C1-C10烷基，苯基或3,3,3-三氟丙基，B是R或 A，r = 0-200，s = 0-50或公式：（2）其中u = 1-20，t = 0-20和t + u> / = 3。 A和/或B表示可被取代的苯并三唑C3-C12亚烷基。

公开(公告)号：US5066427A

公开(公告)日：1991-11-19

申请号：US411043

申请日：1989-09-22

Applicant: Braham Shroot ,  Christopher Hensby ,  Jean Maignan ,  Gerard Lang ,  Serge Restle ,  Michel Colin

Inventor： Braham Shroot ,  Christopher Hensby ,  Jean Maignan ,  Gerard Lang ,  Serge Restle ,  Michel Colin

IPC: A61K8/00 ,  A61K8/11 ,  A61K8/30 ,  A61K8/33 ,  A61K8/36 ,  A61K8/37 ,  A61K8/42 ,  A61K8/49 ,  A61K8/86 ,  A61K31/16 ,  A61K31/165 ,  A61K31/195 ,  A61K31/20 ,  A61K31/202 ,  A61K31/22 ,  A61K31/23 ,  A61K31/40 ,  A61K31/445 ,  A61K31/495 ,  A61P17/00 ,  A61P29/00 ,  A61P37/08 ,  A61P43/00 ,  A61Q5/00 ,  A61Q19/00 ,  C07C17/26 ,  C07C51/353 ,  C07C57/18 ,  C07C57/68 ,  C07C67/00 ,  C07C69/606 ,  C07C231/00 ,  C07C231/02 ,  C07C233/02 ,  C07C233/09 ,  C07C233/16 ,  C07C233/20 ,  C07D295/16 ,  C07D295/18 ,  C07D295/185 ,  C07D317/20 ,  C12N9/99

CPC classification number: A61K8/375 ,  A61K8/42 ,  A61Q19/00 ,  A61Q19/004 ,  C07C17/26 ,  C07C57/18 ,  C07C57/68 ,  C07D295/185 ,  C07D317/20 ,  Y10S514/886

Abstract: Compound, corresponding to the formulaC.sub.8 H.sub.17 (C.tbd.C--CH.sub.2).sub.3 CH.sub.2 CH.sub.2 COR (I)in which R is a C.sub.1 -C.sub.8 lower alkoxy or C.sub.4 -C.sub.6 cycloaly group, substituted with one or more hydroxyl groups and/or interrupted by one or more hetero atoms chosen from oxygen and sulphur, an amino group of structure ##STR1## in which R.sub.1 or R.sub.2, which may be identical or different, denote a hydrogen atom or a linear or branched C.sub.1 -C.sub.8 lower alkyl radical, optionally interrupted by one or more hetero atoms chosen from oxygen, sulphur and nitrogen, this alkyl radical being able to be substituted with one or more hydroxyl groups, R.sub.1 and R.sub.2 not being able to denote hydrogen simultaneously, or alternatively R.sub.1 and R.sub.2 form, together with the nitrogen atom, a heterocyclic system optionally containing oxygen, sulphur or nitrogen as an additional hetero atom, one of the radicals R.sub.1 and R.sub.2 also being able to denote, when the other is a hydrogen atom, an aryl radical of formula (II): ##STR2## or alternatively a benzyl radical of formula (III): ##STR3## in which formulae R.sub.3 and R.sub.4, denote, independently of each other, a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical, a hydroxyl group, a halogen atom or a carboxyl or trifluoromethyl group, the amine group also being able to originate from a sugar, and also the isomers and salts thereof which are pharmaceutically and cosmetically acceptable.

公开(公告)号：US5041143A

公开(公告)日：1991-08-20

申请号：US454006

申请日：1989-12-20

Applicant: Gerard Lang ,  Alex Junino

Inventor： Gerard Lang ,  Alex Junino

IPC: A61K8/41 ,  A61Q5/06 ,  A61Q5/10 ,  C07C215/16 ,  C07D263/20 ,  C07D263/22 ,  C09B51/00 ,  D06P1/19 ,  D06P1/32 ,  D06P3/04

CPC classification number: A61K8/418 ,  A61Q5/065 ,  A61Q5/10 ,  C07D263/22 ,  C09B51/00

