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    Processes for the production of fluoropropanes and halopropenes
    44.
    发明授权
    Processes for the production of fluoropropanes and halopropenes 有权
    制备氟丙烷和卤代丙烯的方法

    公开(公告)号：US08318992B2

    公开(公告)日：2012-11-27

    申请号：US12444462

    申请日：2007-10-31

    申请人： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    发明人： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： C07C17/20

    CPC分类号： C07C17/21 ,  C07C17/10 ,  C07C17/206 ,  C07C17/25 ,  C07C19/08 ,  C07C21/18

    摘要： A process is disclosed for making CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2. The process involves reacting at least one starting material selected from the group consisting of halopropanes of the formula CX3CH2CH2X, halopropenes of the formula CX3CH═CH2 and halopropenes of the formula CX2═CHCH2X, wherein each X is independently F or Cl, with HF and Cl2 in a reaction zone to produce a product mixture comprising HF, HCl, CF3CF2CH3, CF3CF═CH2, and CF3CCl═CH2; and recovering the CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2 from the product mixture. Also disclosed is a process for making CF3CH2CHF2, CF3CH═CHF, and/or CF3CH═CHCl. This process involves reacting at least one starting material selected from the group consisting of halopropenes of the formula CX3CH═CH2 and halopropenes of the formula CX2═CHCH2X, wherein each X is independently F or Cl, with HF and Cl2 in a reaction zone to produce a product mixture comprising HF, HCl, CF3CH2CHF2, CF3CH═CHF and CF3CH═CHCl; and recovering the CF3CH2CHF2, CF3CH═CHF, and/or CF3CH═CHCl from the product mixture. The molar ratio of HF to the total amount of starting materials fed to the reaction zone for both of these processes is at least stoichiometric, and the molar ratio of Cl2 to total amount of starting material fed to the reaction zone for both of these processes is 2:1 or less.

    摘要翻译： 公开了一种制备CF 3 CF 2 CH 3，CF 3CF≡CH2和/或CF 3 CCl = CH 2的方法。 该方法包括使选自式CX3CH2CH2X的卤代丙烷，式CX3CH = CH2的卤代丙烯和式CX2 = CHCH2X的卤代丙烯，其中每个X独立地为F或Cl的至少一种原料与HF和Cl 2反应 在反应区中产生包含HF，HCl，CF 3 CF 2 CH 3，CF 3 CF = CH 2和CF 3 CCl = CH 2的产物混合物; 并从产物混合物中回收CF 3 CF 2 CH 3，CF 3CF≡CH2和/或CF 3 CCl = CH 2。 还公开了制备CF 3 CH 2 CHF 2，CF 3 CH = CHF和/或CF 3 CH = CHCl的方法。 该方法包括使选自式CX3CH = CH2的卤代丙烯和式CX2 = CHCH2X的卤代丙烯，其中每个X独立地为F或Cl的至少一种起始材料与HF和Cl 2在反应区中反应以产生 包含HF，HCl，CF 3 CH 2 CHF 2，CF 3 CH = CHF和CF 3 CH = CHCl的产物混合物; 并从产物混合物中回收CF 3 CH 2 CHF 2，CF 3 CH = CHF和/或CF 3 CH = CHCl。 对于这两种方法，HF与进料到反应区的起始原料的总量的摩尔比至少为化学计量，并且对于这两种方法，进料到反应区的Cl 2与原料的总量的摩尔比为 2：1或更少。

    Processes for producing 2,3,3,3-tetrafluoropropene and/or 1,2,3,3-tetrafluoropropene
    46.
    发明授权
    Processes for producing 2,3,3,3-tetrafluoropropene and/or 1,2,3,3-tetrafluoropropene 失效
    制备2,3,3,3-四氟丙烯和/或1,2,3,3-四氟丙烯的方法

    公开(公告)号：US08133406B2

    公开(公告)日：2012-03-13

    申请号：US12446063

    申请日：2007-10-31

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： C09K5/04 ,  C11D7/30 ,  C07C17/25

    CPC分类号： C07C21/18 ,  C07C17/23 ,  C07C17/25 ,  C07C19/08

    摘要： A process is disclosed for making CF3CF═CH2 or mixtures thereof with CHF2CF═CHF. This process involves (a) reacting CHCl2CF2CF3, and optionally CHClFCF2CClF2, with H2 in the presence of a catalytically effective amount of a hydrogenation catalyst to form CH3CF2CF3 and, when CHClFCF2CClF2 is present, CH2FCF2CHF2; (b) dehydrofluorinating CH3CF2CF3, and optionally any CH2FCF2CHF2, from (a) to form a product mixture including CF3CF═CH2 and, if CH2FCF2CHF2 is present, CHF2CF═CHF; and optionally (c) recovering CF3CF═CH2, or a mixture thereof with CHF2CF═CHF from the product mixture formed in (b) and/or (d) separating at least a portion of any CHF2CF═CHF in the product mixture formed in (b) from the CF3CF═CH2 in the product mixture formed in (b).

