Thermoset coating compositions having improved hardness
    8.
    发明授权
    Thermoset coating compositions having improved hardness 失效
    具有改善硬度的热固性涂料组合物

    公开(公告)号:US5536794A

    公开(公告)日:1996-07-16

    申请号:US364059

    申请日:1994-12-27

    摘要: The present invention provides for amino-crosslinkable coating formulations based on a mixture of a di or polyhydroxy functional polymeric component selected from the group consisting of diesters, polyesters, alkyd polymers, acrylic polymers and polycarbonate polymers, a methylol (alkoxymethyl) amino crosslinking agent and a bis-aromatic polyhydric phenol component having the structure of formula I: ##STR1## wherein X is selected from the group consisting of carbon to carbon covalent bond, oxygen, sulfur, --S--S--, --CO--, --SO--, --SO.sub.2 -- and a divalent organic radical having a molecular weight less than about 400, and wherein Y is independently selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.4 alkyl and C.sub.1 to C.sub.4 alkoxy.

    摘要翻译: 本发明提供了基于选自二酯,聚酯,醇酸聚合物,丙烯酸聚合物和聚碳酸酯聚合物的二或多羟基官能聚合物组分,羟甲基(烷氧基甲基)氨基交联剂和羟甲基(烷氧基甲基)氨基交联剂的混合物的氨基可交联涂料配方, 具有式I结构的双芳族多元酚组分:其中X选自碳 - 碳共价键,氧,硫,-SS - , - CO - , - SO - , - SO 2 - 和分子量小于约400的二价有机基团,其中Y独立地选自氢,卤素,C 1至C 4烷基和C 1至C 4烷氧基。

    Phenol terminated diester compositions derived from discarboxylic acids,
polyester polymers or alkyd polymers, and curable compositions
containing same
    9.
    发明授权
    Phenol terminated diester compositions derived from discarboxylic acids, polyester polymers or alkyd polymers, and curable compositions containing same 失效
    由酚羧酸,聚酯聚合物或醇酸聚合物衍生的苯酚封端的二酯组合物和含有它们的可固化组合物

    公开(公告)号:US5326831A

    公开(公告)日:1994-07-05

    申请号:US6229

    申请日:1993-01-19

    摘要: The present invention is directed towards a process for preparing non-liquid crystalline phenol-terminated diester compositions characterized by the structure of formula 1: ##STR1## wherein R is an aliphatic divalent hydrocarbon radical containing 2 to 40 carbon atoms or a mixture of such radicals, provided however that R contains at least about 8 carbon atoms when n is 0 and p is 0, R.sub.1 is an aliphatic or cycloaliphatic hydrocarbon radical containing 2 to 40 carbon atoms or a mixture of such radicals, R.sub.2 is an aliphatic, aromatic or a mixture of aliphatic and aromatic hydrocarbon radicals having from 2 to 40 carbon atoms, A is divalent aromatic radical selected from the group consisting of phenylene, naphthylene or his phenylene, p is 0 or 1, n is 0 or an integer ranging from 1 to about 40, provided however, that p is 0 when n is 0 and p is 1 when n is an integer.The invention is also directed to a single stage direct esterification or multi stage esterification processes for producing the aforementioned diesters of formula 1 either with or without the use of esterification catalysts, and is particularly directed to such processes for preparing diesters of reduced color using a low temperature process in combination with catalyst systems containing a phosphorous acid or derivative thereof.

    摘要翻译: 本发明涉及一种制备非液晶苯酚封端的二酯组合物的方法,其特征在于式1的结构:其中R是含有2至40个碳原子的脂族二价烃基或 但是,当n为0且p为0时,R包含至少约8个碳原子,R 1为含有2至40个碳原子的脂族或脂环族烃基或这些基团的混合物,R 2为 脂族,芳族或具有2至40个碳原子的脂族和芳族烃基的混合物,A是选自亚苯基,亚萘基或其亚苯基的二价芳族基团,p为0或1,n为0或整数 但是,如果n是0,p是0,当n是整数时,p是1。 本发明还涉及使用或不使用酯化催化剂制备上述式1的二酯的单阶段直接酯化或多阶段酯化方法,特别涉及这样的使用低 与含有亚磷酸或其衍生物的催化剂体系结合使用。