公开(公告)号：US08936717B2

公开(公告)日：2015-01-20

申请号：US13057781

申请日：2009-07-29

Applicant: Emmanuelle Guillon ,  Laurent Simon

Inventor： Emmanuelle Guillon ,  Laurent Simon

IPC: C10G47/02 ,  B01J29/072 ,  B01J29/076 ,  B01J29/76 ,  B01J29/78 ,  B01J37/00 ,  B01J37/20 ,  C01B39/48 ,  C10G47/16 ,  C10G47/20 ,  B01J21/04 ,  B01J21/12

CPC classification number: B01J29/76 ,  B01J21/04 ,  B01J21/12 ,  B01J29/78 ,  B01J37/0009 ,  B01J37/20 ,  B01J2229/20 ,  B01J2229/42 ,  C01B39/48 ,  C10G47/16 ,  C10G47/20 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

Abstract: The present invention relates to a catalyst comprising at least one IZM-2 zeolite, at least one amorphous matrix, at least one hydro-dehydrogenating element selected from the group formed by the elements from group VIB and from group VIII of the periodic table and excluding platinum and palladium. The catalyst also optionally contains a controlled quantity of at least one doping element selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally a group VIIA element. The invention also relates to hydrocracking and hydrotreatment processes implementing this catalyst.

Abstract translation: 本发明涉及包含至少一种IZM-2沸石，至少一种无定形基质，至少一种加氢脱氢元素的催化剂，所述至少一种加氢脱氢元件选自由元素周期表中VIB族和VIII族元素形成的基团，不包括 铂和钯。 催化剂还任选地含有受控量的至少一种选自磷，硼和硅的掺杂元素，任选地包含元素周期表第VB族中的至少一种元素，以及任选的第VIIA族元素。 本发明还涉及实施该催化剂的加氢裂化和加氢处理方法。

公开(公告)号：US08679323B2

公开(公告)日：2014-03-25

申请号：US12942315

申请日：2010-11-09

Applicant: Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

Inventor： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

IPC: C10G47/20 ,  B01J29/10

CPC classification number: C10G45/62 ,  B01J29/106 ,  B01J29/126 ,  B01J29/166 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/108 ,  B01J37/0009 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

Abstract: A process is described for the production of middle distillates from a paraffinic feedstock wherein the feedstock is subjected to hydrocracking and/or hydro-isomerization in the presence of a hydrocracking/hydro-isomerization catalyst. The catalyst comprises at least one hydro-dehydrogenating metal selected from metals of groups VIB and VIII, and a substrate that comprises at least one dealuminified Y zeolite. The dealuminified Y zeolite is modified by a basic treatment stage wherein the dealuminified Y zeolite is mixed with a basic aqueous solution, and at least one heat treatment stage.

Abstract translation: 描述了从石蜡原料生产中间馏分的方法，其中原料在加氢裂化/加氢异构化催化剂存在下进行加氢裂化和/或加氢异构化。 该催化剂包含至少一种选自VIB和VIII族金属的氢化脱氢金属，以及包含至少一种脱铝Y沸石的底物。 脱铝Y沸石通过碱处理阶段进行改性，其中脱铝Y沸石与碱性水溶液和至少一个热处理阶段混合。

公开(公告)号：US08609913B2

公开(公告)日：2013-12-17

申请号：US12572827

申请日：2009-10-02

Applicant: Sylvain Louret ,  Patrice Font ,  Sylvie Lacombe ,  Eric Sanchez ,  Laurent Simon

Inventor： Sylvain Louret ,  Patrice Font ,  Sylvie Lacombe ,  Eric Sanchez ,  Laurent Simon

IPC: C07C1/00 ,  B01J8/00

CPC classification number: B01J8/125 ,  B01J8/0453 ,  B01J8/0492 ,  B01J8/0496 ,  B01J8/085 ,  B01J8/087 ,  B01J2208/00168 ,  B01J2208/00203 ,  C10G50/00 ,  C10G2300/1088 ,  C10G2400/04

Abstract: An axial flow staged zone oligomerization reaction process includes the steps of passing a hydrocarbon feedstock into the lower portion of the axial flow staged zone reactor which includes axial circulation of the hydrocarbon reaction fluid serially in each of the reaction zones, passing catalyst through a constriction zone located between successive upper and lower catalytic reaction zones which includes heat exchanging of the fluids being the constriction zone within the reactor and further includes withdrawing the oligomerized product from the top of the reactor.

