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公开(公告)号：US09145521B2
公开(公告)日：2015-09-29
申请号：US13559845
申请日：2012-07-27
申请人： Omer Refa Koseoglu
发明人： Omer Refa Koseoglu
CPC分类号： C10G21/16 , C10G65/14 , C10G67/0418 , C10G67/0445 , C10G2300/1096 , C10G2300/202 , C10G2300/44 , C10G2400/02 , C10G2400/04
摘要： Aromatic extraction and hydrocracking processes are integrated to optimize the hydrocracking units design and/or performance. By processing aromatics-rich and aromatic-lean fractions separately, the hydrocracking operating severity and or catalyst reactor volume requirement decreases.
摘要翻译： 整合芳香提取和加氢裂化工艺，以优化加氢裂化装置的设计和/或性能。 通过分别处理富含芳香族和芳香族馏分，加氢裂化操作严重度和/或催化剂反应器体积要求降低。
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52.发明授权Gasification of heavy residue with solid catalyst from slurry hydrocracking process 有权从淤浆加氢裂化过程中用固体催化剂气化重质残渣公开(公告)号：US09056771B2
公开(公告)日：2015-06-16
申请号：US13236923
申请日：2011-09-20
IPC分类号： C10G67/12 , C10G47/00 , C10G65/00 , C01B3/36 , C10G65/14 , C10G47/26 , C10G47/06 , C10G47/14
CPC分类号： F01K23/067 , C01B3/36 , C01B2203/0255 , C01B2203/0283 , C01B2203/063 , C10G47/06 , C10G47/10 , C10G47/14 , C10G47/26 , C10G65/14 , C10G67/12 , C10J3/466 , C10J3/82 , C10J2300/0946 , C10J2300/0959 , C10J2300/0976 , C10J2300/1675 , C10J2300/1846 , Y02P20/145
摘要： A cost-effective solution for the disposal of heavy residue bottoms recovered from a slurry hydrocracking process that include solid heterogeneous catalyst particles is provided by their introduction into a membrane wall gasification reactor in the form of a flowable slurry to produce a synthesis gas and, optionally, subjecting the synthesis gas to a water-gas shift reaction to produce a more hydrogen-rich product stream. Process steam and electricity are produced by recovering the sensible heat values from the hot synthesis gas.
摘要翻译： 通过将其以可流动浆料的形式引入到膜壁气化反应器中以产生合成气，并且任选地通过任选地提供，用于处理从包括固体非均相催化剂颗粒的浆料加氢裂化过程中回收的重质残渣底物的经济有效的解决方案 ，使合成气进行水煤气变换反应以产生更富氢的产物流。 通过从热合成气中回收显热值来生产蒸汽和电力。
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公开(公告)号：US09023193B2
公开(公告)日：2015-05-05
申请号：US13113196
申请日：2011-05-23
申请人： Omer Refa Koseoglu
发明人： Omer Refa Koseoglu
IPC分类号： C10G11/02 , C10G9/14 , C10G31/06 , C10G55/04 , C10B55/00 , C10B57/06 , C10B57/04 , C10G9/00 , C10G31/08 , C10G55/06
CPC分类号： C10B55/00 , C10B57/045 , C10B57/06 , C10G9/005 , C10G11/02 , C10G31/08 , C10G55/04 , C10G55/06 , C10G2300/1033 , C10G2300/301 , C10G2300/4006 , C10G2300/4081 , C10G2400/02 , C10G2400/06
摘要： An improved delayed coking process utilizing a coking unit and a coking unit product fractionating column which includes the steps of: heating a mixture of a fresh whole crude oil feedstream and the bottoms from the coking unit product fractionator in a furnace to a coking temperature in the range of 480° C. to 530° C./896° F. to 986° F.; introducing the heated mixed whole crude oil and bottoms feedstream directly into the delayed coking unit; optionally passing the vaporized liquid and gaseous coking unit product stream into a flash unit; recovering a light product gas stream that includes H2S, NH3 and C1 to C4 hydrocarbons from the flash unit; transferring the bottoms from the flash unit to the coking unit product fractionating column; recovering as separate side streams from the fractionating column naphtha, light gas oil and heavy gas oil; recycling a portion of the heavy gas oil by introducing it into the fractionating column optionally with the bottoms from the flash unit; mixing the fractionating column bottoms with the whole crude oil feedstream to form the mixed feedstream; and introducing the mixed whole crude oil and fractionating column bottoms feedstream into the furnace.
