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    Coating compositions for glass substrates
    3.
    发明授权
    Coating compositions for glass substrates 失效
    玻璃基材用涂料组合物

    公开(公告)号：US5852106A

    公开(公告)日：1998-12-22

    申请号：US848948

    申请日：1997-05-01

    申请人： Oswald Wilmes ,  Beate Baumbach ,  Klaus Nachtkamp ,  Eberhard Konig ,  Randall Dearth ,  Manfred Bock ,  Wolfhart Wieczorrek

    发明人： Oswald Wilmes ,  Beate Baumbach ,  Klaus Nachtkamp ,  Eberhard Konig ,  Randall Dearth ,  Manfred Bock ,  Wolfhart Wieczorrek

    IPC分类号： C03C17/32 ,  C08G18/08 ,  C08G18/12 ,  C08G18/64 ,  C08G18/75 ,  C08G18/79 ,  C08G18/80 ,  C09D175/04 ,  C08J3/00 ,  B32B27/00 ,  C08K3/20 ,  C08L75/00

    CPC分类号： C08G18/807 ,  C03C17/322 ,  C08G18/0819 ,  C08G18/12 ,  C08G18/758 ,  C08G18/8058 ,  Y10T428/31551

    摘要： The present invention relates to aqueous polyurethane coating compositions wherein the binder contains a) a polyol component, which is soluble or dispersible in water and is the reaction product of a polyisocyanate component containing 50 to 100 wt. % of 4,4'-diisocyanatodicyclohexylmethane, a polyol component containing one or more polyether polyols and having an OH number of 25 to 350 mg KOH/g solids and an isocyanate-reactive component containing at least one group capable of salt formation and b) a polyisocyanate component, which is soluble or dispersible in water, has blocked isocyanate groups and is the reaction product of a polyisocyanate having an isocyanurate group content of 2 to 30 wt. %, a reversible, monofunctional blocking agent for isocyanate groups, a nonionic hydrophilic component and a stabilizing component which has 1 to 2 hydrazide groups and a molecular weight of 70 to 300, wherein the equivalent ratio of blocked isocyanate groups of component b) to hydroxyl groups of component a) is at least 0.8:1. The present invention also relates to the use of the binders for coating any glass surfaces, especially glass bottles.

    摘要翻译： 本发明涉及水性聚氨酯涂料组合物，其中粘合剂包含a）多元醇组分，其可溶于或分散于水中，并且是含有50-100重量份的多异氰酸酯组分的反应产物。 ％的4,4'-二异氰酸根合二环己基甲烷，含有一种或多种聚醚多元醇并且OH数为25至350mg KOH / g固体的多元醇组分和含有至少一个能够形成盐的基团的异氰酸酯反应性组分，以及b） 可溶于或分散于水中的多异氰酸酯组分具有封闭的异氰酸酯基团，并且是异氰脲酸酯基团含量为2-30重量％的多异氰酸酯的反应产物。 ％，用于异氰酸酯基团的可逆的单官能封端剂，非离子亲水组分和具有1至2个酰肼基和分子量为70至300的稳定组分，其中组分b）的封端异氰酸酯基团与羟基的当量比 组分a）的组分至少为0.8:1。 本发明还涉及粘合剂用于涂覆任何玻璃表面，特别是玻璃瓶的用途。

    Process for the production of diurethanes and their use for the production of diisocyanates
    5.
    发明授权
    Process for the production of diurethanes and their use for the production of diisocyanates 失效
    用于生产二氨基甲酸酯的方法及其用于生产二异氰酸酯的方法

    公开(公告)号：US5744633A

    公开(公告)日：1998-04-28

    申请号：US348704

    申请日：1994-12-02

    申请人： Oswald Wilmes ,  Eberhard Konig ,  Klaus Nachtkamp ,  Ernst Kysela

    发明人： Oswald Wilmes ,  Eberhard Konig ,  Klaus Nachtkamp ,  Ernst Kysela

    IPC分类号： C07C263/04 ,  C07C265/14 ,  C07C269/04 ,  C07C271/20 ,  C07C261/00

    CPC分类号： C07C269/04

    摘要： A new process for the production of high purity (cyclo)aliphatic diurethanes from (cyclo)aliphatic diamines, alcohols and urea in a multistep reaction in which (1) urea is reacted with alcohol with elimination of ammonia, (2) diamine is then introduced into the reaction mixture, optionally in the form of a solution in alcohol, and reacted with continuous release of ammonia and (3) the reaction mixture is freed from volatile components by distillation. The diurethanes produced by this process are useful as starting materials for the production of the corresponding diisocyanates by thermal urethane cleavage.

