摘要:
An anionic cellulose nitrate derivative is described, which has: (i) a degree of acid group substitution (DS (acid)) in the range of 0.01 to 0.2; and (ii) a nitrogen content of 10.7 wt. % to 12.3 wt. %, based on the weight of cellulose nitrate derivative. The anionic cellulose nitrate derivative is prepared by a process which includes esterifying cellulose nitrate feed material with at least one dicarboxylic acid anhydride (e.g., maleic anhydride). Aqueous dispersions according to the present invention include: (a) at least on anionic cellulose nitrate derivative according to the present invention; and (b) at least one base.
摘要:
This invention relates to polyisocyanates which are partially or completely blocked with 3,5-dimethyl-1,2,4-triazole, to heat curable, one-component coating compositions containing these blocked polyisocyanates and to the resulting coatings.
摘要:
The present invention relates to aqueous polyurethane-urea dispersions which are film forming at temperatures of .ltoreq.20.degree. C. in the absence of film forming additives, dry at room temperature to yield films having a hardness according to DIN 53 157 (Konig pendulum hardness) of .gtoreq.100 seconds, in which the polyurethane-ureas have a urethane group content (calculated as --NH--CO--O--, molecular weight 59) of 7 to 20 wt. %, and a urea group content (calculated as -NH-CO-N, molecular weight 57) of 5 to 18 wt. %, and contain 15-70 wt. %, based on resin solids, of structural units prepared by incorporating 1-methyl-2,4- and/or -2,6-diisocyanatocyclohexane in the form of urethane and/or urea groups. The present invention also relates to a process for the production of these aqueous polyurethane-urea dispersions and to their use in coating compositions.
摘要:
The present invention relates to a process for preparing 1,4-bis(aminomethyl)cyclohexane by reacting a 40 to 80 wt. % aqueous solution of 1,4-bis(hydroxymethyl)cyclohexane with a mixture of hydrogen and ammonia in the presence of a nickel/copper/chromium catalyst at a pressure of 100 to 250 bar and a temperature of 150.degree. to 250.degree. C.
摘要:
This present invention relates to a process for thermally cracking carbamic acid esters into the corresponding isocyanate and hydroxyl compounds in the liquid phase, wherein the reaction proceeds as a reactive rectification in the stripping zone of a column and in an inert, high-boiling solvent, which acts as a buffer to keep the reaction away from the evaporator region of the column.
摘要:
Brominated chlorine-substituted poly-1,3-butadiene is produced by a process in which an aqueous chlorine-substituted poly-1,3-butadiene latex is reacted in aqueous phase with a brominating agent in the presence of a radical-forming catalyst and/or in the presence of light at a pH value below 7 and at a temperature of 20.degree. to 95.degree. C., the brominated reaction product is optionally precipitated from the aqueous dispersion obtained and then separated from the aqueous liquid.
摘要:
This present invention relates to a process for the preparation of O-silylated aliphatic hydroxyl, compounds by the reaction of aliphatic hydroxyl compounds with triorganochlorosilanes and removal of the resulting gaseous hydrogen chloride from the reaction mixture, characterized in that the reaction is carried out in the presence of phase transfer catalysts in the absence of solvent.The invention also relates to the use of the O-silylated hydroxyl compounds obtained by this process as starting materials for the preparation of isocyanates containing ester groups by a reaction with isocyanato carboxylic acid chlorides.
摘要:
The present invention is directed to a process for the production of aqueous polyurethane-polyurea dispersions by reacting NCO-prepolymers having an average NCO-functionality of 2 to 2.3 and an average molecular weight of about 700 to about 5000 with organic polyamines having an average amine functionality of 2.05 to about 3 and an average molecular weight of 60 to about 2000 containing primary and/or secondary amino groups at an NCO/NH ratio about 1.05:1 to about 7:1 in the presence of a water-miscible, weakly polar solvent inert to isocyanate groups and having a boiling point at normal pressure below 100.degree. C., converting the resulting solution of the reaction products into an aqueous dispersion by the addition of water and optionally removing the solvent used by distillation, characterized in that the reactants and amounts used are selected such that the resulting reaction products have an NCO-functionality of 2.2 to about 3 and NCO-content of about 0.1 to 5% by weight. The present invention is also directed to the products of this process and their use for the production of coatings.