    摘要翻译： 公开了制备CF 3CF≡CH2或其与CHF 2 CF = CHF的混合物的方法。 该方法包括（a）在催化有效量的氢化催化剂存在下使CHCl 2 CF 2 CF 3和任选的CHClFCF 2 CClF 2与H 2反应以形成CH 3 CF 2 CF 3，并且当CHClFCF 2 CClF 2存在时，CH 2 FCF 2 CHF 2; （b）从（a）得到（CF 3 CF 2 CH 2）和（如果存在CH 2 CF 2 CHF 2）的产物混合物的CH 3 CF 2 CF 3和任选的任何任何CH 2 CF 2 CHF 2脱氟氟化CHF 2 CF = CHF; 和（c）从（b）和/或（d）中形成的产物混合物中回收CF 3 CF = CH 2或其与CHF 2 CF = CHF的混合物，从而分离出在（b）中形成的产物混合物中的至少一部分CHF 2 CF = CHF， b）从（b）中形成的产品混合物中的CF 3CF≡CH2。

    PROCESSES FOR PRODUCING AND COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3- TETRAFLUOROPROPENE
    47.
    发明申请
    PROCESSES FOR PRODUCING AND COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3- TETRAFLUOROPROPENE 审中-公开

    公开(公告)号：US20110245350A1

    公开(公告)日：2011-10-06

    申请号：US13156463

    申请日：2011-06-09

    申请人： MARIO JOSEPH NAPPA ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    发明人： MARIO JOSEPH NAPPA ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： A01N29/02 ,  C09K5/04 ,  C09K3/30 ,  C11D17/00 ,  A01P1/00

    CPC分类号： C07C21/18 ,  C07C17/23 ,  C07C17/25 ,  C07C17/278 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/126 ,  C07C19/10

    摘要： A process is disclosed for making CF3CF═CH2 or mixtures thereof with CHF═CFCHF2. The process involves contacting CCl3CF2CF3 and optionally CCl2FCF2CClF2 with H2 in the presence of a catalyst including a catalytically effective amount of palladium supported on a support of alumina, fluorided alumina and/or aluminum fluoride, to produce a product mixture including CH2═CFCF3 (and when CCl2FCF2CClF2 is present, CHF═CFCHF2); recovering CH2═CFCF3 or a mixture thereof with CHF═CFCHF2 from the product mixture; and optionally, separating at least a portion of any CHF═CFCHF2 in the product mixture from the CH2═CFCF3 in the product mixture. The mole ratio of H2 to the total of CCl3CF2CF3 and CCl2FCF2CClF2 fed to the reaction zone is between about 1:1 and about 5:1. The present invention also provides another process for making CH2═CFCF3 or mixtures thereof with CHF═CFCHF2 This process involves (a) reacting CCl3CF2CF3 and optionally CCl2FCF2CClF2 with H2 in the presence of a catalytically effective amount of a hydrogenation catalyst to form CH3CF2CF3 (and when CCl2FCF2CClF2 is present, CH2FCF2CHF2); (b) dehydrofluorinating CH3CF2CF3 and optionally any CH2FCF2CHF2 from (a) to form a product mixture including CH2═CFCF3, and if CH2FCF2CHF2 is present, CHF═CFCHF2; (c) recovering CH2═CFCF3 or a mixture thereof with CHF═CFCHF2 from the product mixture formed in (b); and optionally (d) separating at least a portion of any CHF═CFCHF2 in the product mixture formed in (b) from the CH2═CFCF3 in the product mixture formed in (b).The present invention also provides compositions involving CH2═CFCF3 and/or CHF═CFCHF2, including compositions useful as refrigerants, foam blowing agents, cleaning agents and aerosols and azeotropic compositions involving (a) CF2HCF═CFH and (b) HF.

