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    Process for manufacturing molecular sieve of MFS framework type and its use
    42.
    发明申请
    Process for manufacturing molecular sieve of MFS framework type and its use 有权
    制造MFS框架型分子筛的工艺及其应用

    公开(公告)号：US20070191663A1

    公开(公告)日：2007-08-16

    申请号：US11699166

    申请日：2007-01-29

    申请人： Ivy D. Johnson ,  Machteld M. Mertens ,  An Verberckmoes

    发明人： Ivy D. Johnson ,  Machteld M. Mertens ,  An Verberckmoes

    IPC分类号： C07C2/02 ,  C01B39/00 ,  C10G11/00 ,  C07C1/00 ,  C07C2/68 ,  C07C15/12

    CPC分类号： B01J29/7026 ,  C01B39/48 ,  C07C2/12 ,  C10G49/08 ,  C10G2400/20 ,  C10G2400/22 ,  C07C11/02

    摘要： A method of making a crystalline molecular sieve of MFS framework type, said method comprising the steps of (a) adding at least one source of ions of tetravalent element (Y), at least one source of ions of trivalent element (X), at least one hydroxide source (OH−), at least one structure-directing-agent (R), at least one seed source (Seed), and water (H2O) to form a mixture having the following mole composition (expressed in term of oxide): YO2:(n)X2O3:(x)OH−:(y)R:(z)H2O+(m)Seed wherein the m is in the range of from about 10 wtppm to about 2 wt. % (based on total weight of the synthesis mixture), the n is in the range of from about 0.005 to 0.05, the x is in the range of from about 0.01 to about 0.3, the y is in the range of from about 0.03 to about 2; and the z is in the range of from about 3 to about 30; and (b) treating said mixture under crystallization conditions to form said crystalline molecular sieve substantially free of non-MFS material, wherein said crystallization conditions comprise a temperature in the range of from about 150° C. to about 250° C., and crystallization time less than 100 hr, the weight hourly throughput is at least 0.001 hr−1.

    摘要翻译： 一种制备MFS框架型结晶分子筛的方法，所述方法包括以下步骤：（a）将至少一种四价元素（Y）的离子的至少一种源，至少一种三价元素（X）的离子源加入 至少一种氢氧化物源（OH - ），至少一种结构导向剂（R），至少一种种子源（Seed）和水（H 2 O 2） ）以形成具有以下摩尔组成（以氧化物表示）的混合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> YO 2： （n）X 2 O 3（x）OH - （y）R：（z）H 2 SUB> O +（m）种子<？in-line-formula description =“In-line Formulas”end =“tail”？>其中m在约10重量ppm至约2重量％的范围内。 ％（基于合成混合物的总重量），n在约0.005至0.05的范围内，x在约0.01至约0.3的范围内，y在约0.03至 约2; 并且z在约3至约30的范围内; 和（b）在结晶条件下处理所述混合物以形成基本上不含非MFS材料的所述结晶分子筛，其中所述结晶条件包括在约150℃至约250℃范围内的温度和结晶 时间小于100小时，重量小时生产量至少为0.001小时-1。

    Dual-loop xylene isomerization process
    44.
    发明授权
    Dual-loop xylene isomerization process 有权
    双环二甲苯异构化工艺

    公开(公告)号：US5977420A

    公开(公告)日：1999-11-02

    申请号：US139463

    申请日：1998-08-25

    申请人： Jeevan S. Abichandani ,  Jeffrey S. Beck ,  Stephen H. Brown ,  Ronald J. Cimini ,  Ivy D. Johnson ,  Dimitris K. Liguras ,  David L. Stern

    发明人： Jeevan S. Abichandani ,  Jeffrey S. Beck ,  Stephen H. Brown ,  Ronald J. Cimini ,  Ivy D. Johnson ,  Dimitris K. Liguras ,  David L. Stern

