公开(公告)号：US10156277B2

公开(公告)日：2018-12-18

申请号：US15578806

申请日：2016-04-28

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Mamoru Nakashima ,  Hideki Sakai ,  Daisuke Taki

IPC: F16D69/02 ,  C01G23/00 ,  C09K3/14 ,  F16D13/64 ,  F16D65/092

Abstract: Provided is an alkali-metal titanate in which the content and adhesivity of the fibrous potassium titanate is significantly reduced.The alkali-metal titanate includes 0.5 mol to 2.2 mol of potassium oxide in terms of potassium atoms, 0.05 mol to 1.4 mol of sodium oxide in terms of sodium atoms, and 0 mol to 1.4 mol of lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate, in which a total content of potassium oxide in terms of potassium atoms, sodium oxide in terms of sodium atoms, and lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate is 1.8 mol to 2.3 mol; and the alkali-metal titanate has a single phase conversion ratio of 85% to 100%, a fiber ratio of 0% by volume to 10% by volume, and a moisture content of 0% by mass to 1.0% by mass.

公开(公告)号：US20180187815A1

公开(公告)日：2018-07-05

申请号：US15740320

申请日：2016-02-16

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Minoru YOSHIDA

IPC: F16L53/38 ,  C22B34/12 ,  C22B5/04

CPC classification number: F16L53/38 ,  B01J2219/0013 ,  B01J2219/00452 ,  C22B5/04 ,  C22B34/12 ,  C22B34/1272

Abstract: A connection pipe for coupling at least one reaction vessel used in producing titanium sponge with at least one recovering vessel for condensing and recovering magnesium and magnesium chloride separated from the titanium sponge in the reaction vessel; wherein the connection pipe is configured as a dual wall structure constituted of an inner pipe and an outer pipe, and comprises at least one heating unit provided between the inner pipe and the outer pipe, two or more sets of lead terminals located through the outer pipe to provide electrical connection to a power terminal in the outside of the connection pipe, insulators for sealing the lead terminals, lead wires for electrically coupling the heating unit with the lead terminals, and a stress absorbed portion provided on the outer pipe; wherein the stress absorbed portion is provided between the lead terminals thereby preventing short circuit and meltdown of the lead wires.

公开(公告)号：US09656879B2

公开(公告)日：2017-05-23

申请号：US14429588

申请日：2014-03-06

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Matsuhide Horikawa ,  Eiichi Fukasawa

IPC: C01G23/00 ,  C01G23/02 ,  B09B3/00 ,  B09B5/00 ,  C01G49/02 ,  C01G49/10 ,  C01B7/03

CPC classification number: C01G23/024 ,  B09B3/00 ,  B09B5/00 ,  C01B7/035 ,  C01G23/022 ,  C01G49/02 ,  C01G49/10

Abstract: A method for producing titanium tetrachloride is provided, in which valuable materials such as unreacted titanium-containing raw material, carbon raw material and chlorine can be recovered from solid recovered material generated in chlorinating process of titanium-containing raw material, and titanium-containing raw material can be efficiently used. The treatment method of titanium-containing raw material includes the steps: separating and removing impurities selectively from the titanium-containing raw material as chlorides so as to obtain high titanium-containing raw material, producing titanium tetrachloride using the high titanium-containing raw material, and performing separating process of impurities from solid recovered material byproduced in the production of titanium tetrachloride, together with selective chlorinating treatment of the titanium-containing raw material. Thus, the high titanium-containing raw material can be produced while recovering chlorine and impure oxides.

公开(公告)号：US20150368119A1

公开(公告)日：2015-12-24

申请号：US14429675

申请日：2014-03-06

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Matsuhide HORIKAWA ,  Seiichiro TANI ,  Ryota HORIGUCHI ,  Eiichi FUKASAWA

IPC: C01G23/02

CPC classification number: C01G23/022

Abstract: A technique is provided in which valuable material is recovered from solid recovered material generated during chlorinating process of titanium-containing raw material, and in particular, in which chlorine gas and titanium-containing raw material can be efficiently separated and recovered from the solid recovered material. The method for production of titanium tetrachloride includes: a chlorinating process in which titanium-containing raw material, coke and chlorine are reacted, a recovering process in which chlorine gas, titanium oxide and coke are recovered by treating solid recovered material which is byproduced during the chlorinating process, and a reusing process in which these recovered material are reused as raw material for the chlorinating process.

