摘要:
The present invention provides a method for producing a fullerene derivative, comprising the organic group addition step B in which an organic group is further added by reacting at least a basic compound and a halogen compound with a fullerene derivative, which is obtained by addition of a hydrogen atom and an organic group in the organic group addition step A, in which an organic group is added by reacting at least a Grignard reagent and a polar substance with a fullerene or fullerene derivative.
摘要:
A problem of the present invention is to provide an economical process with minimized toxicity for producing an aromatic compound having a variety of substituents such as various alkyl groups, and the problem is solved by a process for production of an aromatic compound represented by formula (1) below, which comprises reacting a compound represented by formula (2) below with an aromatic magnesium reagent represented by formula (3a) below in the presence of an iron catalyst and a diamine compound: wherein R is an optionally substituted hydrocarbon group or a C3-C10 saturated or unsaturated ring group; A is an optionally substituted C4-C20 aromatic group or an optionally substituted heteroaromatic group; X is a halogen atom or a sulfonic acid ester; and Y1 is bromine, iodine, chlorine or a carbanion ligand.
摘要:
The present invention provides a method for producing a fullerene derivative, comprising the organic group addition step B in which an organic group is further added by reacting at least a basic compound and a halogen compound with a fullerene derivative, which is obtained by addition of a hydrogen atom and an organic group in the organic group addition step A, in which an organic group is added by reacting at least a Grignard reagent and a polar substance with a fullerene or fullerene derivative.
摘要:
The present invention provides a fullerene derivative represented by the following formula (1):wherein in formula (1), R1 is a substituted or unsubstituted organic group or a hydrogen atom, and wherein in formulae (2) and (3): W is a single bond, C1-C11, alkylene, C2-C12 alkenylene, or C2-C12 alkynylene, wherein any —CH2— in the alkylene, alkenylene or alkynylene can be substituted with —O—, —S—, —COO—, or —OCO—; Z is an element belonging to group IVB; and R21 to R23 are each independently a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C2-C15 alkenyl group, or a substituted or unsubstituted C2-C15 alkynyl group.
摘要:
A problem of the present invention is to provide an economical process with minimized toxicity for producing an aromatic compound having a variety of substituents such as various alkyl groups, and the problem is solved by a process for production of an aromatic compound represented by formula (1) below, which comprises reacting a compound represented by formula (2) below with an aromatic magnesium reagent represented by formula (3a) below in the presence of an iron catalyst and a diamine compound: wherein R is an optionally substituted hydrocarbon group or a C3-C10 saturated or unsaturated ring group; A is an optionally substituted C4-C20 aromatic group or an optionally substituted heteroaromatic group; X is a halogen atom or a sulfonic acid ester; and Y1 is bromine, iodine, chlorine or a carbanion ligand.
摘要:
An all terrain vehicle has a rear structure in which a exhaust duct extends rearward from a rear portion of a belt transmission and is detachably supported by a vehicle body frame, the exhaust duct is composed of a plurality of constituent members coupled to one another along an exhaust direction of the exhaust air flowing in the exhaust duct, the constituent members having a distance from one another are formed from a high rigidity material maintaining its own shape thereof, and the constituent members are detachably coupled to one another through a coupling member formed of an elastic material.
摘要:
This invention attempts to provide a method for producing a DNA chip which can be accomplished in simple steps at a low cost, and wherein use of the resulting DNA chip reduces loss of probes and sample substances in the washing step enabling efficient use of such probe and sample. This invention also attempts to provide a DNA chip produced by such method. Accordingly, a method for producing a DNA chip comprising a substrate and a DNA-binding layer formed on the substrate wherein said DNA-binding layer is a diamond like film having a DNA-binding group is provided, and this method comprises the steps of: reducing pressure of a vacuum chamber to a predetermined degree of vacuum; feeding the chamber with a gas which is the source of said diamond like film; feeding the chamber with a gas which is the source of nitrogen; and forming the diamond like film having a DNA-binding group on the substrate by CVD. Also provided is the DNA chip produced by such method.
摘要:
An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals. A coating film is formed on the surface of a gear simultaneously with hardening of the gear and the gear can be provided with resistance to pitching.
摘要:
A novel process for producing alcohols, characterized by reacting an organic halide represented by the formula R—X (wherein R means an organic residue and X means a halogen atom) with oxygen molecules in the presence of an organotin compound and a reducing agent and optionally in the presence of a free-radical inhibitor in an amount up to 0.3 equivalent based on the organic halide to obtain an alcohol represented by the general formula R—OH (wherein R has the same meaning as the above).
摘要:
The invention provides a water-soluble quenching medium suitably usable for quenching of metal, which can prevent quenching cracks and quenching ununiformity while having good hardenability. The medium comprises (A) a polyalkylene glycol having a weight average molecular weight of from 10,000 to 100,000 and/or its derivative, (B) a glycol ether having a weight average molecular weight of 1,000 smaller, and optionally (C) an alkylene glycol having a weight average molecular weight of 1,000 or smaller, (D) an alkali metal carboxylate, and (E) an organic amine compound having a weight average molecular weight of 1,000 or smaller.