公开(公告)号：US20080221376A1

公开(公告)日：2008-09-11

申请号：US11955825

申请日：2007-12-13

申请人： NGI SUOR GNEP ,  Emmanuelle Guillon ,  Sylvie Lacombe ,  Laurent Simon ,  Pierre Moreau ,  Patrick Magnoux

发明人： NGI SUOR GNEP ,  Emmanuelle Guillon ,  Sylvie Lacombe ,  Laurent Simon ,  Pierre Moreau ,  Patrick Magnoux

IPC分类号： C07C5/22

CPC分类号： B01J29/7446 ,  B01J29/7246 ,  B01J29/7646 ,  B01J29/7846 ,  B01J2229/123 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/42 ,  C07C5/2775 ,  Y02P20/52 ,  C07C15/08

摘要： A process for isomerizing a feed comprising at least one aromatic compound containing eight carbon atoms per molecule is carried out in the presence of a catalyst comprising at least one modified zeolite with structure type EUO, at least one binder and at least one metal from group VIII of the periodic table, said catalyst having been prepared using a process which comprises the following in succession: a) a step for treatment of a zeolite with structure type EUO in the presence of at least one molecular compound containing at least one silicon atom, during which said compound, with a diameter greater than the maximum pore opening diameter in said zeolite, is deposited in the gas phase on the outer surface of said zeolite; b) at least one heat treatment step; c) forming said zeolite with a binder; d) at least one step for introducing at least one metal from group VIII of the periodic table onto a support based on said modified and formed zeolite.

摘要翻译： 在包含至少一种结构类型为EUO的改性沸石，至少一种粘合剂和至少一种来自VIII族的金属的催化剂的存在下，进行包含至少一种每分子含有8个碳原子的芳族化合物的进料异构化的方法 所述催化剂已经使用以下方法制备的催化剂：a）在存在至少一种含有至少一个硅原子的分子化合物的存在下，处理具有结构型EUO的沸石的步骤，在 其中所述化合物的直径大于所述沸石中的最大孔开口直径在气相中沉积在所述沸石的外表面上; b）至少一个热处理步骤; c）用粘合剂形成所述沸石; d）至少一个步骤，用于将基于所述改性和形成的沸石的元素周期表第Ⅷ族中的至少一种金属引入到载体上。

公开(公告)号：US07872166B2

公开(公告)日：2011-01-18

申请号：US11955825

申请日：2007-12-13

申请人： Ngi Suor Gnep ,  Emmanuelle Guillon ,  Sylvie Lacombe ,  Laurent Simon ,  Pierre Moreau ,  Patrick Magnoux

发明人： Ngi Suor Gnep ,  Emmanuelle Guillon ,  Sylvie Lacombe ,  Laurent Simon ,  Pierre Moreau ,  Patrick Magnoux

IPC分类号： C07C5/27

CPC分类号： B01J29/7446 ,  B01J29/7246 ,  B01J29/7646 ,  B01J29/7846 ,  B01J2229/123 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/42 ,  C07C5/2775 ,  Y02P20/52 ,  C07C15/08

摘要： A process for isomerizing a feed comprising at least one aromatic compound containing eight carbon atoms per molecule is carried out in the presence of a catalyst comprising at least one modified zeolite with structure type EUO, at least one binder and at least one metal from group VIII of the periodic table, said catalyst having been prepared using a process which comprises the following in succession: a) a step for treatment of a zeolite with structure type EUO in the presence of at least one molecular compound containing at least one silicon atom, during which said compound, with a diameter greater than the maximum pore opening diameter in said zeolite, is deposited in the gas phase on the outer surface of said zeolite; b) at least one heat treatment step; c) forming said zeolite with a binder; d) at least one step for introducing at least one metal from group VIII of the periodic table onto a support based on said modified and formed zeolite.