摘要翻译： 一种利用焦化装置和焦化装置产品分馏塔的改进的延迟焦化方法，其包括以下步骤：将来自炼焦装置产品分馏器的新鲜的整个原油进料流和塔底物的混合物加热至炉中的焦化温度 范围为480°C至530°C / 896°F至986°F。 将加热的混合的全部原油和底部原料流直接引入延迟焦化装置; 任选地将蒸发的液体和气态焦化装置产物流送入闪光单元; 从闪光单元回收包括H 2 S，NH 3和C 1 -C 4烃的轻质产物气流; 将底部从闪光单元转移到焦化装置产品分馏塔; 作为从分馏柱石脑油，轻瓦斯油和重瓦斯油分离的侧流回收; 通过将一部分重质瓦斯油通过将其从闪光单元中的底部引入分馏塔中; 将分馏柱底部与全部原油进料流混合以形成混合进料流; 并将混合的全部原油和分馏塔底部原料流引入炉中。
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54.发明授权Apparatus for upgrading whole crude oil to remove nitrogen and sulfur compounds 有权用于提升整个原油以除去氮和硫化合物的装置公开(公告)号：US08986622B2
公开(公告)日：2015-03-24
申请号：US12658660
申请日：2010-02-09
CPC分类号： C10G25/11 , C10G7/00 , C10G7/06 , C10G25/003 , C10G25/05 , C10G25/12 , C10G2300/202 , C10G2300/205
摘要： A crude oil feedstream is treated to remove or reduce the content of known undesired heteroatomic and polynuclear aromatic compounds containing nitrogen and sulfur by contacting the feedstream with one or more solid adsorbent materials selected from attapulgus clay, alumina, silica gel and activated carbon in a mixing vessel for a time that is sufficient to optimize the adsorption of the undesired compounds from the crude oil, subjecting the mixture to atmospheric flash distillation and then to vacuum flash distillation to recover presorbed boiling ranges of products having a lowered content of the undesired compounds, and preferably regenerating at least a portion of the solid adsorbent material for reuse in the process.
摘要翻译： 处理原油进料流以除去或减少含有氮和硫的已知不需要的杂原子和多核芳族化合物的含量，其通过将进料流与选自attapulgus粘土，氧化铝，硅胶和活性炭的一种或多种固体吸附材料接触，混合 容器足以优化来自原油的不期望的化合物的吸附，使混合物经历大气闪蒸，然后进行真空闪蒸以回收具有降低的不期望的化合物含量的产物的沸点范围，以及 优选地在该过程中再生至少一部分固体吸附剂材料以供再利用。
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公开(公告)号：US08828219B2
公开(公告)日：2014-09-09
申请号：US13012353
申请日：2011-01-24
申请人： Omer Refa Koseoglu
发明人： Omer Refa Koseoglu
CPC分类号： C10G67/14 , C10G67/06 , C10G2300/1074 , C10G2300/1096 , C10G2300/202 , C10G2300/4081 , C10G2300/44 , C10G2300/701
摘要： A hydrocracking process for treating a first and a second heavy hydrocarbon feedstream, in which the first heavy hydrocarbon feedstream contains undesired nitrogen-containing compounds, sulfur-containing compounds and poly-nuclear aromatic compounds. The process includes contacting the first heavy hydrocarbon feedstream with adsorbent material to produce a hydrocarbon stream having a reduced content of nitrogen-containing, sulfur-containing compounds and poly-nuclear aromatic compounds. The second heavy hydrocarbon feedstream is combined with the adsorbent-treated heavy hydrocarbon stream. The combined stream is charged to a hydrocracking reaction unit. The hydrocracked effluent is fractioned to recover hydrocracked products and a bottoms stream containing heavy poly-nuclear aromatic compounds, and bottoms are contacted with adsorbent material to produce an adsorbent-treated fractionator bottoms stream having a reduced content of heavy poly-nuclear aromatic compounds, and are recycled to the hydrocracking reaction unit.