Abstract translation: 提供了一种技术，其中有用材料从含钛原料的氯化过程中产生的固体回收材料回收，特别是其中可以从固体回收材料中有效地分离和回收氯气和含钛原料 。 四氯化钛的制造方法包括：使含钛原料，焦炭和氯反应的氯化工艺，通过处理在该过程中产生的固体回收材料回收氯气，氧化钛和焦炭的回收方法 这些回收材料被重新用作氯化工艺的原料，并且重新使用过程。

公开(公告)号：US20150099197A1

公开(公告)日：2015-04-09

申请号：US14396955

申请日：2013-04-22

Applicant: TOHO TITANIUM CO., LTD. ,  NAKASHIMA SANGYO CO., LTD. ,  THE GAKUSHUIN SCHOOL CORPORATION

Inventor： Mamoru Nakashima ,  Yoshiyuki Inaguma ,  Mikio Nakashima

IPC: H01M10/0562 ,  H01M12/08 ,  H01M10/0525

CPC classification number: H01M10/0562 ,  C01G23/005 ,  C01G23/006 ,  C01G35/006 ,  C01G49/0054 ,  C01P2002/50 ,  C01P2004/61 ,  C01P2006/40 ,  C04B35/462 ,  C04B35/47 ,  C04B35/495 ,  C04B35/64 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3213 ,  C04B2235/3217 ,  C04B2235/3227 ,  C04B2235/3236 ,  C04B2235/3255 ,  C04B2235/3272 ,  C04B2235/3286 ,  C04B2235/3418 ,  C04B2235/5436 ,  C04B2235/661 ,  C04B2235/786 ,  C04B2235/80 ,  C04B2235/81 ,  H01B1/06 ,  H01M10/0525 ,  H01M12/08 ,  H01M2300/0071 ,  Y02E60/128 ,  Y02T10/7011

Abstract: A lithium-lanthanum-titanium oxide sintered material has a lithium ion conductivity 3.0×10−4 Scm−1 or more at a measuring temperature of 27° C., the material is described by one of general formulas (1−a)LaxLi2-3xTiO3-aSrTiO3, (1−a)LaxLi2-3xTiO3-aLa0.5K0.5TiO3, LaxLi2-3xTi1-aMaO3-a, Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3 (0.55≦x≦0.59, 0≦a≦0.2, M=at least one of Fe or Ga), amount of Al contained is 0.35 mass % or less as Al2O3, amount of Si contained is 0.1 mass % or less as SiO2, and average particle diameter is 18 μm or more.

Abstract translation: 锂 - 镧 - 氧钛烧结材料在测量温度为27℃时的锂离子电导率为3.0×10 -4 Scm-1以上，该材料由通式（1-a）LaxLi2- （1-a）LaxLi2-3xTiO3-aLa0.5K0.5TiO3，LaxLi2-3xTi1-aMaO3-a，Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3（0.55＆nlE; x＆ ; 0.2，M = Fe或Ga中的至少一种），Al的含量相对于Al 2 O 3为0.35质量％以下，Si的含量为SiO 2为0.1质量％以下，平均粒径为18μm以上。

公开(公告)号：US3764591A

公开(公告)日：1973-10-09

申请号：US3764591D

申请日：1971-12-28

Applicant: TOHO TITANIUM CO LTD

Inventor： HOTTA Y ,  FUJII M ,  MIYOSHI K ,  IWASAKI Y

IPC: C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F1/56 ,  C08F3/10

CPC classification number: C08F10/00 ,  Y10S526/906 ,  C08F4/631

Abstract: Alpha -OLEFIN POLYMERIZATION IS EFFECTED IN THE PRESENCE OF A CATALYST COMPRISING: (1) AN ORGANO ALUMINUM COMPOUND, AND (2) A COMPOUND PREPARED BY MILLING A HALOGEN COMPOUND OF TITANIUM, WHEREIN SAID TITANIUM ION HAS A VALANCE OF LESS THAN THE MAXIMUM VALENCE, WITH AN Alpha , Beta -UNSATURATED CARBOXYLIC ESTER AND THEREAFTER TREATING WITH 0.1 - 5 MOLE PERCENT OF OXYGEN, BASED ON SAID TITANIUM COMPOUND.

