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51.发明授权Functionalization of polymers based on Koch chemistry and derivatives thereof 失效基于Koch化学及其衍生物的聚合物的功能化
公开(公告)号：US5717039A
公开(公告)日：1998-02-10
申请号：US470883
申请日：1995-06-06
申请人： Joseph Victor Cusumano , William Daniel Diana , Jacob Emert , Keith Raymond Gorda , Richard H. Schlosberg , David A. Young , Albert I. Yezrielev , William Bernard Eckstrom , Edris Eileen Manry , Michael John Keenan
发明人： Joseph Victor Cusumano , William Daniel Diana , Jacob Emert , Keith Raymond Gorda , Richard H. Schlosberg , David A. Young , Albert I. Yezrielev , William Bernard Eckstrom , Edris Eileen Manry , Michael John Keenan
IPC分类号： C10M159/12 , B01J10/00 , B01J19/24 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/32 , C08F8/34 , C08L23/26 , C08L101/00 , C08L101/06 , C10L1/14 , C10L1/18 , C10L1/195 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/00 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , C10M159/18 , C10N20/04 , C10N30/04
CPC分类号： C10M159/18 , B01J19/2415 , B01J19/242 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/14 , C08F8/18 , C08F8/32 , C08F8/34 , C10L1/143 , C10L1/1817 , C10L1/195 , C10L1/198 , C10L1/206 , C10L1/221 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/2475 , C10L1/2493 , C10L1/2691 , C10L1/285 , C10L1/303 , C10L10/04 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , B01J2219/00094 , C08F2800/20 , C10L1/208 , C10L1/2387 , C10L1/2683 , C10L1/30 , C10M2207/023 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/289 , C10M2209/00 , C10M2209/02 , C10M2209/082 , C10M2209/10 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/22 , C10M2215/221 , C10M2215/224 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/024 , C10M2217/046 , C10M2217/06 , C10M2219/062 , C10M2227/061 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/05 , C10N2210/06 , C10N2210/07 , C10N2210/08 , C10N2240/00 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/22 , C10N2240/30 , C10N2240/40 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2270/02
摘要： A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.
摘要翻译： 作为至少一种数均分子量为至少500且每个聚合物链至少烯属双键的聚合物与一氧化碳和亲核捕集剂的反应产物的Koch官能化产物。 本发明包括官能化聚合物，其衍生物及其制备方法。
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52.发明授权Polyol ester compositions with unconverted hydroxyl groups for use as lubricant base stocks 失效具有未转化羟基的多元醇酯组合物，用作润滑剂基础油料
公开(公告)号：US5698502A
公开(公告)日：1997-12-16
申请号：US712023
申请日：1996-09-11
申请人： Bernie J. Pafford , Jeenok T. Kim , Patrick E. Godici , Haven S. Aldrich , Richard H. Schlosberg , Martin A. Krevalis
发明人： Bernie J. Pafford , Jeenok T. Kim , Patrick E. Godici , Haven S. Aldrich , Richard H. Schlosberg , Martin A. Krevalis
IPC分类号： C07C69/30 , C07C69/33 , C10M101/00 , C10M105/40 , C10M105/42 , C10M105/74 , C10M105/76 , C10M107/02 , C10M107/32 , C10M107/48 , C10M107/50 , C10M129/74 , C10M129/78 , C10N30/08 , C10N30/10 , C10N40/13 , C10M129/76
CPC分类号： C10M129/78 , C07C69/30 , C07C69/33 , C10M105/40 , C10M105/42 , C10M129/74 , C10M2207/289 , C10M2207/30 , C10N2240/00 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/14 , C10N2240/22 , C10N2240/30 , C10N2240/401 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： A synthetic ester composition which exhibits thermal and oxidative stability, lower friction coefficient and lower wear, wherein the ester composition comprises the reaction product of: a linear or branched alcohol having the general formula R(OH).sub.n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and at least one linear and/or branched acid which has a carbon number in the range between about C.sub.4 to C.sub.20, wherein the synthetic ester composition has a hydroxyl number of between about greater than 5 to 180, preferably between about greater than 5 to 100, and more preferably between about 10 to 80.
