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    METALLOCENE COMPLEX, PREPARATION METHOD THEREOF AND CATALYST COMPOSITION
    43.
    发明申请
    METALLOCENE COMPLEX, PREPARATION METHOD THEREOF AND CATALYST COMPOSITION 有权
    金属络合物，其制备方法和催化剂组合物

    公开(公告)号：US20160229928A1

    公开(公告)日：2016-08-11

    申请号：US15025244

    申请日：2013-11-11

    申请人： CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES

    发明人： Dongmei Cui ,  Chunji Wu ,  Changguang Yao

    IPC分类号： C08F4/58 ,  C07F17/00

    CPC分类号： C08F4/58 ,  C07F5/00 ,  C07F17/00 ,  C07F19/00 ,  C08F4/52 ,  C08F10/00 ,  C08F12/08 ,  C08F36/20 ,  C08F2420/06 ,  C08F210/02 ,  C08F236/20 ,  C08F2500/25 ,  C08F112/08 ,  C08F2500/03 ,  C08F212/08 ,  C08F210/16 ,  C08F210/14 ,  C08F4/54 ,  C08F232/00

    摘要： This invention provides a metallocene complex and the preparation method thereof and a catalyst composition. This catalyst composition comprises a metallocene complex represented by formula (I) and an organic boron salt. Compared to the prior art, the catalyst used in this invention, which is the metallocene complex represented by formula (I), does not contain any side chain, and the coordination space of the central metal has a large opening degree. Therefore, the catalytic activity for more sterically hindered monomers is higher, and the comonomer incorporation is also higher. Furthermore, the metallocene complex represented by formula (I) used in this invention is a heterocyclic ring fused cyclopentadienyl ligand. Heterocyclic rings have relatively strong electron-donating capacity. By fusing a cyclopentadienyl group using heterocyclic rings, it is possible to change the electronic effect of the metal center and in turn increase the activity of catalyst. Therefore, by using the metallocene complex represented by formula (I), it is possible to prepare copolymers of ethylene with other olefins at high activity and high comonomer incorporation, and it is also possible to catalyze the polymerization of styrene and substituted styrene at high syndiotacticity and high activity.

    摘要翻译： 本发明提供茂金属络合物及其制备方法和催化剂组合物。 该催化剂组合物包含由式（I）表示的茂金属络合物和有机硼盐。 与现有技术相比，本发明中使用的催化剂（其是式（I）表示的茂金属络合物）不含任何侧链，中心金属的配位空间具有较大的开口度。 因此，对于空间位阻单体的催化活性较高，共聚单体掺入也较高。 此外，本发明中使用的式（I）表示的茂金属络合物是杂环稠合环戊二烯基配体。 杂环具有较强的给电能力。 通过使用杂环融合环戊二烯基，可以改变金属中心的电子效应，从而提高催化剂的活性。 因此，通过使用由式（I）表示的茂金属络合物，可以制备高活性和高共聚单体掺入的乙烯与其它烯烃的共聚物，并且还可以催化苯乙烯和取代苯乙烯的高间同立构聚合 和高活动。

    METHOD FOR PRODUCING DENATURED CONJUGATED DIENE POLYMER
    44.
    发明申请
    METHOD FOR PRODUCING DENATURED CONJUGATED DIENE POLYMER 有权
    用于生产脱模的连接二烯聚合物的方法

    公开(公告)号：US20140309363A1

    公开(公告)日：2014-10-16

    申请号：US14342200

    申请日：2012-08-29

    申请人： Hiroyuki Morita ,  Takeshi Yuasa ,  Koichiro Tani ,  Naoya Nosaka ,  Ryouji Tanaka ,  Koji Okada

    发明人： Hiroyuki Morita ,  Takeshi Yuasa ,  Koichiro Tani ,  Naoya Nosaka ,  Ryouji Tanaka ,  Koji Okada

    IPC分类号： C08F4/58

    CPC分类号： C08F4/58 ,  B60C1/0016 ,  B60C1/0025 ,  C08C19/22 ,  C08C19/25 ,  C08C19/44 ,  C08F8/42 ,  C08F36/04 ,  C08F36/06 ,  C08F236/10 ,  C08K3/013 ,  Y02T10/862 ,  C08F4/48 ,  C08K3/0033 ,  C08L15/00 ,  C08F297/04

    摘要： A method for producing a conjugated diene polymer usable as a raw material of a crosslinked polymer which is used for use in tires of automobiles and can enhance low fuel consumption performance of automobiles is provided.A method for producing a modified conjugated diene polymer comprising a polymerization step in which monomer including a conjugated diene compound or monomer including a conjugated diene compound and an aromatic vinyl compound are polymerized in the presence of at least one compound selected from the group consisting of the following formulae (1) and (2) and an alkali metal compound or an alkaline earth metal compound to obtain a modified conjugated diene polymer. (In the formulae, A1 is a functional group which has a three-substituted hydrocarbylsilyl group; has at least one atom selected from the group consisting of N, P and S; has no active hydrogen and is bound to R1 by any one atom of the above N, P and S. R1 and R2 are hydrocarbylene groups. In the formulae, R1, R2 and A1 which are each present in plurality may each be same or different.)