摘要翻译： 在包含至少一种结构类型为EUO的改性沸石，至少一种粘合剂和至少一种来自VIII族的金属的催化剂的存在下，进行包含至少一种每分子含有8个碳原子的芳族化合物的进料异构化的方法 所述催化剂已经使用以下方法制备的催化剂：a）在存在至少一种含有至少一个硅原子的分子化合物的存在下，处理具有结构型EUO的沸石的步骤，在 其中所述化合物的直径大于所述沸石中的最大孔开口直径在气相中沉积在所述沸石的外表面上; b）至少一个热处理步骤; c）用粘合剂形成所述沸石; d）至少一个步骤，用于将基于所述改性和形成的沸石的元素周期表第Ⅷ族中的至少一种金属引入到载体上。

公开(公告)号：US20120205286A1

公开(公告)日：2012-08-16

申请号：US13345041

申请日：2012-01-06

申请人： Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

发明人： Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC分类号： C10G65/12 ,  B01J29/04 ,  C10G47/06

CPC分类号： B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

摘要： Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

摘要翻译： 使用包含至少一种单独或混合使用的VIB族和非贵重族VIII的加氢脱氢元素的催化剂，以及包含至少一种多孔矿物基质和至少一种多孔矿物基质的载体来加氢裂化和/或加氢处理烃进料的方法 具有2.5至10的整体硅 - 铝原子比的脱铝USY沸石，相对于存在于沸石中的铝的总质量大于10％的网络外铝原子的重量百分比，测量的中孔体积 通过氮气孔隙度法大于0.07ml.g-1，并且元素网的晶体参数a0大于24.28，其中元素镍的量相对于沸石的总质量为0.5-3重量％ 沉积在所述USY沸石上，其中所述催化剂为硫化物形式。

公开(公告)号：US20110192765A1

公开(公告)日：2011-08-11

申请号：US13057781

申请日：2009-07-29

申请人： Emmanuelle Guillon ,  Laurent Simon

发明人： Emmanuelle Guillon ,  Laurent Simon

IPC分类号： C10G47/02 ,  B01J29/076 ,  B01J29/072 ,  C10G49/08 ,  C07C4/02 ,  C10G45/00 ,  C10G65/00 ,  C07C7/00

CPC分类号： B01J29/76 ,  B01J21/04 ,  B01J21/12 ,  B01J29/78 ,  B01J37/0009 ,  B01J37/20 ,  B01J2229/20 ,  B01J2229/42 ,  C01B39/48 ,  C10G47/16 ,  C10G47/20 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： The present invention relates to a catalyst comprising at least one IZM-2 zeolite, at least one amorphous matrix, at least one hydro-dehydrogenating element selected from the group formed by the elements from group VIB and from group VIII of the periodic table and excluding platinum and palladium. The catalyst also optionally contains a controlled quantity of at least one doping element selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally a group VIIA element. The invention also relates to hydrocracking and hydrotreatment processes implementing this catalyst.

摘要翻译： 本发明涉及包含至少一种IZM-2沸石，至少一种无定形基质，至少一种加氢脱氢元素的催化剂，所述至少一种加氢脱氢元件选自由元素周期表中VIB族和VIII族元素形成的基团，不包括 铂和钯。 催化剂还任选地含有受控量的至少一种选自磷，硼和硅的掺杂元素，任选地包含元素周期表第VB族中的至少一种元素，以及任选的第VIIA族元素。 本发明还涉及实施该催化剂的加氢裂化和加氢处理方法。

公开(公告)号：US20110120910A1

公开(公告)日：2011-05-26

申请号：US12942315

申请日：2010-11-09

申请人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

发明人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

IPC分类号： C10G69/02 ,  C10G47/20 ,  C10G35/04

CPC分类号： C10G45/62 ,  B01J29/106 ,  B01J29/126 ,  B01J29/166 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/108 ,  B01J37/0009 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

摘要： This invention describes a process for the production of middle distillates from a paraffinic feedstock that is produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one dealuminified Y zeolite that has an initial overall atomic ratio of silicon to aluminum of between 2.5 and 20, a starting extra-lattice aluminum atom fraction by weight that is greater than 10%, relative to the total mass of aluminum that is present in the zeolite, a starting mesopore volume that is measured by nitrogen porosimetry that is greater than 0.07 ml.g−1, and a starting crystalline parameter ao of the elementary mesh of between 24.38 Å and 24.30 Å, whereby said zeolite is modified by a) a basic treatment stage consisting in mixing said dealuminified Y zeolite with a basic aqueous solution, and at least one heat treatment stage c).