    IPC分类号： C07C15/08 ,  C07C1/00 ,  C07C5/22

    CPC分类号： C07C15/08 ,  C07C2529/00

    摘要： A method for increasing the efficiency of xylene isomerization by using a two stage isomerization process. In the first stage of the process, a C.sub.9.sup.+ aromatics feedstock is subjected to ethylbenzene conversion and xylene isomerization. Non-C.sub.8 aromatics are removed from the effluent, which is then processed in a second stage of the process to remove para-xylene and isomerize the para-xylene depleted effluent. The effluent from the second stage isomerization unit is then recycled into the inlet of the second stage of the process and a slip stream from the para-xylene separator is recycled to the feedstock and to the effluent of the ethylbenzene conversion unit. In this way, the production of para-xylene is maximized. In a preferred embodiment, toluene is co-fed into the feedstock to minimize the loss of xylenes during the ethylbenzene conversion reaction.

    摘要翻译： 一种通过使用两级异构化方法提高二甲苯异构化效率的方法。 在该方法的第一阶段，C9 +芳烃原料进行乙苯转化和二甲苯异构化。 从流出物中除去非-C 8芳族化合物，然后在该方法的第二阶段中处理以除去对二甲苯并使对二甲苯贫乏的流出物异构化。 然后将来自第二级异构化单元的流出物再循环到该方法的第二阶段的入口中，并且来自对二甲苯分离器的滑流再循环至原料和乙苯转化单元的流出物。 以这种方式，对二甲苯的生产最大化。 在优选的实施方案中，将甲苯共同进料到原料中以使乙苯转化反应期间二甲苯的损失最小化。

    Isoparaffin:olefin alkylation process employing Lewis-acid promoted pillared layered silicate
    46.
    发明授权
    Isoparaffin:olefin alkylation process employing Lewis-acid promoted pillared layered silicate 失效
    异链烷烃：使用路易斯酸促进柱状层状硅酸盐的烯烃烷基化方法

    公开(公告)号：US5221777A

    公开(公告)日：1993-06-22

    申请号：US713240

    申请日：1991-06-07

    申请人： Albin Huss, Jr. ,  Ivy D. Johnson

    发明人： Albin Huss, Jr. ,  Ivy D. Johnson

    IPC分类号： C07C2/60

    CPC分类号： C07C2/60 ,  C07C2521/08 ,  C07C2527/1213 ,  C07C2527/126 ,  C07C2527/133

    摘要： A process is provided for alkylating an isoparaffin with an olefin comprising effecting reaction of isoparaffin and olefin in the presence of an alkylation catalyst complex comprising a Lewis acid and a solid component, said solid component comprising a layered silicate and pillars of an oxide of at least one element selected from Groups IB, IIB, IIIA, IIIB, IVA, IVB, VA, VB, VIA, VIIA and VIIIA of the Periodic Table of the Elements separating the layers of the silicate.

    摘要翻译： 提供了一种用烯烃烷基化异链烷烃的方法，包括在包含路易斯酸和固体组分的烷基化催化剂络合物的存在下进行异链烷烃和烯烃的反应，所述固体组分包含层状硅酸盐和至少一种氧化物的柱 选自分离硅酸盐层的元素周期表的IB，IIB，IIIA，IIIB，IVA，IVB，VA，VB，VIA，VIIA和VIIIA中的一种元素。

    Pillared layered silicate compositions containing pillars of silica and metal oxide and their preparation
    47.
    发明授权
    Pillared layered silicate compositions containing pillars of silica and metal oxide and their preparation 失效
    含有二氧化硅和金属氧化物柱的柱状层状硅酸盐组合物及其制备方法

    公开(公告)号：US4968652A

    公开(公告)日：1990-11-06

    申请号：US494910

    申请日：1990-03-09

    申请人： Ivy D. Johnson ,  Pochen Chu

    发明人： Ivy D. Johnson ,  Pochen Chu

    IPC分类号： B01J20/12 ,  B01J29/04 ,  C01B33/20

    CPC分类号： B01J29/049 ,  C01B33/20 ,  C01B33/28

    摘要： Pillared layered silicate compositions containing pillars of silica and metal oxides, e.g., alumina are prepared by contacting organic-swelled layered silicates, e.g. kenyaite-type materials, with a hydrolyzable silica precursor, e.g., tetraethylorthosilicate which forms silanol groups between the layers and contacting the resulting product with an aqueous solution containing inorganic metal salt and effecting hydrolysis of the silanol groups.