    摘要翻译： 然后引入（1）尿素与醇与氨反应脱除（2）二胺时，在多步反应中从（环）脂族二胺，醇和尿素生产高纯度（环）脂族二氨基甲酸酯的新方法 进入反应混合物中，任选地呈醇的溶液形式，并与氨的连续释放反应，和（3）通过蒸馏除去挥发性组分。 通过该方法制备的二氨基甲酸酯可用作通过热氨基甲酸酯切割生产相应的二异氰酸酯的起始原料。

    Anionic cellulose nitrate derivatives and aqueous dispersions thereof
    7.
    发明授权
    Anionic cellulose nitrate derivatives and aqueous dispersions thereof 失效
    阴离子硝酸纤维素衍生物及其水分散体

    公开(公告)号：US07071326B2

    公开(公告)日：2006-07-04

    申请号：US11290193

    申请日：2005-11-30

    申请人： Carsten Hüttermann ,  Thomas Wagner ,  Klaus Nachtkamp

    发明人： Carsten Hüttermann ,  Thomas Wagner ,  Klaus Nachtkamp

    IPC分类号： C08B7/00 ,  C09D101/20

    CPC分类号： C08J3/05 ,  C08B7/00 ,  C08J2301/18 ,  C08L1/20

    摘要： An anionic cellulose nitrate derivative is described, which has: (i) a degree of acid group substitution (DS (acid)) in the range of 0.01 to 0.2; and (ii) a nitrogen content of 10.7 wt. % to 12.3 wt. %, based on the weight of cellulose nitrate derivative. The anionic cellulose nitrate derivative is prepared by a process which includes esterifying cellulose nitrate feed material with at least one dicarboxylic acid anhydride (e.g., maleic anhydride). Aqueous dispersions according to the present invention include: (a) at least on anionic cellulose nitrate derivative according to the present invention; and (b) at least one base.

    摘要翻译： 描述了一种阴离子硝酸纤维素衍生物，其具有：（i）酸基置换度（DS（酸））在0.01至0.2的范围内; 和（ii）10.7重量％的氮含量。 ％〜12.3重量％ ％，基于硝酸纤维素衍生物的重量。 通过包括用至少一种二羧酸酐（例如马来酸酐）将硝酸纤维素原料酯化的方法制备阴离子硝酸纤维素衍生物。 根据本发明的水分散体包括：（a）至少一种根据本发明的阴离子硝酸纤维素衍生物; 和（b）至少一个碱基。

    Process for the preparation of cellulose derivatives containing amino groups
    8.
    发明申请
    Process for the preparation of cellulose derivatives containing amino groups 审中-公开
    制备含氨基的纤维素衍生物的方法

    公开(公告)号：US20060041117A1

    公开(公告)日：2006-02-23

    申请号：US11184093

    申请日：2005-07-19

    申请人： Jurgen Engelhardt ,  Meinolf Brackhagen ,  Klaus Nachtkamp ,  Wolfgang Koch ,  Thomas Schulze ,  Frank Meister

    发明人： Jurgen Engelhardt ,  Meinolf Brackhagen ,  Klaus Nachtkamp ,  Wolfgang Koch ,  Thomas Schulze ,  Frank Meister

    IPC分类号： C08B11/00

    CPC分类号： C08B11/145 ,  A61K8/731 ,  A61Q19/00 ,  C02F1/56 ,  D21H17/07 ,  D21H17/25

    摘要： A process is described for the preparation of cellulose derivatives containing amino groups that involves reacting, in the presents of water as a reaction medium, alkali cellulose or alkali cellulose derivatives with reagents represented by the following formula, X—(CH2)n—NR1R2 in which: X is selected from the group consisting of chlorine, bromine, iodine and a sulfonic acid radical R′SO3, in which R′ is an aromatic radical or an aliphatic radical; n is at least 2; and R1 and R2 independently of each other are selected from the group consisting of aliphatic substituents, branched alkyl substituents, cyclic alkyl substituents, aryl substituents, aryl substituents substituted by heteroatoms, H, and R1 and R2 together form a ring with the nitrogen. In the process, the mole ratio of cellulose to water, of said reaction medium, is 1:5 to 1:40 mol water per mol of anhydroglucose unit (AGU). Amino functional cellulose derivatives prepared in accordance with the method of the present invention are useful in cosmetic formulations and aqueous paper treatment compositions.

    摘要翻译： 描述了制备含有氨基的纤维素衍生物的方法，该方法包括在作为反应介质的水的存在下，将碱纤维素或碱性纤维素衍生物与下式表示的试剂反应：<？在线配方说明= “In-line Formulas”end =“lead”？> X-（CH 2）n - NR 1 R 2 - 其中：X选自氯，溴，碘和磺酸基R'SO 2，其中：X选自氯，溴，碘，磺酸根R' 其中R'是芳族基团或脂族基团; n至少为2; R 1和R 2彼此独立地选自脂族取代基，支链烷基取代基，环烷基取代基，芳基取代基，被杂原子取代的芳基取代基 ，H和R 1和R 2一起与氮一起形成环。 在该过程中，所述反应介质的纤维素与水的摩尔比为每摩尔脱水葡萄糖单元（AGU）为1:5至1:40摩尔水。 根据本发明的方法制备的氨基官能纤维素衍生物可用于化妆品制剂和水性纸处理组合物中。