摘要翻译： 本发明描述了一种由费 - 托合成生产的石蜡原料生产中间馏分的方法，其实施加氢裂化/加氢异构化催化剂，其包含至少一种加氢脱氢金属，其选自由 元素周期表VIB族和VIII族的金属以及包含至少一种脱铝Y沸石的底物，其具有硅与铝的初始总原子比为2.5至20，起始晶格间铝原子级分的重量比为 相对于存在于沸石中的铝的总质量大于10％，通过氮气孔率法测量的起始中孔体积大于0.07ml.g-1，并且初级晶体参数ao为初级 筛网在24.38埃至24.30埃之间，由此所述沸石通过以下步骤进行改性：a）将所述脱铝Y沸石w 碱性水溶液和至少一个热处理阶段c）。

公开(公告)号：US08641889B2

公开(公告)日：2014-02-04

申请号：US12942351

申请日：2010-11-09

申请人： Laurent Simon ,  Emmanuelle Guillon

发明人： Laurent Simon ,  Emmanuelle Guillon

IPC分类号： C10G47/20 ,  B01J29/12

CPC分类号： C01B39/00 ,  B01J29/084 ,  B01J29/146 ,  B01J29/166 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/16 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/38 ,  B01J2229/40 ,  C10G45/08 ,  C10G45/12 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/1007 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018 ,  C10G2400/02 ,  C10G2400/04

摘要： Described herein is a hydrocracking and/or hydrotreatment process which uses a catalyst comprising an active phase containing at least one hydrogenating/dehydrogenating component, and a support comprising at least one dealuminated zeolite Y having an overall initial atomic ratio of silicon to aluminum between 2.5 and 20, an initial weight fraction of extra-lattice aluminum atoms greater than 10%, an initial mesopore volume greater than 0.07 ml.g−1, and an initial crystal lattice parameter a0 between 24.38 Å and 24.30 Å. The zeolite Y is modified by a basic treatment stage, and at least one thermal treatment stage.

摘要翻译： 本文描述的是使用包含含有至少一个氢化/脱氢组分的活性相的催化剂的加氢裂化和/或加氢处理方法，以及包含至少一种脱铝沸石Y的载体，其中硅与铝的总初始原子比在2.5和 20，超晶格铝原子的初始重量分数大于10％，初始中孔体积大于0.07ml.g-1，初始晶格参数a0在24.38和24.30之间。 沸石Y通过碱处理阶段和至少一个热处理阶段进行改性。

公开(公告)号：US08399373B2

公开(公告)日：2013-03-19

申请号：US12541540

申请日：2009-08-14

申请人： Simone Goergen ,  Loic Rouleau ,  Emmanuelle Guillon ,  Florent Guillou ,  Laurent Simon ,  Christophe Bouchy ,  Joël Patarin

发明人： Simone Goergen ,  Loic Rouleau ,  Emmanuelle Guillon ,  Florent Guillou ,  Laurent Simon ,  Christophe Bouchy ,  Joël Patarin

IPC分类号： C07C5/22 ,  B01J29/06 ,  C10G47/02

CPC分类号： B01J29/06 ,  B01J29/084 ,  B01J29/166 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7023 ,  B01J29/7446 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1066 ,  B01J2229/186 ,  B01J2229/64 ,  C10G47/16 ,  C10G49/08

摘要： The invention describes a porous composite material that comprises a porous substrate based on a refractory inorganic oxide in which said substrate has a zeolite crystal content that is less than 25% by mass, whereby said crystals are dispersed homogeneously in the pores of said substrate, and the distribution coefficient that is measured by Castaing microprobe is between 0.75 and 1.25, and in which the total pore volume of said substrate represents at least 40% of the initial total pore volume of the substrate, and the mean diameter of the pores represents at least 50% of the mean diameter of the pores of the initial substrate, its process for preparation and its use as catalyst in the hydrocarbon feedstock conversion reactions.