摘要翻译： 一种表现出热和氧化稳定性，较低摩擦系数和较低磨损的合成酯组合物，其中该酯组合物包含以下反应产物：具有通式R（OH）n的直链或支链醇，其中R为脂族或环 具有约2至20个碳原子并且n至少为2的脂族基团; 和至少一种碳数在约C4至C20之间的直链和/或支链酸，其中所述合成酯组合物的羟值为约大于5至180，优选约大于5至100 ，更优选为约10〜80。
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53.发明授权Polymers having terminal hydroxyl aldehyde, or alkylamino substitutents and derivatives thereof 失效具有末端羟基醛的聚合物或烷基氨基取代基及其衍生物
公开(公告)号：US5674950A
公开(公告)日：1997-10-07
申请号：US391845
申请日：1995-02-27
申请人： Warren A. Thaler , Jacob I. Emert , Istvan T. Horvath , Richard H. Schlosberg , David A. Young , Stephen Zushma
发明人： Warren A. Thaler , Jacob I. Emert , Istvan T. Horvath , Richard H. Schlosberg , David A. Young , Stephen Zushma
IPC分类号： C10M145/20 , C08F8/00 , C08F8/28 , C08F8/30 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58 , C10N30/04
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A polymer having a terminal hydroxyl, aldehyde or alkylamino substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a polyene (diene, e.g.), monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical. Preferably, the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.
摘要翻译： 具有末端羟基，醛或烷基氨基取代基的聚合物，其可以直接或以衍生形式用作燃料和润滑油组合物的分散剂，其中聚合物的Mn为约300至10,000，并且衍生自聚烯烃 其衍生自多烯（二烯，例如），式H2C = CHR4的单体，其中R 4是氢或直链或支链烷基。 优选地，聚烯烃具有至少约30％的末端亚乙烯基不饱和键。 特别理想的胺衍生物可以通过单步氨基甲基化方法或两步加氢甲酰化和还原胺化方法形成。
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公开(公告)号：US5534652A
公开(公告)日：1996-07-09
申请号：US324544
申请日：1994-10-18
申请人： Larry O. Jones , Paul H. Daniels , Leonard G. Krauskopf , Konstantinos R. Rigopoulos , Richard H. Schlosberg
发明人： Larry O. Jones , Paul H. Daniels , Leonard G. Krauskopf , Konstantinos R. Rigopoulos , Richard H. Schlosberg
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , Y02P20/582
摘要： A process for the formation of esters from at least one phthalic anhydride residue stream produced from the vapor phase oxidation of o-xylene, naphthalene and/or the like which comprises: (a) adding a phthalic anhydride residue stream and a mono-alcohol to a reaction vessel to form a reaction mixture; and (b) heating the reaction mixture and maintaining a pressure sufficient to obtain boiling of the reaction mixture thereby converting any acid and/or anhydride components of the phthalic anhydride residue stream to an ester.
摘要翻译： 从由邻二甲苯，萘等的气相氧化产生的至少一种邻苯二甲酸酐残余物流形成酯的方法，其包括：（a）将邻苯二甲酸酐残余物流和单醇加入到 形成反应混合物的反应容器; 和（b）加热反应混合物并保持足够的压力以获得反应混合物的沸腾，从而将邻苯二甲酸酐残余物流的任何酸和/或酸酐组分转化成酯。
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55.发明授权Refrigeration working fluid compositions containing difluoroethane or pentafluoroethane and a polyolester lubricant 失效含有二氟乙烷或五氟乙烷和多元醇酯润滑剂的制冷工作流体组合物
公开(公告)号：US5494597A
公开(公告)日：1996-02-27
申请号：US298515
申请日：1994-08-30
IPC分类号： C09K5/04 , C10M105/38 , C10M171/00 , C10N20/02 , C10N30/00 , C10N40/30 , C10M105/34
CPC分类号： C10M171/008 , C09K5/045 , C10M105/38 , C09K2205/22 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2211/022 , C10M2211/06 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： There are disclosed refrigeration working fluid compositions comprising R125 (pentafluoroethane) or R152a (1,1-difluoroethane) refrigerants and certain polyol esters of C.sub.7 to C.sub.10 branched alkanoic acids or mixtures of such branched acids with linear C.sub.7 to C.sub.10 monoalkanoic acids. The polyols are neopentylglycol, technical grade pentaerythritol and trimethylolpropane; the esters exhibit suitable viscosity ranges and miscibility with refrigerants over a broad compositional range. The acids have a defined average effective carbon chain length in order to be miscible with the refrigerants over the range of 5 to 55 wt. % ester lubricant.
