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公开(公告)号：US07956132B2
公开(公告)日：2011-06-07
申请号：US12377037
申请日：2007-08-23
Applicant: Daniel J. Arriola , John R. Briggs , Francis J. Timmers , Nicole L. Wagner , Timothy T. Wenzel
Inventor： Daniel J. Arriola , John R. Briggs , Francis J. Timmers , Nicole L. Wagner , Timothy T. Wenzel
CPC classification number: C08G18/6204 , C08C19/08 , C08C19/28 , C08F8/00 , C08F2810/30 , C08G63/52 , Y10S525/91 , Y10S525/911 , Y10S525/938 , C08F210/02
Abstract: Telechelic unsaturated polymers suitable for conversion to functionalized derivatives such as polyols are prepared by metathesis of an unsaturated copolymer formed by addition polymerization of ethylene, a diene or alkyne and, optionally, one or more C3.20 α-olefins.
Abstract translation: 适用于转化为官能化衍生物如多元醇的非线性不饱和聚合物通过由乙烯，二烯或炔和任选的一种或多种C 3 O.20α-烯烃的加成聚合形成的不饱和共聚物的复分解来制备。
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42.发明申请公开(公告)号：US20110124818A1
公开(公告)日：2011-05-26
申请号：US12962822
申请日：2010-12-08
Applicant: Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
Inventor： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
IPC: C08F210/16 , C08F4/30 , C08F216/04
CPC classification number: B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
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43.发明授权Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent 有权通过多中心穿梭剂控制聚合物结构和分子量分布公开(公告)号：US07947787B2
公开(公告)日：2011-05-24
申请号：US12065861
申请日：2006-09-14
Applicant: Edmund M. Carnahan , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Timothy T. Wenzel
Inventor： Edmund M. Carnahan , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Timothy T. Wenzel
CPC classification number: C08F10/00 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F210/16 , C08F297/00 , C08F2410/01 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08L2314/06 , C08F2/38 , C08F4/65912 , C08L2666/06 , C08F210/14 , C08F2500/05 , C08F4/64048 , C08F4/64193 , C08F4/64148 , C08F4/64144
Abstract: A process for the polymerization of one or more addition polymerizable monomers and the resulting polymer composition, said process comprising contacting an addition polymerizable monomer or mixture of monomers in a reactor or reactor zone with a composition comprising at least one polymerization catalyst and a cocatalyst under polymerization conditions, characterized in that at least a portion of said polymerization is conducted in the presence of a multi-centered shuttling agent thereby causing the composition to have a bimodal molecular weight distribution.
Abstract translation: 一种用于聚合一种或多种可加聚单体和所得聚合物组合物的方法，所述方法包括在反应器或反应器区域中将可加聚单体或单体混合物与包含至少一种聚合催化剂和助催化剂的组合物在聚合反应 条件，其特征在于所述聚合的至少一部分在多中心穿梭剂的存在下进行，从而使组合物具有双峰分子量分布。
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公开(公告)号：US20110092651A1
公开(公告)日：2011-04-21
申请号：US12978006
申请日：2010-12-23
Applicant: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
Inventor： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
IPC: C08F297/02
CPC classification number: C08F297/08 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/6492 , C08F4/65912 , C08F2/38 , C08F210/14 , C08F2/001 , C08F4/64048 , C08F4/64144 , C08F4/64148 , C08F4/64193
Abstract: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
Abstract translation: 聚合方法和所得聚合物组合物，所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下，聚合一种或多种可加聚单体和可聚合穿梭剂， 支链聚合物，优选包括伪嵌段分子结构。
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45.发明授权Catalyst composition comprising shuttling agent for ethylene copolymer formation 有权催化剂组合物包含用于乙烯共聚物形成的穿梭剂公开(公告)号：US07915192B2
公开(公告)日：2011-03-29
申请号：US10589378
申请日：2005-03-17
Applicant: Daniel J. Arriola , David D. Devore , Edmund M. Carnahan , Phillip D. Hustad , Roger L. Kuhlman , Timothy T. Wenzel
Inventor： Daniel J. Arriola , David D. Devore , Edmund M. Carnahan , Phillip D. Hustad , Roger L. Kuhlman , Timothy T. Wenzel
IPC: C08F4/606 , C08F4/64 , C08F2/38 , C08F210/02 , C08F297/00
CPC classification number: C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F110/02 , C08F210/16 , C08F297/08 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08F4/65904 , C08F2/38 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F210/14 , C08F2500/08 , C08F4/64048 , C08F4/6411 , C08F4/64193 , C08F4/7006
Abstract: A composition for use in forming a multi-block copolymer from a single polymerizable monomer, said copolymer containing therein two or more segments or blocks differing in branching index, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, at least one of catalyst (A) or catalyst (B) being capable of forming a branched polymer by means of chain walking or reincorporation of in situ formed olefinic polymer chains, and (C) a chain shuttling agent.
