公开(公告)号：US09957403B2

公开(公告)日：2018-05-01

申请号：US15216413

申请日：2016-07-21

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  THE REGENTS OF THE UNIVERSITY OF CALIFORNIA ,  Rohm and Haas Company

Inventor： Joseph Jankolovits ,  Alexander Katz ,  James C. Bohling ,  Clayton J. Radke ,  Antony K. Van Dyk ,  John A. Roper, III

IPC: C09D17/00 ,  C09C1/36 ,  C09C1/40 ,  C09C3/12 ,  C09C1/02 ,  C09C1/04 ,  C09C1/24 ,  C09C1/30 ,  C09D101/28 ,  C09D133/02

CPC classification number: C09D17/003 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/22 ,  C09C1/02 ,  C09C1/028 ,  C09C1/043 ,  C09C1/24 ,  C09C1/3081 ,  C09C1/3684 ,  C09C1/407 ,  C09C3/12 ,  C09D17/001 ,  C09D101/286 ,  C09D133/02

Abstract: The present invention relates to a composition comprising a) a stable aqueous dispersion of inorganic pigment particles hydrophobically modified with covalently bonded polysiloxane or silyl groups; and b) a polymeric anionic dispersant; wherein the hydrophobically modified inorganic pigment particles have an average particle size in the range of from 200 nm to 10 μm, and the solids content of the hydrophobically modified inorganic pigment particles is from 10 to 80 weight percent, based on the weight of inorganic pigment particles and water. The composition of the present invention provides a way to improve water resistance in coatings formulations.

公开(公告)号：US09834697B2

公开(公告)日：2017-12-05

申请号：US15329736

申请日：2014-07-30

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： James C. Bohling ,  Junyu Chen ,  Edwin Nungesser ,  Zhen Qian ,  Tao Wang

IPC: C09D133/06 ,  C09D143/02 ,  C08F220/10 ,  C08F230/02 ,  C09D133/04

CPC classification number: C09D133/06 ,  C08F220/10 ,  C08F230/02 ,  C09D133/04 ,  C09D143/02

Abstract: The present invention is an above-critical coating composition comprising an aqueous dispersion of polymer particles, pigment particles, and extender particles wherein the polymer particles comprise, in a single phase and based on the weight of the polymer particles, from 35 to 79.9 weight percent structural units of vinyl acetate and from 0.1 to 6 weight percent structural units of a phosphorus acid monomer or a salt thereof, wherein the polymer particles have a particle size by dynamic light scattering of from 250 nm to 500 nm. The above-critical composition shows surprising improvements in hiding with increasing particle size of the polymer particles.

公开(公告)号：US20250026941A1

公开(公告)日：2025-01-23

申请号：US18713449

申请日：2022-12-06

Applicant: Rohm and Haas Company

Inventor： Keith A. Alderfer ,  Timothy P. Moneypenny ,  James C. Bohling ,  Juan F. Callejas ,  Stephanie M. Bortko ,  David J. Bluder

IPC: C09D7/61 ,  C08K3/22 ,  C08K3/26 ,  C08K5/101 ,  C09D7/63

Abstract: The present invention relates to a composition comprising cerium (III) carbonate and a photoinitiator. The composition is useful for paints formulations that benefit from dirt pickup resistance and retention of color over time.

公开(公告)号：US10676580B2

公开(公告)日：2020-06-09

申请号：US15973930

申请日：2018-05-08

Applicant: Rohm and Haas Company

Inventor： Kebede Beshah ,  James C. Bohling ,  Ibrahim Eryazici ,  Philip R. Harsh ,  Partha S. Majumdar ,  Edwin Nungesser

IPC: C08F220/18 ,  C08F230/02 ,  C08J7/16 ,  C09D7/42 ,  C08F275/00 ,  C08F285/00

Abstract: The present invention relates to an aqueous dispersion of a class of organic phosphate functionalized microspheres having a particle size in the range of from 1 μm to 25 μm, and a process for preparing the dispersion. The microspheres, which have a low coefficient of variation and low gel concentration, are useful in coatings applications, especially where a matte finish is desired.

公开(公告)号：US10563059B2

公开(公告)日：2020-02-18

申请号：US15840145

申请日：2017-12-13

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Muhunthan Sathiosatham

IPC: C08K3/22 ,  C09D151/00 ,  C08F265/06 ,  C08L51/00 ,  C09D5/00

Abstract: The present invention relates to a composition comprising a stable aqueous dispersion of polymer particles comprising structural units of a polymerizable amino acid and structural units of an acid monomer or a salt thereof. The composition of the present invention is useful in improving lipstick stain resistance in coatings compositions.

