公开(公告)号：US07858707B2

公开(公告)日：2010-12-28

申请号：US12065867

申请日：2006-09-14

Applicant: Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Francis J. Timmers ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Francis J. Timmers ,  Timothy T. Wenzel

IPC: C08F297/08 ,  C08F297/00

CPC classification number: C08F297/08 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/16 ,  C08F4/6492 ,  C08F4/65912 ,  C08F2/38 ,  C08F210/14 ,  C08F2/001 ,  C08F4/64048 ,  C08F4/64144 ,  C08F4/64148 ,  C08F4/64193

Abstract: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.

Abstract translation: 聚合方法和所得聚合物组合物，所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下，聚合一种或多种可加聚单体和可聚合穿梭剂， 支链聚合物，优选包括伪嵌段分子结构。

公开(公告)号：US07858706B2

公开(公告)日：2010-12-28

申请号：US10589377

申请日：2005-03-17

Applicant: Daniel J. Arriola ,  Edmund M. Carnahan ,  Yunwa Wilson Cheung ,  David D. Devore ,  David D. Graf ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Colin Li Pi Shan ,  Benjamin C. Poon ,  Gordon R. Roof ,  James C. Stevens ,  Pamela J. Stirn ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  Yunwa Wilson Cheung ,  David D. Devore ,  David D. Graf ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Colin Li Pi Shan ,  Benjamin C. Poon ,  Gordon R. Roof ,  James C. Stevens ,  Pamela J. Stirn ,  Timothy T. Wenzel

IPC: C08F255/00 ,  C08F255/02 ,  C08F293/00

CPC classification number: B32B27/327 ,  B32B27/06 ,  B32B27/32 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/14 ,  C08F110/02 ,  C08F210/14 ,  C08F210/16 ,  C08F295/00 ,  C08F297/00 ,  C08F297/08 ,  C08F297/083 ,  C08F297/086 ,  C08F2410/01 ,  C08F2410/04 ,  C08F2420/02 ,  C08L23/02 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/0853 ,  C08L23/10 ,  C08L53/00 ,  C08L53/005 ,  Y10T428/24942 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31573 ,  Y10T428/31587 ,  C08F2/38 ,  C08F4/65904 ,  C08L2666/06 ,  C08F2500/09 ,  C08F2500/03 ,  C08F4/64148 ,  C08F4/64193 ,  C08F4/64048 ,  C08F4/6411 ,  C08F4/64144 ,  C08F2500/08 ,  C08F4/64113 ,  C08L2666/02 ,  C08L2666/04 ,  C08F2500/12 ,  C08F2500/20 ,  C08F210/08 ,  C08F2500/11 ,  C08F2500/21 ,  C08F210/02 ,  C08F212/08 ,  C08F232/02 ,  C08F232/08

Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

Abstract translation: 一种用于形成多嵌段共聚物的组合物，所述共聚物中含有两个或更多个化学或物理性质不同的链段或嵌段，使用该多嵌段共聚物的聚合方法和所得聚合物，其中组合物包含混合物或反应产物 由（A）第一金属络合物烯烃聚合催化剂，（B）能够在等效聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二金属络合物烯烃聚合催化剂，以及 （C）链式穿梭剂。

公开(公告)号：US20100010161A1

公开(公告)日：2010-01-14

申请号：US12377019

申请日：2007-08-23

Applicant: Daniel J. Arriola ,  Brain A. Jazdzewski ,  Francis J. Timmers ,  Paul C. Vosejpka ,  Nicole L. Wagner ,  Brian G. Landes ,  Guenter A. Jueptner ,  David H. Bank ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Brain A. Jazdzewski ,  Francis J. Timmers ,  Paul C. Vosejpka ,  Nicole L. Wagner ,  Brian G. Landes ,  Guenter A. Jueptner ,  David H. Bank ,  Timothy T. Wenzel

IPC: C08F8/00

CPC classification number: C08F299/00 ,  C08L9/00 ,  C08L23/16 ,  C08L2312/00 ,  C08L2666/08

Abstract: Two or more chemically distinguishable ethylenically unsaturated polymers, at least one having from 0.001 to 50 mole percent unsaturation and at least one other having an expected Tg or measured Tm value greater than 100° C. are cross-metathesized to form thermoplastic elastomers having improved performance properties.

Abstract translation: 两种或更多种化学上可区分的烯键式不饱和聚合物，至少一种具有0.001至50摩尔％不饱和度和至少一种具有预期Tg或测量的Tm值大于100℃的其它聚合物进行交叉分层以形成具有改进性能的热塑性弹性体 属性。

公开(公告)号：US20090186985A1

公开(公告)日：2009-07-23

申请号：US10585597

申请日：2005-01-21

Applicant: Roger L. Kuhlman ,  Timothy T. Wenzel ,  Yunwa W. Cheung ,  Phillip D. Hustad ,  Edmund M. Carnahan ,  John R. Briggs ,  Brian A. Jazdzewski ,  Wenbin Liang ,  Roji Mori ,  Kouichi Kizu ,  Nobuo Kawahara ,  Shingo Matuso ,  Shinichi Kojoh ,  Norio Kashiwa