Abstract translation: 一种用于从单一可聚合单体形成多嵌段共聚物的组合物，所述共聚物中含有两个或更多个支链指数不同的链段或嵌段，使用其的聚合方法和所得聚合物，其中组合物包含混合物 或（A）第一烯烃聚合催化剂，（B）能够在相同的聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二种烯烃聚合催化剂，至少 催化剂（A）或催化剂（B）中的一种能够通过原位形成的烯烃聚合物链的链式步行或再结合形成支链聚合物，和（C）链式穿梭剂。
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Patent Agency Ranking
46.发明申请PRODUCTION OF TELECHELIC COMPOUNDS BY METATHESIS DEPOLYMERIZATION 有权通过METATHESIS DEPOLYMERIZATION生产电话化合物公开(公告)号：US20100168352A1
公开(公告)日：2010-07-01
申请号：US12377037
申请日：2007-08-23
Applicant: Daniel J. Arriola , John R. Briggs , Francis J. Timmers , Nicole L. Wagner , Timothy T. Wenzel
Inventor： Daniel J. Arriola , John R. Briggs , Francis J. Timmers , Nicole L. Wagner , Timothy T. Wenzel
CPC classification number: C08G18/6204 , C08C19/08 , C08C19/28 , C08F8/00 , C08F2810/30 , C08G63/52 , Y10S525/91 , Y10S525/911 , Y10S525/938 , C08F210/02
Abstract: Telechelic unsaturated polymers suitable for conversion to functionalized derivatives such as polyols are prepared by metathesis of an unsaturated copolymer formed by addition polymerization of ethylene, a diene or alkyne and, optionally, one or more C3.20 α-olefins.
Abstract translation: 适用于转化为官能化衍生物如多元醇的非线性不饱和聚合物通过由乙烯，二烯或炔和任选的一种或多种C 3 20.20α-烯烃的加成聚合形成的不饱和共聚物的复分解来制备。
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47.发明申请Catalyst Composition Comprising Shuttling Agent for Higher Olefin Multi-Block Copolymer Formation 有权催化剂组合物包含用于较高烯烃多嵌段共聚物形成的穿梭剂公开(公告)号：US20080311812A1
公开(公告)日：2008-12-18
申请号：US10589379
申请日：2005-03-17
Applicant: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Roger L. Kuhlman , Timothy T. Wenzel
Inventor： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Roger L. Kuhlman , Timothy T. Wenzel
CPC classification number: C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F110/02 , C08F210/16 , C08F297/08 , C08F2410/04 , C08F2420/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , Y10T442/60 , C08F4/65904 , C08F2/38 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F210/14 , C08F2500/08 , C08F4/64193 , C08F4/64048 , C08F4/7006 , C08F4/6411 , C08F4/64113 , C08F4/64144
Abstract: Copolymers, especially multi-block copolymer containing therein two or more segments or blocks differing in chemical or physical properties, are prepared by polymerizing propylene, 4-methyl-1-pentene, or other C4-8α-olefin and one or more copolymerizable comonomers, especially ethylene in the presence of a composition comprising the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
Abstract translation: 通过聚合丙烯，4-甲基-1-戊烯或其它C 4-8α-烯烃和一种或多种可共聚共聚单体制备共聚物，特别是其中含有两个或更多个化学或物理性质不同的链段或嵌段的多嵌段共聚物， 特别是乙烯在组合物存在下，该组合物包含通过混合得到的混合物或反应产物：（A）第一金属络合物烯烃聚合催化剂，（B）能够制备化学或物理性质不同的聚合物的第二金属络合物烯烃聚合催化剂 在等同的聚合条件下由催化剂（A）制备的聚合物，和（C）链穿梭剂。
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公开(公告)号：US06956094B2
公开(公告)日：2005-10-18
申请号：US10772823
申请日：2004-02-05
Applicant: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
Inventor： Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC: C08F2/00 , C08F2/34 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F12/06
CPC classification number: C08F10/00 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F210/16 , Y10S526/905 , Y10S526/943 , C08F4/65904 , C08F4/65916 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
Abstract translation: 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说，该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料，催化剂组分溶液和催化剂组合物的方法，以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。
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公开(公告)号：US06605675B2
公开(公告)日：2003-08-12
申请号：US09729550
申请日：2000-12-04
Applicant: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
Inventor： Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC: C08F444
CPC classification number: B01J8/1827 , B01J4/002 , B01J2219/00108 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F4/65916 , C08F4/65904 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
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公开(公告)号：US06369174B1
公开(公告)日：2002-04-09
申请号：US09392417
申请日：1999-09-09
Applicant: Timothy T. Wenzel , David James Schreck , Thomas H. Peterson
Inventor： Timothy T. Wenzel , David James Schreck , Thomas H. Peterson
IPC: C08F200
CPC classification number: C08F110/02 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/901 , Y10S526/943 , C08F2/40
Abstract: The present invention relates to the use of at least one solid compound that when used with a polymerization catalyst in a polymerization process results in a phase change of the solid compound to a liquid that renders the polymerization catalyst substantially or completely inactive.
Abstract translation: 本发明涉及至少一种固体化合物的用途，当在聚合过程中与聚合催化剂一起使用时，固体化合物与使聚合催化剂基本上或完全无活性的液体相变。
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