Abstract translation: α-烯烃聚合在催化剂存在下受到影响：（1）有机铝化合物，和（2）通过研磨钛酸盐的化合物制备的化合物，其中所述的钛离子具有小于最大值的值 ，具有α，β-受体羧酸酯和具有0.1〜5％的氧含量的氧化亚铁，基于固体钛化合物。

公开(公告)号：US20250101153A1

公开(公告)日：2025-03-27

申请号：US18832591

申请日：2022-10-17

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Keisuke Goto ,  Toshiya Uozumi ,  Hiroyuki Kono ,  Shinta Marui ,  Chika Yoshizaki

IPC: C08F110/06

Abstract: A solid catalyst component for olefin polymerization containing magnesium, titanium, a halogen, a carbonate compound (A) represented by the following general formula (1): R1—O—C(═O)—O—Z—O—R2 (1), and an ether compound (B) having two or more ether groups, wherein a proportion of the ether compound (B) in a total of the carbonate compound (A) and the ether compound (B) is 33.0 to 80.0 mol %. The invention can provide a solid catalyst component for olefin polymerization using an ether compound having two or more ether groups and a carbonate compound as internal electron donating compounds, wherein the solid catalyst component for olefin polymerization has, in the polymerization of olefins, a moderately wide molecular weight distribution of an olefin polymer obtained therefrom and can increase the polymerization activity.

公开(公告)号：US20250100048A1

公开(公告)日：2025-03-27

申请号：US18730840

申请日：2022-12-27

Applicant: Toho Titanium Co., Ltd.

Inventor： Yosuke Inoue

IPC: B22F3/11 ,  C22C14/00

Abstract: The titanium porous body according to the present invention is in a form of a sheet, and has a titanium content of 97% by mass or more, an oxygen content of 0.9% by mass or more and 2.0% by mass or less, and a carbon content of 0.01% by mass or more and 0.06% by mass or less, and has a thickness of 0.3 mm or less, a porosity of 35% or more and 45% or less, an irreversible deformation amount after being pressurized at 65 MPa of 5.0% or less, and a bending strain at break of 0.005 or more.

公开(公告)号：US20240218087A1

公开(公告)日：2024-07-04

申请号：US18288916

申请日：2022-05-24

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Hideo Funabashi ,  Kunihiko Tashino ,  Hayashi Ogawa ,  Hirokazu Soga

IPC: C08F4/654 ,  C08F110/06 ,  C08F297/08

CPC classification number: C08F4/654 ,  C08F110/06 ,  C08F297/083 ,  C08F2810/30

Abstract: To provide a solid catalyst component for polymerization of an olefin, which can easily produce a polymer of an olefin, which is excellent in fluidity and also is high in rigidity even though the molecular weight distribution is narrow, without performing complicated polymerization treatment. A solid catalyst component for polymerization of an olefin includes magnesium, titanium and halogen, and further includes an aromatic carboxylic acid ester and a 1,3-diether compound as internal electron-donating compounds, wherein a content ratio of the titanium is 0.5 to 2.0% by mass, a content ratio of the aromatic carboxylic acid ester in a total content of the internal electron-donating compounds is 40 to 60 mol %, and a content ratio of the 1,3-diether compound in the total content of the internal electron-donating compounds is 40 to 60 mol %.

公开(公告)号：US20230374627A1

公开(公告)日：2023-11-23

申请号：US18029943

申请日：2021-09-16

Applicant: Toho Titanium Co., Ltd. ,  Toyota Jidosha Kabushiki Kaisha

Inventor： Shougo Tsumagari ,  Yosuke Inoue ,  Hiroyuki Kawai

IPC: C22C1/04 ,  C22C14/00

CPC classification number: C22C1/0458 ,  C22C14/00

Abstract: A method for manufacturing a porous metal body according to the present invention is a method for manufacturing a sheet-shaped porous metal body 4a containing titanium by sintering a titanium-containing powder 4 by heating it on a forming surface 2 of a forming die 1, the method including: an area setting step of setting, on the forming surface 2 of the forming die 1, an adhesion area Aa where it is located on an outer edge side of the forming surface 2 and the titanium-containing powder 4 adheres during sintering without a releasing layer 3, and an easily releasable area Ar where a releasing layer 3 is formed; after the area setting step, a powder deposition step of depositing the titanium-containing powder 4 in a dry process on the forming surface 2; and after the powder deposition step, a powder sintering step of sintering the titanium-containing powder 4 on the forming surface 2 while heating the titanium-containing powder 4 at a temperature of 950° C. or more on the forming surface 2 and allowing the titanium-containing powder 4 located on the adhesion area Aa to adhere to the adhesion area Aa.