Abstract: The present invention relates to a process for preparing a N,N'-disubstituted nitro-para-phenylenediamine (I) according to the following scheme: ##STR1## X denoting a halogen and R a lower alkyl, lower mono- or polyhydroxyalkyl, lower alkoxyalkyl or lower aminoalkyl group, in which the amino group can be mono- or disubstituted with a lower alkyl or lower mono- or polyhydroxyalkyl group, the nitrogen atom of said amino group being able to form part of a heterocyclic system.The invention also relates to the intermediate oxazolidones of formulae (II) and (III), and the new nitro-para-phenylenediamines in which R denotes a lower alkoxyalkyl, lower polyhydroxyalkyl or lower aminoalkyl group, as well as the dyeing compositions for keratinous fibres containing these new nitro-para-phenylenediamines.

公开(公告)号：US5037901A

公开(公告)日：1991-08-06

申请号：US371751

申请日：1989-06-27

Applicant: Serge Forestier ,  Gerard Lang ,  Edith Sainte Beuve

Inventor： Serge Forestier ,  Gerard Lang ,  Edith Sainte Beuve

IPC: A61K8/91 ,  A61Q17/04 ,  C08G69/00 ,  C08G69/02 ,  C08G69/26 ,  C08G69/46 ,  C08G69/48 ,  C08G73/00 ,  C08G73/02 ,  E05F15/10

CPC classification number: A61Q17/04 ,  A61K8/91 ,  C08G69/48 ,  C08G73/028 ,  A61K2800/57 ,  Y10S424/01

Abstract: Polyaminoamides of formula: ##STR1## in which A.sub.1 represents a divalent radical of structure: ##STR2## in which a and b=0 or 1 ##STR3## in which c and d=0 or 1 ##STR4## B.sub.1 represents: 1) in the proportions of 60 to 100% (in moles), the radical ##STR5## in which x.sub.2 =2 and n.sub.1 =1 or 2, or alternatively, x.sub.1 =3 and n.sub.1 =1 and e=0 or 12) in the proportions of 0 to 40% (in moles), the radical (II) above in which x.sub.1 =2 and n.sub.1 =0 or the radical ##STR6## 3) in the proportions of 0 to 20% (in moles), the radical--NH--(CH.sub.2).sub.6 --NH--;in radicals A.sub.1 and B.sub.1, Y represents a residue of an ultraviolet radiation-absorbing molecule, anda+b+c+d+e.gtoreq.1, it being understood that when a, b, c, d or e are zero, the nitrogen atom is then bound to a hydrogen atom;the ratio ##EQU1## is between 0.05 and 0.5; A.sub.2 represents a bivalent radical which has one of the following structures: ##STR7## B.sub.2 represents: 1) in the proportions of 60 to 100% (in moles), the radical ##STR8## in which x.sub.2 =2 and n.sub.2 =2 or 3, or alternatively, x.sub.2 =3 and n.sub.2 =22) in the proportions of 0 to 40% (in moles), the radical (III) above in which x.sub.2 =2 and n.sub.2 =1 or the radical ##STR9## 3) in the proportions of 0 to 20% (in moles), the radical--NH--(CH.sub.2).sub.6 --NH-- process for their preparation and their use as sunlight filters for hair and skin.

公开(公告)号：US5032137A

公开(公告)日：1991-07-16

申请号：US583079

申请日：1990-09-13

Applicant: Alex Junino ,  Alain Genet ,  Gerard Lang

Inventor： Alex Junino ,  Alain Genet ,  Gerard Lang

IPC: A61K8/00 ,  A61K8/33 ,  A61K8/40 ,  A61K8/41 ,  A61K8/42 ,  A61K8/46 ,  A61K8/49 ,  A61Q5/10 ,  C07C319/20 ,  C07C323/25 ,  C09B53/00 ,  D06P3/08

CPC classification number: A61Q5/10 ,  A61K8/411 ,  C07C323/25

Abstract: The invention relates to p-phenylenediamines of formula: ##STR1## in which R.sub.1 denotes an alkyl, hydroxyalkyl or polyhydroxyalkyl radical and R.sub.2 denotes a hydrogen atom or an alkyl radical, as well as the corresponding salts with acids, and to the compositions and the process for dyeing keratinous fibres, and especially hair, employing them.