    摘要翻译： 提供了可用作汽车用轮胎中的交联聚合物的原料的共轭二烯聚合物的制造方法，能够提高汽车的低燃料消耗性能。 一种制备改性共轭二烯聚合物的方法，其包括聚合步骤，其中包含共轭二烯化合物的单体或包含共轭二烯化合物和芳族乙烯基化合物的单体在至少一种选自以下的化合物的存在下聚合： （1）和（2）和碱金属化合物或碱土金属化合物，得到改性共轭二烯聚合物。 （式中，A 1为具有三取代烃基甲硅烷基的官能团，具有选自N，P，S中的至少1个以上的原子，不具有活性氢， 上述N，P和S.R 1和R 2为亚烃基，式中，R 1，R 2和A 1各自各自相同或不同。

    METHOD FOR MAKING FUNCTIONALIZED POLYMER
    46.
    发明申请
    METHOD FOR MAKING FUNCTIONALIZED POLYMER 有权
    制备官能化聚合物的方法

    公开(公告)号：US20120283387A1

    公开(公告)日：2012-11-08

    申请号：US13462221

    申请日：2012-05-02

    申请人： Yuan-Yong Yan

    发明人： Yuan-Yong Yan

    IPC分类号： C08F8/30

    CPC分类号： C08C19/44 ,  C08F36/04 ,  C08F212/08 ,  C08F4/48 ,  C08F4/58

    摘要： A macromolecule includes at least one polymer chain and terminal functionality. The terminal functionality includes a ring-opened radical of a cyclosilazane or cyclic hydrosiloxane. The polymer can include unsaturated mer units and can be provided via anionic polymerization techniques. The macromolecule can be used as a component of a composition that also includes particulate fillers, with the composition being useful for the production of vulcanizates.

    摘要翻译： 大分子包括至少一个聚合物链和末端官能团。 末端官能团包括环硅氮烷或环状硅氧烷的开环基团。 聚合物可以包括不饱和聚合单元，并且可以通过阴离子聚合技术提供。 大分子可以用作组合物的组分，该组合物还包括颗粒填料，该组合物可用于生产硫化橡胶。

    Polymerization catalysts, main group coordination compounds, process for preparing polyolefins and polyolefins
    47.
    发明授权
    Polymerization catalysts, main group coordination compounds, process for preparing polyolefins and polyolefins 失效
    聚合催化剂，主要配位化合物，制备聚烯烃和聚烯烃的方法

    公开(公告)号：US07750097B2

    公开(公告)日：2010-07-06

    申请号：US11631683

    申请日：2005-06-30

    申请人： Robert L. Jones

    发明人： Robert L. Jones

    IPC分类号： C08F4/52 ,  C08F4/00 ,  B01J31/14 ,  B01J31/18 ,  B01J31/22

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/54 ,  C08F4/58 ,  C08F2500/17 ,  C08F2500/03

    摘要： The present invention relates to catalyst systems for preparing isotactic polyolefins which are obtained by reacting at least one chiral coordination compound of a main group element selected from the group of elements consisting of Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb, Te, TI, Pb, Bi and Po as central atom and at least one cocatalyst which is able to convert the chiral coordination compound into a species which displays polymerization activity toward at least one olefin, with the chiral coordination compound comprising two bidentate chelating ligands joined to one another via a bridge and, optionally, one or two further monodentate ligands and with the four coordinating atoms of the two chelating ligands surrounding the main group element as central atom of the coordination compound in an approximately planar fashion and up to two further ligands being located above and below this approximately planar coordination sphere formed by the four coordinating atoms of the two chelating ligands and, in the case of two such further ligands, these being in trans positions relative to one another.

    摘要翻译： 本发明涉及制备全同立构聚烯烃的催化剂体系，其通过使选自由Al，Si，P，S，Ga，Ge，As，Se组成的元素组中的主要元素的至少一种手性配位化合物 ，In，Sn，Sb，Te，TI，Pb，Bi和Po作为中心原子，以及至少一种助催化剂，其能够将手性配位化合物转化为向至少一种烯烃显示聚合活性的物质，具有手性配位 包含两个二齿螯合配体的化合物，其通过桥连接并且任选地一个或两个另外的单齿配体以及围绕主组元素的两个螯合配体的四个配位原子作为配位化合物的中心原子在大致平面 时尚和多达两个另外的配体位于由两个螯合物l的四个配位原子形成的该近似平面配位球的上方和下方 并且在两个这样的另外的配体的情况下，它们相对于彼此处于反式位置。