摘要翻译： 一种用于处理第一和第二重烃进料流的加氢裂化方法，其中第一重烃进料流含有不需要的含氮化合物，含硫化合物和多核芳族化合物。 该方法包括使第一重烃进料流与吸附材料接触以产生含氮，含硫化合物和多核芳族化合物含量降低的烃流。 将第二重烃进料流与吸附剂处理的重质烃流混合。 将合并的流加入加氢裂化反应单元。 将加氢裂化的流出物分馏以回收加氢裂化产物和含有重多芳族芳族化合物的塔底物流，并将塔底物与吸附剂材料接触以产生具有降低的重多元芳族化合物含量的吸附剂处理的分馏塔底部料流，以及 被再循环到加氢裂化反应单元。
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56.发明授权Integrated desulfurization and denitrification process including mild hydrotreating and oxidation of aromatic-rich hydrotreated products 有权综合脱硫脱氮工艺，包括芳香族富氢加氢处理产物的轻度加氢处理和氧化公开(公告)号：US08741127B2
公开(公告)日：2014-06-03
申请号：US12967199
申请日：2010-12-14
IPC分类号： C10G45/00
CPC分类号： C10G45/22 , B01J19/006 , B01J19/18 , B01J2219/00768 , B01J2219/00777 , C10G21/00 , C10G21/16 , C10G21/20 , C10G21/27 , C10G27/04 , C10G27/12 , C10G27/14 , C10G45/02 , C10G53/04 , C10G53/14 , C10G67/04 , C10G67/0418 , C10G67/12 , C10G67/14 , C10G2300/1096 , C10G2300/202 , C10G2300/44
摘要： Reduction of sulfur-containing and nitrogen-containing compounds from hydrocarbon feeds is achieved by first contacting the entire feed with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. An extraction zone downstream of the hydrotreating reaction zone separates an aromatic-rich fraction that contains a substantial amount of the remaining refractory organosulfur and organonitrogen compounds. The aromatic-lean fraction is substantially free of organosulfur and organonitrogen compounds, since the non-aromatic organosulfur and organonitrogen compounds were the labile organosulfur and organonitrogen compounds which were initially removed by mild hydrotreating. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized sulfur-containing and nitrogen-containing hydrocarbon compounds. These oxidized organosulfur and organonitrogen compounds are subsequently removed.
摘要翻译： 通过在温和条件下操作的加氢处理反应区中首先使整个进料与加氢处理催化剂接触，以使不稳定的有机硫和有机氮化合物转化，从而进一步从烃进料中还原含硫和含氮化合物。 在加氢处理反应区下游的萃取区分离富含芳烃的级分，其中含有大量剩余的难熔有机硫和有机氮化合物。 芳香族贫馏分基本上不含有机硫和有机氮化合物，因为非芳族有机硫和有机氮化合物是不稳定的有机硫和有机氮化合物，最初通过轻度加氢处理除去。 氧化富含芳烃的级分将难熔有机硫和有机氮化合物转化为氧化的含硫和含氮烃化合物。 随后除去这些氧化的有机硫和有机氮化合物。
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公开(公告)号：US08658027B2
公开(公告)日：2014-02-25
申请号：US12748888
申请日：2010-03-29
IPC分类号： C10G69/02
CPC分类号： C10G67/12 , B01J8/00 , C10G27/00 , C10G27/04 , C10G31/08 , C10G45/02 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/44 , C10G2400/04
摘要： A system and process for desulfurizing a hydrocarbon feed stream containing organosulfur compounds is provided. In general, the system includes a conventional hydrotreating unit through the high pressure cold or hot separator. Aqueous oxidant and an oxidative catalyst are mixed with the hydrotreated hydrocarbon effluent from the high pressure cold or hot separator, and oxidative desulfurization reactions occur in the low pressure separation zone, thereby minimizing or eliminating the requirement of additional oxidative desulfurization reactors.