摘要翻译： 公开了包含R125（五氟乙烷）或R152a（1,1-二氟乙烷）制冷剂和C7至C10支链烷酸的某些多元醇酯或这些支链酸与线性C 7至C 10单链烷酸的混合物的制冷工作流体组合物。 多元醇是新戊二醇，工业级季戊四醇和三羟甲基丙烷; 该酯在宽的组成范围内表现出合适的粘度范围和与制冷剂的混溶性。 这些酸具有确定的平均有效碳链长度，以便与5至55重量％范围内的制冷剂混溶。 ％酯润滑剂。
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56.发明授权
公开(公告)号：US5391313A
公开(公告)日：1995-02-21
申请号：US042031
申请日：1993-04-02
申请人： Shlomo Antika , Thomas G. Dietz , Richard H. Schlosberg , David W. Turner , George A. Weisgerber
发明人： Shlomo Antika , Thomas G. Dietz , Richard H. Schlosberg , David W. Turner , George A. Weisgerber
IPC分类号： C09K5/04 , C10M105/38 , C10M105/42 , C10M105/44 , C10M171/00 , C10M105/18 , C09K5/00
CPC分类号： C09K5/045 , C10M105/38 , C10M105/42 , C10M105/44 , C10M171/008 , C10M2207/283 , C10M2207/30 , C10M2211/022 , C10M2211/06 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： A refrigerator working fluid which comprises(a) tetrafluoroethane, and(b) a synthetic ester lubricant with a viscosity of about 150 cSt or less at 40.degree. C. and having the formula (R.sub.1 -R.sub.2).sub.n R.sub.3wherein R.sub.1 is ##STR1## in which R.sub.5, R.sub.6 and R.sub.7 are each independently hydrocarbyl group of from 1 to 7 carbon atoms with the proviso that the sum of carbon atoms in R.sub.5 +R.sub.6 +R.sub.7 is from 3 to 9,R.sub.2 is selected from the group consisting of (CH.sub.2 --CH.sub.2 --O--).sub.b, ##STR2## and mixtures thereof, where b is an integer from 1 to 3, R.sub.3 is a monobasic or polybasic carboxylic acid radical of the formula ##STR3## where R.sub.4 is a hydrocarbyl group having m carbon atoms where m is an integer from 1 to 9, andn is an integer from 1 to 4.
摘要翻译： 一种冰箱工作流体，其包含（a）四氟乙烷和（b）在40℃下具有约150cSt或更低的粘度并具有式（R1-R2）nR3的合成酯润滑剂，其中R1为
其中R5，R6和R7各自独立为1至7个碳原子的烃基，条件是R5 + R6 + R7中的碳原子总数为3至9，R2选自（CH2- CH2-O-）b，其组合和其混合物，其中b是1至3的整数，R 3是下式的一元或多元羧酸基团，其中R 4是具有m个碳原子的烃基，其中 m为1〜9的整数，n为1〜4的整数。 -
57.发明授权
公开(公告)号：US5034154A
公开(公告)日：1991-07-23
申请号：US220587
申请日：1988-07-18
IPC分类号： C08F2/06 , C08F2/04 , C08F20/26 , C08F220/10 , C08F220/12 , C08F220/28 , C08L61/20 , C09D4/02 , C09D133/04 , C09D133/06
CPC分类号： C09D133/066 , C08L61/20
摘要： According to one aspect of the present invention, an improved method for preparing acrylic copolymer resins is provided in which the polymerization solvent includes an internal olefin. The monomers comprise hydroxy-substituted alkyl (meth)acrylates, and non-hydroxy substituted alky (meth)acrylates, and the process provides an improved method for forming low molecular weight acrylic resins useful as components in high solids acrylic coatings suitable for electrostatic spraying. The polymerization solvent can remain in the resin to become the solvent employed in the higher solids coating containing the thus-forming acrylic resins and provides surprisingly improved electrical resistivity and color decreased over previously used polymerization solvents, and has good compatibility with the acrylic monomer/resin system.