摘要翻译： 本发明描述了一种多孔复合材料，其包括基于难熔无机氧化物的多孔基材，其中所述基材的沸石晶体含量小于25质量％，由此所述晶体均匀地分散在所述基材的孔中，以及 由Castaing微探针测量的分布系数在0.75和1.25之间，其中所述基材的总孔体积占基材初始总孔体积的至少40％，孔的平均直径至少表示 初始底物的孔的平均直径的50％，其制备方法及其作为烃原料转化反应中的催化剂。

公开(公告)号：US09914113B2

公开(公告)日：2018-03-13

申请号：US13345041

申请日：2012-01-06

申请人： Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

发明人： Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC分类号： C10G45/12 ,  C10G47/06 ,  C10G65/12 ,  B01J29/04 ,  B01J29/14 ,  B01J29/16 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/20 ,  C10G49/08

CPC分类号： B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

摘要： Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

公开(公告)号：US08936717B2

公开(公告)日：2015-01-20

申请号：US13057781

申请日：2009-07-29

申请人： Emmanuelle Guillon ,  Laurent Simon

发明人： Emmanuelle Guillon ,  Laurent Simon

IPC分类号： C10G47/02 ,  B01J29/072 ,  B01J29/076 ,  B01J29/76 ,  B01J29/78 ,  B01J37/00 ,  B01J37/20 ,  C01B39/48 ,  C10G47/16 ,  C10G47/20 ,  B01J21/04 ,  B01J21/12

CPC分类号： B01J29/76 ,  B01J21/04 ,  B01J21/12 ,  B01J29/78 ,  B01J37/0009 ,  B01J37/20 ,  B01J2229/20 ,  B01J2229/42 ,  C01B39/48 ,  C10G47/16 ,  C10G47/20 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： The present invention relates to a catalyst comprising at least one IZM-2 zeolite, at least one amorphous matrix, at least one hydro-dehydrogenating element selected from the group formed by the elements from group VIB and from group VIII of the periodic table and excluding platinum and palladium. The catalyst also optionally contains a controlled quantity of at least one doping element selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally a group VIIA element. The invention also relates to hydrocracking and hydrotreatment processes implementing this catalyst.

摘要翻译： 本发明涉及包含至少一种IZM-2沸石，至少一种无定形基质，至少一种加氢脱氢元素的催化剂，所述至少一种加氢脱氢元件选自由元素周期表中VIB族和VIII族元素形成的基团，不包括 铂和钯。 催化剂还任选地含有受控量的至少一种选自磷，硼和硅的掺杂元素，任选地包含元素周期表第VB族中的至少一种元素，以及任选的第VIIA族元素。 本发明还涉及实施该催化剂的加氢裂化和加氢处理方法。

公开(公告)号：US08679323B2

公开(公告)日：2014-03-25

申请号：US12942315

申请日：2010-11-09

申请人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

发明人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

IPC分类号： C10G47/20 ,  B01J29/10

CPC分类号： C10G45/62 ,  B01J29/106 ,  B01J29/126 ,  B01J29/166 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/108 ,  B01J37/0009 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

摘要： A process is described for the production of middle distillates from a paraffinic feedstock wherein the feedstock is subjected to hydrocracking and/or hydro-isomerization in the presence of a hydrocracking/hydro-isomerization catalyst. The catalyst comprises at least one hydro-dehydrogenating metal selected from metals of groups VIB and VIII, and a substrate that comprises at least one dealuminified Y zeolite. The dealuminified Y zeolite is modified by a basic treatment stage wherein the dealuminified Y zeolite is mixed with a basic aqueous solution, and at least one heat treatment stage.

摘要翻译： 描述了从石蜡原料生产中间馏分的方法，其中原料在加氢裂化/加氢异构化催化剂存在下进行加氢裂化和/或加氢异构化。 该催化剂包含至少一种选自VIB和VIII族金属的氢化脱氢金属，以及包含至少一种脱铝Y沸石的底物。 脱铝Y沸石通过碱处理阶段进行改性，其中脱铝Y沸石与碱性水溶液和至少一个热处理阶段混合。