    摘要翻译： 包含二氧化硅和金属氧化物柱的例如氧化铝的柱状层状硅酸盐组合物通过使有机溶胀的层状硅酸盐例如氧化铝接触而制备。 碱土金属类材料与可水解的二氧化硅前体，例如四乙基原硅酸盐，其在层之间形成硅烷醇基团，并使得到的产物与含有无机金属盐的水溶液接触并进行硅烷醇基团的水解。

    Layered aluminum compounds containing phosphorus or arsenic and pendant organic groups
    48.
    发明授权
    Layered aluminum compounds containing phosphorus or arsenic and pendant organic groups 失效
    含有磷或砷的分层铝化合物和有机基团

    公开(公告)号：US4960745A

    公开(公告)日：1990-10-02

    申请号：US382444

    申请日：1989-07-20

    申请人： Ivy D. Johnson

    发明人： Ivy D. Johnson

    IPC分类号： B01J20/02 ,  B01J23/18 ,  B01J27/16 ,  B01J31/02 ,  B01J31/14

    CPC分类号： B01J31/0259 ,  B01J20/223 ,  B01J23/18 ,  B01J27/16 ,  B01J29/84 ,  B01J31/0234 ,  B01J31/0274

    摘要： There is provided layered oxides of aluminum and phosphorus or arsenic having pendant organic groups which protrude into the inner layer region of these layered materials. These materials may be prepared by reacting a suitable organoarsenic or organophosphorus compound, such as phenylphosphonic acid, with a suitable aluminum compound, such as alumina, in the presence of a suitable solvent, such as a mixture of ethanol and water, under conditions of elevated temperature.

    摘要翻译： 提供具有突出到这些层状材料的内层区域中的具有侧基的有机基团的铝和磷或砷的层状氧化物。 这些材料可以通过使合适的有机砷或有机磷化合物如苯基膦酸与合适的铝化合物如氧化铝在合适的溶剂如乙醇和水的混合物存在下，在升高的条件下反应来制备 温度。

    Dehydrogenation process utilizing a pillared layered silicate plus a base metal or noble metal
    49.
    发明授权
    Dehydrogenation process utilizing a pillared layered silicate plus a base metal or noble metal 失效
    使用柱状层状硅酸盐加贱金属或贵金属的脱氢方法

    公开(公告)号：US4956517A

    公开(公告)日：1990-09-11

    申请号：US459215

    申请日：1989-12-29

    申请人： Ivy D. Johnson ,  Pochen Chu ,  Charles T. Kresge

    发明人： Ivy D. Johnson ,  Pochen Chu ,  Charles T. Kresge

    IPC分类号： C07C5/32 ,  C07C5/333

    CPC分类号： C07C5/325 ,  C07C5/3337

    摘要： There is provided a process for the dehydrogenation of saturated hydrocarbons having from 2 to 5 carbon atoms. The feed is contacted with a catalyst which includes a base metal or noble metal which is incorporated into or onto a pillared layered silicate. A preferred pillared layered silicate is kenyaite containing interspathic silica, and a preferred base metal or noble metal is chromium.

    摘要翻译： 提供了具有2至5个碳原子的饱和烃脱氢的方法。 进料与催化剂接触，催化剂包括引入到柱状层状硅酸盐中或其上的贱金属或贵金属。 优选的柱状层状硅酸盐是含有间隙二氧化硅的肯尼亚，优选的贱金属或贵金属是铬。