公开(公告)号：US10308730B2

公开(公告)日：2019-06-04

申请号：US15703346

申请日：2017-09-13

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Wei Gao

IPC: C08L43/02 ,  C08F230/02 ,  C08F265/06 ,  C08F2/24 ,  C08F2/00 ,  C08F212/36 ,  C08F220/06 ,  C08F220/18 ,  C08K3/22 ,  C08L33/02 ,  C08L33/04 ,  C09D143/02 ,  C08L51/00 ,  C08F285/00

Abstract: The present invention relates to an in situ preparation of a redox initiated bimorphological aqueous dispersion of first polymer particles with protuberating phosphorus acid cores and second polymer particles without protuberating cores. The method provides a more efficient way of making compositions for pigmented coating formulations.

公开(公告)号：US10287450B2

公开(公告)日：2019-05-14

申请号：US15830245

申请日：2017-12-04

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Andrew Swartz

IPC: C08L33/08 ,  C09D143/02 ,  C09D7/40 ,  C09D125/14 ,  C09D133/08 ,  C09D133/12 ,  C08F265/06 ,  C09D151/00 ,  C08F2/22 ,  C08F212/08 ,  C08F220/14 ,  C08F220/18 ,  C08K3/22 ,  B82Y30/00 ,  C08F12/30

Abstract: The present invention relates to a composition comprising 1) an aqueous dispersion of polymer particles having a core-shell morphology wherein the core protuberates from the shell and comprises less than 0.09 structural units of a phosphorus acid monomer, based on the weight of the core; and 2) pigment particles with a refractive index in the range of from 2.0 and 3.0, wherein the pigment volume concentration of the pigment particles is at least 11. The composition of the present invention is useful for improving block resistance in coatings applications.

公开(公告)号：US10119018B2

公开(公告)日：2018-11-06

申请号：US15338530

申请日：2016-10-31

Applicant: Rohm and Haas Company

Inventor： Kebede Beshah ,  James C. Bohling ,  Pu Luo

IPC: C08L31/04 ,  C08F218/08 ,  C09D131/04

Abstract: The present invention relates to a process for preparing an aqueous dispersion of a vinyl acetate polymer comprising the step of polymerizing vinyl acetate under emulsion polymerization conditions in the presence of a chain transfer agent which is a hypophosphite salt or X—R1—SH, where R1 is a C1-C4 alkyl group and X is sulfonate, hydroxyl, sulfate, phosphate, phosphonate, carboxylic acid or a salt thereof, or C1-C3-alkyl carboxylate. The process provides a way of lowering the viscosity of the vinyl acetate polymer at a given solids content.

公开(公告)号：US09745492B2

公开(公告)日：2017-08-29

申请号：US15262566

申请日：2016-09-12

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Jihui Guo ,  Kevin J. Henderson ,  Ericka Lynn Killian ,  John J. Rabasco ,  Daniel A. Saucy ,  Jordan Stracke

IPC: C08K9/00 ,  C09D133/12 ,  C09D5/00

CPC classification number: C09D133/12 ,  C09D5/00

Abstract: The present invention relates to a composition comprising an aqueous dispersion of an associative thickener having a hydrophobic portion with a calculated log P in the range of from 2.7 to 4.8; and composite particles comprising phosphorus acid functionalized polymer particles adsorbed to the surfaces of TiO2 particles. The composition of the present invention provides formulators with flexibility in their use of low and mid shear rate thickeners to balance paint performance properties.

公开(公告)号：US20170081547A1

公开(公告)日：2017-03-23

申请号：US15262566

申请日：2016-09-12

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Jihui Guo ,  Kevin J. Henderson ,  Ericka Lynn Killian ,  John J. Rabasco ,  Daniel A. Saucy ,  Jordan Stracke

IPC: C09D133/12

CPC classification number: C09D133/12 ,  C09D5/00

Abstract: The present invention relates to a composition comprising an aqueous dispersion of an associative thickener having a hydrophobic portion with a calculated log P in the range of from 2.7 to 4.8; and composite particles comprising phosphorus acid functionalized polymer particles adsorbed to the surfaces of TiO2 particles. The composition of the present invention provides formulators with flexibility in their use of low and mid shear rate thickeners to balance paint performance properties.