摘要翻译： 提供了一种用于使含有机硫化合物的烃进料流脱硫的系统和方法。 通常，该系统包括通过高压冷或热分离器的常规加氢处理单元。 将水性氧化剂和氧化催化剂与来自高压冷或热分离器的加氢处理的烃流出物混合，并且氧化脱硫反应发生在低压分离区中，从而最小化或消除了额外的氧化脱硫反应器的需要。
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58.发明授权公开(公告)号：US08623199B2
公开(公告)日：2014-01-07
申请号：US12462338
申请日：2009-07-30
申请人： Abdennour Bourane , Omer Refa Koseoglu , Musaed Salem Al-Ghrami , Christopher F. Dean , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
发明人： Abdennour Bourane , Omer Refa Koseoglu , Musaed Salem Al-Ghrami , Christopher F. Dean , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
IPC分类号： C10G45/04
CPC分类号： B01J29/088 , B01J20/0211 , B01J20/0244 , B01J20/12 , B01J20/3204 , B01J20/3236 , B01J21/066 , B01J21/16 , B01J23/06 , B01J23/08 , B01J29/084 , B01J35/0006 , B01J35/0073 , B01J37/0205 , B01J37/0207 , B01J37/30 , C10G11/05 , C10G11/18
摘要： Compositions and processed for their use as additives for reducing the sulfur content of FCC gasoline employ a support material having deposited on its surface (a) a first metal component from Group IIB of the Periodic Table and (b) a second metal component from Group III or Group IV of the Periodic Table. The additive composition is preferably made of a montmorillonite clay support containing zinc and gallium, zinc and zirconium. Alternatively, the additive composition includes support material having deposited on its surface a metal component from Group III of the Periodic Table, preferably a montmorillonite clay support containing gallium. The clay is impregnated with the metal(s) using the known incipient wetness method and the dried powdered additive composition is preferably formed into shapes suitable for use in the FCC unit.
摘要翻译： 作为用于降低FCC汽油的硫含量的添加剂的组合物和其加工物使用沉积在其表面上的载体材料（a）来自元素周期表IIB族的第一金属组分和（b）来自III族的第二种金属组分 或周期表第IV组。 添加剂组合物优选由含有锌和镓，锌和锆的蒙脱石粘土载体制成。 或者，添加剂组合物包括在其表面上沉积了来自元素周期表III族的金属组分的载体材料，优选含有镓的蒙脱石粘土载体。 使用已知的初湿法将粘土浸渍有金属，干燥的粉末状添加剂组合物优选形成适合用于FCC装置的形状。
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59.发明申请公开(公告)号：US20130334060A1
公开(公告)日：2013-12-19
申请号：US13915661
申请日：2013-06-12
IPC分类号： C25B1/10
摘要： An integrated process for hydrogen gas production includes: a. operating a water electrolysis cell with an external source of electricity to produce oxygen and hydrogen; b. optionally operating an air separation unit to produce additional oxygen for the process; c. introducing a hydrocarbon feedstock into a membrane wall gasification reactor with an ash-forming material and steam, and oxygen from the electrolysis cell and, optionally, oxygen from the air separation unit to produce hot raw synthesis gas; d. passing the hot raw synthesis gas from the gasification reactor to a steam-generating heat exchanger to produce steam and a cooled raw synthesis gas; e. introducing the steam generated in the heat exchanger into a turbine to produce electricity to operate the electrolysis cell; and f. recovering the hydrogen gas from the water electrolysis cell and, optionally, subjecting the synthesis gas to a water-gas shift reaction to increase the hydrogen content and recovering the hydrogen.
摘要翻译： 氢气生产的综合过程包括：a。 操作具有外部电源的水电解池以产生氧和氢; b。 任选地操作空气分离单元以产生用于该方法的额外的氧气; C。 将碳氢化合物原料引入到具有成灰材料和蒸汽的膜壁气化反应器中，以及来自电解槽的氧气和任选的来自空气分离单元的氧气以产生热的原始合成气; d。 将来自气化反应器的热原料合成气通过蒸汽发生热交换器产生蒸汽和冷却的原始合成气; e。 将在热交换器中产生的蒸汽引入涡轮机以产生电力来操作电解槽; 和f。 从水电解池回收氢气，并且任选地使合成气进行水煤气变换反应以增加氢含量并回收氢。
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60.发明申请公开(公告)号：US20130030236A1
公开(公告)日：2013-01-31
申请号：US13558081
申请日：2012-07-25
IPC分类号： C07C7/148
摘要： The process provided herein is concerned with disposal of oxidized sulfur compounds formed by oxidative desulfurization. The process uses solid base catalyst in the presence of a caustic solution or solid base catalyst pretreated with a base and eliminates the need to separate the sulfones from the hydrocarbon streams and recover the hydrocarbons.
摘要翻译： 本文提供的方法涉及通过氧化脱硫形成的氧化硫化合物的处理。 该方法在用碱处理的苛性碱溶液或固体碱催化剂存在下使用固体碱催化剂，并且不需要将烃与烃流分离并回收烃。
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