Abstract translation: 轴向流段分段低聚反应方法包括以下步骤：使烃原料进入轴流式分段反应器的下部，其包括在每个反应区中连续地将烃反应流体轴向循环，使催化剂通过收缩区 位于连续的上部和下部催化反应区之间，其包括在反应器内作为收缩区的流体的热交换，并且还包括从反应器的顶部排出低聚产物。

公开(公告)号：US20110083999A1

公开(公告)日：2011-04-14

申请号：US12903573

申请日：2010-10-13

Applicant: Laurent SIMON

Inventor： Laurent SIMON

IPC: C10G45/00 ,  C10G47/20

CPC classification number: C10G45/12 ,  B01J29/064 ,  B01J29/072 ,  B01J29/076 ,  B01J29/084 ,  B01J29/166 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/12 ,  B01J2229/32 ,  B01J2229/37 ,  B01J2229/42 ,  C10G45/08 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

Abstract: The present invention describes a method for hydrocracking and/or hydrotreating hydrocarbon-containing feeds using a catalyst comprising at least one hydro-dehydrogenizing metal selected from the group made up of group VIB and non-noble group VIII metals of the periodic table and a support comprising at least one zeolite having at least pore openings containing 12 oxygen atoms, modified by a) at least a stage of introducing at least one alkaline cation belonging to groups IA or IIA of the periodic table, b) a stage of treating said zeolite in the presence of at least one molecular compound containing at least one silicon atom, c) at least one stage of partial exchange of said alkaline cations by NH4+ cations in such a way that the proportion of alkaline cations remaining in the modified zeolite at the end of stage c) is such that the alkaline cation/aluminium molar ratio ranges between 0.2:1 and 0.01:1, and d) at least one thermal treatment stage.

Abstract translation: 本发明描述了一种使用包含至少一种选自元素周期表VIB族和非贵族VIII族金属的加氢脱氢金属的催化剂加氢裂化和/或加氢处理含烃原料的方法， 包括至少一种沸石，其至少具有含有12个氧原子的孔隙，通过a）至少引入至少一种属于周期表的IA或IIA族的碱性阳离子的阶段，b）将所述沸石处理的阶段 存在至少一种含有至少一个硅原子的分子化合物，c）至少一个阶段通过NH 4 +阳离子部分交换所述碱性阳离子，使得残留在改性沸石中末端的碱性阳离子的比例 阶段c）使得碱性阳离子/铝的摩尔比在0.2:1和0.01:1之间，d）至少一个热处理阶段。

公开(公告)号：US07872166B2

公开(公告)日：2011-01-18

申请号：US11955825

申请日：2007-12-13

Applicant: Ngi Suor Gnep ,  Emmanuelle Guillon ,  Sylvie Lacombe ,  Laurent Simon ,  Pierre Moreau ,  Patrick Magnoux

Inventor： Ngi Suor Gnep ,  Emmanuelle Guillon ,  Sylvie Lacombe ,  Laurent Simon ,  Pierre Moreau ,  Patrick Magnoux

IPC: C07C5/27

CPC classification number: B01J29/7446 ,  B01J29/7246 ,  B01J29/7646 ,  B01J29/7846 ,  B01J2229/123 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/42 ,  C07C5/2775 ,  Y02P20/52 ,  C07C15/08

Abstract: A process for isomerizing a feed comprising at least one aromatic compound containing eight carbon atoms per molecule is carried out in the presence of a catalyst comprising at least one modified zeolite with structure type EUO, at least one binder and at least one metal from group VIII of the periodic table, said catalyst having been prepared using a process which comprises the following in succession: a) a step for treatment of a zeolite with structure type EUO in the presence of at least one molecular compound containing at least one silicon atom, during which said compound, with a diameter greater than the maximum pore opening diameter in said zeolite, is deposited in the gas phase on the outer surface of said zeolite; b) at least one heat treatment step; c) forming said zeolite with a binder; d) at least one step for introducing at least one metal from group VIII of the periodic table onto a support based on said modified and formed zeolite.

Abstract translation: 在包含至少一种结构类型为EUO的改性沸石，至少一种粘合剂和至少一种来自VIII族的金属的催化剂的存在下，进行包含至少一种每分子含有8个碳原子的芳族化合物的进料异构化的方法 所述催化剂已经使用以下方法制备的催化剂：a）在存在至少一种含有至少一个硅原子的分子化合物的存在下，处理具有结构型EUO的沸石的步骤，在 其中所述化合物的直径大于所述沸石中的最大孔开口直径在气相中沉积在所述沸石的外表面上; b）至少一个热处理步骤; c）用粘合剂形成所述沸石; d）至少一个步骤，用于将基于所述改性和形成的沸石的元素周期表第Ⅷ族中的至少一种金属引入到载体上。