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公开(公告)号：US4836912A
公开(公告)日：1989-06-06
申请号：US94309
申请日：1987-09-04
CPC分类号： C10G49/04 , B01J31/1825 , B01J31/183 , B01J31/2243 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： Disclosed are hydroconversion processes catalyzed by aromatic-metal chelate compositions which are deficient in hydrogen, are cross-linked, and which are comprised of two or more heteroatoms, wherein at least one of the heteroatoms are part of a 5 to 6 member heterocyclic ring, and wherein the metal constituent is selected from Groups III, IVB, VB, VIB, VIIB, and VIII of the Periodic Table of the Elements, and the heteroatom is selected from sulfur, oxygen, and nitrogen.
摘要翻译： 公开了由缺乏氢的芳族 - 金属螯合物组合物催化的加氢转化方法，其交联并由两个或更多个杂原子组成，其中至少一个杂原子是5至6元杂环的一部分， 并且其中金属成分选自元素周期表的III，IVB，VB，VIB，VIIB和VIII族，杂原子选自硫，氧和氮。
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公开(公告)号：US4652647A
公开(公告)日：1987-03-24
申请号：US772462
申请日：1985-09-04
IPC分类号： B01J31/16 , B01J31/18 , C07F11/00 , C07F13/00 , C07F15/02 , C07F15/06 , C10G49/12 , C07F5/00 , C07F7/00 , C07F9/00 , C07F15/04
CPC分类号： C10G49/12 , B01J31/1825 , B01J31/183 , C07F11/005 , C07F13/005 , C07F15/025 , C07F15/065 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： Disclosed are aromatic-metal chelate compositions which are deficient in hydrogen, are cross-linked, and which are comprised of two or more heteroatoms, wherein at least one of the heteroatoms are part of a 5 to 6 member heterocyclic ring, and wherein the metal constituent is selected from Groups III, IVB, VB, VIB, VIIB, and VIII of the Periodic Table of the Elements, and the heteroatom is selected from sulfur, oxygen, and nitrogen.
摘要翻译： 公开了缺乏氢的交联的芳族金属螯合物组合物，它们由两个或多个杂原子组成，其中至少一个杂原子是5至6元杂环的一部分，其中金属 组分选自元素周期表的III，IVB，VB，VIB，VIIB和VIII族，杂原子选自硫，氧和氮。
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60.发明授权
公开(公告)号：US4072475A
公开(公告)日：1978-02-07
申请号：US720144
申请日：1976-09-03
CPC分类号： C10L9/02 , C10B57/08 , C10J3/00 , C10J2300/0903 , C10J2300/093 , Y10S44/905
摘要： Coal is electrophilically aromatically substituted (i.e., alkylated or acylated) in the presence of an alkylating or acylating agent with or without a catalyst under mild conditions to give a treated coal product. This treated coal product may then be solvent extracted to give an extract and an upgraded coal residue, with this residue being subjected to a gasification process procedure or the treated coal product may be subjected to gasification process procedures without any prior extraction being performed. By means of either technique, a material is prepared for which the rate of gasification and the yield of desired product upon gasification is dramatically increased when compared with nonelectrophilically aromatically substituted material (i.e., raw coal). An improved gasification process is disclosed comprising the steps of electrophilically aromatically substituting coal and subjecting such pretreated coal, either extracted or unextracted to gasification process techniques.
摘要翻译： 在温和条件下，在具有或不具有催化剂的烷基化或酰化剂的存在下，煤被亲电芳烃取代（即烷基化或酰化），得到经处理的煤制品。 然后可以对经处理的煤产品进行溶剂萃取，得到提取物和升级后的煤渣，将该残余物进行气化处理程序，或者经处理的煤制品可进行气化处理程序，而不进行任何先前的提取。 通过任一技术，制备了与非吸附性芳香取代的材料（即原料煤）相比，气化速率和所需产物在气化时的产率显着增加的材料。 公开了一种改进的气化方法，其包括以下步骤：亲煤取代煤，并对经过这些预处理的煤进行气化处理技术的提取或未提取。
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