    PROCESS FOR THE MANUFACTURE FLUOROCARBONS
    48.
    发明申请
    PROCESS FOR THE MANUFACTURE FLUOROCARBONS 失效
    制造氟化物的方法

    公开(公告)号：US20110237847A1

    公开(公告)日：2011-09-29

    申请号：US13153580

    申请日：2011-06-06

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarhjuna Rao ,  Allen Capron Sievert ,  Jeffrey P. Knapp

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarhjuna Rao ,  Allen Capron Sievert ,  Jeffrey P. Knapp

    IPC分类号： C07C17/38 ,  C09K3/00

    CPC分类号： C07C17/38 ,  C07C17/206 ,  C07C17/386 ,  C07C19/08 ,  C07C19/10 ,  C09K5/045 ,  C09K2205/126

    摘要： Halocarbons of the structure CF3CF2CH2X, wherein X is either F or Cl or mixtures thereof prepared by: contacting at least one 2-fluorochloropropane with hydrogen fluoride in a first fluorination step in the gas phase or liquid phase under substantially anhydrous conditions, in the absence of added catalyst to partially fluorinate said 2-fluorochloropropane; contacting said partially fluorinated 2-fluorochloropropane with at least the stoichiometric molar equivalent of hydrogen fluoride under substantially anhydrous conditions, in the presence of at least one fluorination catalyst in a second fluorination step; removing said reaction products from contact with said catalyst, and isolating a substantial yield of at least 1,1,1,2,2,3-hexafluoropropane or 1,1,1,2,2, penta-3-chloropropane, or mixtures thereof, respectively.

    摘要翻译： 结构CF 3 CF 2 CH 2 X的卤代烃，其中X是F或Cl或其混合物，其通过以下步骤制备：在基本上无水条件下，在气相或液相中的第一氟化步骤中使至少一种2-氟氯丙烷与氟化氢接触， 加入催化剂部分氟化所述2-氟氯丙烷; 在第二次氟化步骤中，在至少一种氟化催化剂的存在下，在基本无水的条件下使所述部分氟化的2-氟氯丙烷与化学计量摩尔当量的氟化氢接触; 除去所述反应产物不与所述催化剂接触，并分离出至少1,1,1,2,2,3-六氟丙烷或1,1,1,2,2，五-3-氯丙烷或其混合物的实质产率 分别。

    AZEOTROPIC COMPOSITIONS COMPRISING FLUORINATED OLEFINS FOR CLEANING APPLICATIONS
    49.
    发明申请
    AZEOTROPIC COMPOSITIONS COMPRISING FLUORINATED OLEFINS FOR CLEANING APPLICATIONS 失效
    包含用于清洁应用的氟化油的AZEOPTRIC组合物

    公开(公告)号：US20110152152A1

    公开(公告)日：2011-06-23

    申请号：US13038492

    申请日：2011-03-02

    申请人： Melodie A. SCHWEITZER ,  Allen Capron Sievert ,  Joan Ellen Bartelt ,  Barbara Haviland Minor

    发明人： Melodie A. SCHWEITZER ,  Allen Capron Sievert ,  Joan Ellen Bartelt ,  Barbara Haviland Minor

    IPC分类号： C11D7/60

    CPC分类号： C11D7/5068 ,  C11D7/504 ,  C11D11/0029 ,  C23G5/02803 ,  C23G5/02809

    摘要： The present invention relates to azeotropic or azeotrope-like compositions comprising a fluorinated olefin having the formula E- or Z—C3F7CH═CHC3F7, and at least one alcohol, halocarbon, hydrofluorocarbon, fluoroether, or alkanes and combinations thereof. In one embodiment, the one compound selected from the group consisting of alcohols, halocarbons, fluoroalkyl ethers, hydrofluorocarbons, alkanes is either methanol, ethanol, iso-propanol, n-propanol, trans-1,2-dichloroethylene, cis-1,2-dichloroethylene, n-propyl bromide, C4F9OCH3, C4F9OC2H5, HFC-43-10mee, HFC-365mfc, heptane, or combinations thereof. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.

    摘要翻译： 本发明涉及包含具有式E-或Z-C 3 F 7 CH = CHC 3 F 7的氟化烯烃和至少一种醇，卤代烃，氢氟烃，氟醚或其烷烃及其组合的共沸或类共沸组合物。 在一个实施方案中，选自醇，卤代烃，氟代烷基醚，氢氟烃，烷烃的一种化合物是甲醇，乙醇，异丙醇，正丙醇，反式-1,2-二氯乙烯，顺式-1,2 二氯乙烯，正丙基溴，C 4 F 9 OCH 3，C 4 F 9 OC 2 H 5，HFC-43-10mee，HFC-365mfc，庚烷或其组合。 在另一个实施方案中，这些组合物可用于清洁用作脱脂剂或去除剂，用于从表面除去油和/或其它残留物。