公开(公告)号：US20100179361A1

公开(公告)日：2010-07-15

申请号：US12541540

申请日：2009-08-14

Applicant: Simone GOERGEN ,  Loic ROULEAU ,  Emmanuelle GUILLON ,  Florent GUILLOU ,  Laurent SIMON ,  Christophe BOUCHY ,  Joël PATARIN

Inventor： Simone GOERGEN ,  Loic ROULEAU ,  Emmanuelle GUILLON ,  Florent GUILLOU ,  Laurent SIMON ,  Christophe BOUCHY ,  Joël PATARIN

IPC: C07C5/22 ,  B01J29/06 ,  B01J29/40 ,  B01J29/064 ,  C10G47/04

CPC classification number: B01J29/06 ,  B01J29/084 ,  B01J29/166 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7023 ,  B01J29/7446 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1066 ,  B01J2229/186 ,  B01J2229/64 ,  C10G47/16 ,  C10G49/08

Abstract: The invention describes a porous composite material that comprises a porous substrate based on a refractory inorganic oxide in which said substrate has a zeolite crystal content that is less than 25% by mass, whereby said crystals are dispersed homogeneously in the pores of said substrate, and the distribution coefficient that is measured by Castaing microprobe is between 0.75 and 1.25, and in which the total pore volume of said substrate represents at least 40% of the initial total pore volume of the substrate, and the mean diameter of the pores represents at least 50% of the mean diameter of the pores of the initial substrate, its process for preparation and its use as catalyst in the hydrocarbon feedstock conversion reactions.

Abstract translation: 本发明描述了一种多孔复合材料，其包括基于难熔无机氧化物的多孔基材，其中所述基材的沸石晶体含量小于25质量％，由此所述晶体均匀地分散在所述基材的孔中，以及 由Castaing微探针测量的分布系数在0.75和1.25之间，其中所述基材的总孔体积占基材初始总孔体积的至少40％，孔的平均直径至少表示 初始底物孔的平均直径的50％，其制备方法及其作为烃原料转化反应中的催化剂。

公开(公告)号：US07611677B2

公开(公告)日：2009-11-03

申请号：US11267570

申请日：2005-11-07

Applicant: Sylvain Louret ,  Patrice Font ,  Sylvie Lacombe ,  Eric Sanchez ,  Laurent Simon

Inventor： Sylvain Louret ,  Patrice Font ,  Sylvie Lacombe ,  Eric Sanchez ,  Laurent Simon

IPC: F27B15/08 ,  B01J23/90

CPC classification number: B01J8/125 ,  B01J8/0453 ,  B01J8/0492 ,  B01J8/0496 ,  B01J8/085 ,  B01J8/087 ,  B01J2208/00168 ,  B01J2208/00203 ,  C10G50/00 ,  C10G2300/1088 ,  C10G2400/04

Abstract: This invention relates to a staged-zone reactor of the axial-flow type that makes it possible to implement strongly endothermic or exothermic reactions. The reactor comprises a constriction of the catalytic bed between an upper zone (3a) and a lower zone (3b), making it possible to house in the reactor a heat exchanger for the intermediate heating or cooling of the effluents. Process of chemical conversion using this reactor for exothermic or endothermic reactions in the gas and/or liquid phase, and in particular for the oligomerization reaction of C2 to C12 fractions for the purpose of producing a diesel fraction.

Abstract translation: 本发明涉及一种能够实现强吸热或放热反应的轴流式分级反应器。 反应器包括上部区域（3a）和下部区域（3b）之间的催化床的收缩部，使得可以在反应器中容纳用于中间加热或冷却流出物的热交换器。 用于在气体和/或液相中使用该反应器进行放热或吸热反应的化学转化方法，特别是用于生产柴油馏分的C2至C12馏分的低聚反应的方法。

公开(公告)号：US07237820B2

公开(公告)日：2007-07-03

申请号：US10275631

申请日：2001-05-11

Applicant: Franck Cathala ,  Jean-Pierre Eustache ,  Laurent Simon ,  Marcel Trebouet

Inventor： Franck Cathala ,  Jean-Pierre Eustache ,  Laurent Simon ,  Marcel Trebouet

IPC: B60J1/20

CPC classification number: B60S1/583 ,  B60Q1/2661 ,  B60Q2900/20 ,  B60S1/0416 ,  B60S1/0419 ,  B60S1/0438 ,  B60S1/0822 ,  B60S1/0881

Abstract: A module for equipping a motor vehicle rear opening panel includes a support plate on which are directly mounted accessories, in particular, a drive motor for a wiper device. The support plate forms a plate for closing the drive motor of the wiper device.

Abstract translation: 用于装备机动车辆后开口板的模块包括支撑板，在该支撑板上直接安装附件，特别是用于刮水器装置的驱动马达。 支撑板形成用于关闭刮水器装置的驱动马达的板。