    Group III-B metal catalyst system
    49.
    发明申请
    Group III-B metal catalyst system 有权
    III-B族金属催化剂体系

    公开(公告)号：US20060020090A1

    公开(公告)日：2006-01-26

    申请号：US11240862

    申请日：2005-09-30

    申请人： Wen-Liang Hsu ,  Adel Halasa ,  Chad Jasiunas

    发明人： Wen-Liang Hsu ,  Adel Halasa ,  Chad Jasiunas

    IPC分类号： C08F4/44 ,  B01J31/00

    CPC分类号： C08F36/04 ,  C08F136/06 ,  C08F136/08 ,  C08F4/58 ,  C08F4/545 ,  C08F236/06 ,  C08F236/08

    摘要： The subject invention relates to a process for preparing a catalyst system that comprises the sequential steps of (I) reacting an organometalic compound that contains a metal from Group III-B of the Periodic System with an organoaluminum compound at a temperature which is within the range of 50° C. to 100° C. to produce an aluminum modified Group III-B metal containing catalyst component, and (II) mixing the aluminum modified Group III-B metal containing catalyst component with a halogen containing compound to produce the Group III-B metal containing catalyst system, wherein the catalyst system is void of compounds selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, wherein the organometalic compound that contains a metal from Group III-B of the Periodic System is reacted with the organoaluminum compound in the absence of conjugated diene monomers, and wherein the catalyst system is prepared in the absence of compounds that contain labile halogen atoms.

    摘要翻译： 本发明涉及制备催化剂体系的方法，其包括以下顺序步骤：（I）使含有周期系统的III-B族金属的有机金属化合物与有机铝化合物在一定范围内的温度下反应 50℃至100℃，以制备含铝改性的含III-B族金属的催化剂组分，和（II）将经改性的含III-B族金属的催化剂组分与含卤素的化合物混合以制备III族 -B金属的催化剂体系，其中所述催化剂体系没有选自脂族醇，脂环族醇，脂族硫醇，脂环族硫醇，三烷基硅烷醇和三芳基硅烷醇的化合物，其中含有组中的金属的有机金属化合物 周期性体系的III-B在不存在共轭二烯单体的情况下与有机铝化合物反应，并且其中催化剂 在没有含有不稳定卤素原子的化合物的情况下制备体系。

    Group III-B metal catalyst system
    50.
    发明申请
    Group III-B metal catalyst system 有权
    III-B族金属催化剂体系

    公开(公告)号：US20040186252A1

    公开(公告)日：2004-09-23

    申请号：US10765485

    申请日：2004-01-27

    发明人： Wen-Liang Hsu ,  Adel Farhan Halasa ,  Chad Aaron Jasiunas

    IPC分类号： C08F004/44

    CPC分类号： C08F36/04 ,  C08F136/06 ,  C08F136/08 ,  C08F4/58 ,  C08F4/545 ,  C08F236/06 ,  C08F236/08

    摘要： The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubber which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a Group III-B metal containing catalyst system that is made by the sequential steps of (I) reacting an organometalic compound that contains a metal from Group III-B of the Periodic System with an organoaluminum compound at a temperature which is within the range of 50null C. to 100null C. to produce an aluminum modified Group III-B metal containing catalyst component, and (II) mixing the aluminum modified Group III-B metal containing catalyst component with a halogen containing compound, wherein the catalyst system is void of compounds selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols.

    摘要翻译： 本发明涉及一种用于合成1,3-丁二烯和异戊二烯橡胶状非渐变，无规共聚物的技术。 这些橡胶状共聚物表现出用于卡车轮胎的轮胎胎侧橡胶化合物中的优异的性能组合。 通过在轮胎侧壁中使用这些异戊二烯 - 丁二烯橡胶，可以在不牺牲滚动阻力的情况下构建具有改善的耐切割生长性的轮胎。 这种橡胶也可以用在轮胎胎面胶料中以改善胎面磨损特性并降低滚动阻力而不牺牲牵引特性。 本发明更具体地公开了一种用于合成异戊二烯 - 丁二烯橡胶的方法，该方法包括在含有III-B族金属的催化剂体系存在下，将异戊二烯单体和1,3-丁二烯单体在有机溶剂中共聚， 步骤（I）使含有周期性体系的III-B族金属的有机金属化合物与有机铝化合物在50℃至100℃的温度范围内反应，生成铝改性基团 含有III-B族金属的催化剂组分，和（II）将含有铝的改性的含III-B族金属的催化剂组分与含卤素化合物混合，其中催化剂体系没有选自脂族醇，脂环族醇， 脂族硫醇，脂环族硫醇，三烷基硅烷醇和三芳基硅烷醇。