Crosslinked polyamino-polyamide in hair conditioning compositions

    公开(公告)号:US4189468A

    公开(公告)日:1980-02-19

    申请号:US881513

    申请日:1978-02-27

    摘要: A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di-carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis-primary and mono- or bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of (a') simple bi-functional compounds selected from bis-halohydrins, bis-azetidinium, bis-haloacyl diamine and alkyl bis-halides, (b') oligomers obtained by the reaction of (1') a compound selected from the group consisting of the compounds in (a') above or an epihalohydrin, a bis-epoxide, or a bis-unsaturated derivative with (2') a compound reactive with the compound in (1'), and (c') the quaternized compounds comprising said crosslinked polymer alkylated with an alkylating agent selected from the group consisting of (a) epoxides, (b) ethylenically unsaturated compounds, (c) chloroacetic acid, and (d) alkane sultone selected from the group consisting of propane sultone and butane sultone. The crosslinking agent is employed in amounts of 0.025-0.35 mole per amine group in said polyamino-polyamide. The said crosslinked polymer is soluble in water in amounts of 10 weight percent thereof without essentially any gel formation and a 10 weight percent aqueous solution of the said crosslinked polymer has a viscosity greater than 3 centipoises at 25.degree. C.

    Anionic surface active compositions
    52.
    发明授权
    Anionic surface active compositions 失效
    阴离子表面活性组分

    公开(公告)号:US3983171A

    公开(公告)日:1976-09-28

    申请号:US457354

    申请日:1974-04-02

    IPC分类号: C07C59/125 C11D1/06 C07C59/22

    摘要: An anionic compound having surface-active properties and responding to the formula ##EQU1## in which R is selected from the group consisting of alkyl and alkenyl radicals having 8 to 22 carbon atoms and alkyl-aryl radicals having 12 to 22 carbon atoms;X and X' are each selected from the group consisting of oxygen, sulfur and sulfoxide;A is selected from the group consisting of ethylene, propylene and butylene;A' is selected from the group consisting of --C.sub.2 H.sub.3 (CH.sub.2 OH)-- and --CH.sub.2 CHOH--CH.sub.2 ;A" is selected from the group consisting of --CH.sub.2 CHOH--CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 -- and --CH.sub.2 CH(CH.sub.3)--;at least one of the radicals A' and A" is --CH.sub.2 CHOH--CH.sub.2 or C.sub.2 H.sub.3 (CH.sub.2 OH);m and n represent numbers having a statistical average value between 0 and 10 inclusive;R' is selected from the group consisting of hydrogen and a lower alkyl radical having from 0 to 2 carbon atoms; andIn which when m and n are both equal to zero, X' must be sulfoxide.

    摘要翻译: 具有表面活性特性并对式RX-(AO)m -A'O)n-A“-X'-CH-COOH(I)| R'的阴离子化合物,其中R选自 具有8-22个碳原子的烷基和烯基以及具有12-22个碳原子的烷基 - 芳基; X和X'各自选自氧,硫和亚砜; A选自乙烯,丙烯和丁烯; A'选自-C 2 H 3(CH 2 OH) - 和-CH 2 CHOH-CH 2; A“选自-CH 2 CHOH-CH 2 - , - CH 2 CH 2 CH 2 - 和-CH 2 CH(CH 3) - ; 基团A'和A“中的至少一个是-CH 2 CHOH-CH 2或C 2 H 3(CH 2 OH); m和n表示具有0和10之间的统计平均值的数字; R'选自氢和具有0至2个碳原子的低级烷基; 当M和N两个等于零时,X'必须是亚砜。