Inventor： Roger L. Kuhlman ,  Timothy T. Wenzel ,  Yunwa W. Cheung ,  Phillip D. Hustad ,  Edmund M. Carnahan ,  John R. Briggs ,  Brian A. Jazdzewski ,  Wenbin Liang ,  Roji Mori ,  Kouichi Kizu ,  Nobuo Kawahara ,  Shingo Matuso ,  Shinichi Kojoh ,  Norio Kashiwa

IPC: C08L53/00

CPC classification number: C08G81/021

Abstract: The present invention relates to olefinic compositions comprising a functionalized branched olefin copolymer containing functionalized sidechains derived from olefin and at least one chain end nucleophilic heteroatom containing functional group with at least one protic hydrogen, optionally with one or more copolymerizable monomers, the copolymer characterized by having A) a Tg 100° C.; C) an elongation at break of greater than or equal to 500 percent; D) a Tensile Strength of greater than or equal to 1,500 psi (10,300 kPa) at 25° C.; E) a TMA temperature>80° C., and F) an elastic recovery of greater than or equal to 50 percent.

Abstract translation: 本发明涉及烯烃组合物，其包含官能化的支链烯烃共聚物，其含有衍生自烯烃的官能化侧链和至少一个具有至少一个官能团的链末端亲核杂原子与至少一个质子氢，任选具有一个或多个可共聚单体，所述共聚物的特征在于具有 A）通过DSC测量的Tg <-10℃; B）Ta> 100℃。 C）断裂伸长率大于或等于500％; D）在25℃下的拉伸强度大于或等于1,500psi（10,300kPa）; E）TMA温度> 80℃，F）大于或等于50％的弹性恢复。

公开(公告)号：US20090163667A1

公开(公告)日：2009-06-25

申请号：US12065867

申请日：2006-09-14

Applicant: Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Francis J. Timmers ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Francis J. Timmers ,  Timothy T. Wenzel

IPC: C08L23/16 ,  C08F4/44 ,  C08F2/00 ,  C08F210/00

CPC classification number: C08F297/08 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/16 ,  C08F4/6492 ,  C08F4/65912 ,  C08F2/38 ,  C08F210/14 ,  C08F2/001 ,  C08F4/64048 ,  C08F4/64144 ,  C08F4/64148 ,  C08F4/64193

Abstract: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.

Abstract translation: 聚合方法和所得聚合物组合物，所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下，聚合一种或多种可加聚单体和可聚合穿梭剂， 支链聚合物，优选包括伪嵌段分子结构。

公开(公告)号：US06956089B2

公开(公告)日：2005-10-18

申请号：US10373121

申请日：2003-02-24

Applicant: Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

Inventor： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC: C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F4/64 ,  B01J31/38 ,  C08F210/14

CPC classification number: B01J8/1827 ,  B01J4/002 ,  B01J2219/00108 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65904 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

公开(公告)号：US06825287B2

公开(公告)日：2004-11-30

申请号：US10772921

申请日：2004-02-05

Applicant: Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

Inventor： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC: C08F234

CPC classification number: C08F10/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/905 ,  Y10S526/943 ,  C08F4/65904 ,  C08F4/65916 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

Abstract translation: 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说，该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料，催化剂组分溶液和催化剂组合物的方法，以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。

公开(公告)号：US06689847B2

公开(公告)日：2004-02-10

申请号：US09995043

申请日：2001-11-27

Applicant: Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

Inventor： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC: C08F464

CPC classification number: C08F10/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/903 ,  Y10S526/907 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65904 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

公开(公告)号：US06180735B2

公开(公告)日：2001-01-30

申请号：US09215432

申请日：1998-12-17

Applicant: Timothy T. Wenzel

Inventor： Timothy T. Wenzel

IPC: C08F442

CPC classification number: C08F110/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/943 ,  C08F2/40

Abstract: The present invention relates to a catalyst composition and a method for making the catalyst composition of a polymerization catalyst and a carbonyl compound. The invention is also directed to the use of the catalyst composition in the polymerization of olefin(s). In particular, the polymerization catalyst system is supported on a carrier. More particularly, the polymerization catalyst comprises a bulky ligand metallocene-type catalyst system.

Abstract translation: 本发明涉及催化剂组合物和制备聚合催化剂和羰基化合物的催化剂组合物的方法。 本发明还涉及催化剂组合物在烯烃聚合中的用途。 特别地，聚合催化剂体系被负载在载体上。 更具体地，聚合催化剂包含庞大配体金属茂型催化剂体系。

公开(公告)号：US5136105A

公开(公告)日：1992-08-04

申请号：US676439

申请日：1991-03-28

Applicant: Timothy T. Wenzel

Inventor： Timothy T. Wenzel

IPC: B01J31/30 ,  C07B61/00 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C45/68 ,  C07C47/02 ,  C07C67/29

CPC classification number: C07C45/68 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C67/29

Abstract: A process for the oxidation of a compound having a terminal carbon-carbon double bond to produce the corresponding aldehyde is disclosed. In one embodiment, the process comprises contacting the compound with molecular oxygen in the presence of a Group VIII metal component initially substantially free of NO ligands and NO.sub.2 ligands in an amount effective to promote the oxidation of the compound, a reoxidation component in an amount effective to reoxidize a reduced Group VIII metal component to the Group VIII metal component and at least one alcohol selected from secondary alcohols, tertiary alcohols and mixture thereof in an amount effective to increase the aldehyde selectivity of the oxidation. The contacting occurs at conditions effective to oxidize the compound and the form the corresponding aldehyde.