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51.发明授权Method of synthesizing an olefin product from an oxygenate feedstock utilizing silicoaluminophosphate molecular sieves 有权使用硅铝磷酸盐分子筛从含氧化合物原料合成烯烃产物的方法公开(公告)号：US08049053B2
公开(公告)日：2011-11-01
申请号：US13015709
申请日：2011-01-28
CPC分类号： C07C1/20 , B01J29/85 , C01B39/54 , C07C2529/85 , Y02P30/42 , Y10S423/30 , Y10S502/514 , C07C11/02
摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.
摘要翻译： 在合成硅铝磷酸盐分子筛的方法中，通过组合磷源和至少一种有机导向剂来制备合成混合物; 然后将铝源引入磷源和有机导向剂的组合中，其中当添加铝源时，组合的温度小于或等于50℃。 加入硅源后，将合成混合物加热至约100℃至约300℃的结晶温度，并回收分子筛。
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52.发明申请Method of Preparing A Molecular Sieve and Its Use In The Conversion Of Oxygenates To Olefins 有权分子筛的制备方法及其在烯烃转化中的应用公开(公告)号：US20110152478A1
公开(公告)日：2011-06-23
申请号：US12916964
申请日：2010-11-01
申请人： Machteld M. Mertens , Chunshe Cao
发明人： Machteld M. Mertens , Chunshe Cao
CPC分类号： C01B39/54 , B01J29/85 , B01J35/023 , B01J2229/42 , C07C1/20 , C07C1/24 , C07C2529/85 , C08F10/00 , Y02P20/52 , Y02P30/42 , Y10S423/30 , Y10T428/2982 , C07C11/02 , C07C11/04 , C08F4/02
摘要： A method of preparing a silicoaluminophosphate molecular sieve which comprises the steps of combining a source of silica, a source of phosphorous, a source of alumina and water to form a primary mixture; adding a structure directing agent to said mixture and optional seeds to form a synthesis mixture. The synthesis mixture is synthesized by heating the mixture to a crystallization temperature to form the sieve. The molar ratio of the structure directing agent relative to the source of alumina may vary between 1.3 and 1.9 and the ratio of water to the source of alumina may vary between 20 to 34.
摘要翻译： 一种制备硅铝磷酸盐分子筛的方法，其包括将二氧化硅源，磷源，氧化铝源和水混合以形成初级混合物的步骤; 向所述混合物和任选的种子中加入结构导向剂以形成合成混合物。 通过将混合物加热至结晶温度以形成筛子来合成合成混合物。 结构导向剂相对于氧化铝源的摩尔比可以在1.3和1.9之间变化，并且水与氧化铝源的比率可以在20至34之间变化。
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公开(公告)号：US20110124937A1
公开(公告)日：2011-05-26
申请号：US13015709
申请日：2011-01-28
CPC分类号： C07C1/20 , B01J29/85 , C01B39/54 , C07C2529/85 , Y02P30/42 , Y10S423/30 , Y10S502/514 , C07C11/02
摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.
摘要翻译： 在合成硅铝磷酸盐分子筛的方法中，通过组合磷源和至少一种有机导向剂来制备合成混合物; 然后将铝源引入磷源和有机导向剂的组合中，其中当添加铝源时，组合的温度小于或等于50℃。 加入硅源后，将合成混合物加热至约100℃至约300℃的结晶温度，并回收分子筛。
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公开(公告)号：US07901649B2
公开(公告)日：2011-03-08
申请号：US11268016
申请日：2005-11-07
CPC分类号： C07C1/20 , B01J29/85 , C01B39/54 , C07C2529/85 , Y02P30/42 , Y10S423/30 , Y10S502/514 , C07C11/02
摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.
摘要翻译： 在合成硅铝磷酸盐分子筛的方法中，通过组合磷源和至少一种有机导向剂来制备合成混合物; 然后将铝源引入磷源和有机导向剂的组合中，其中当添加铝源时，组合的温度小于或等于50℃。 加入硅源后，将合成混合物加热至约100℃至约300℃的结晶温度，并回收分子筛。
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公开(公告)号：US20100087610A1
公开(公告)日：2010-04-08
申请号：US12533745
申请日：2009-07-31
CPC分类号： C08F10/00 , B01J29/85 , C01B39/54 , C07C1/20 , C07C2529/85 , C08F110/02 , C08F210/16 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/02 , C08F4/16 , C08F4/12 , C08F210/06
摘要： A crystalline microporous silicoaluminophosphate (SAPO) molecular sieve is prepared by: (a) providing a reaction mixture having a molar composition within the following ranges: P:Al from 0.75 to 1.25, Si:Al2 from 0.01 to 0.32, H2O:Al2 from 25 to 50, and R:Al2 from 1 to 3, where R designates a structure directing agent (template), and wherein the molar ratios for the aluminum, phosphorus, and silicon sources are calculated based on the oxide forms; (b) heating the mixture to a crystallization temperature of between 150° C. to 250° C. to form the crystalline molecular sieve within the reaction mixture; and (c) following crystallization in step (b), aging the crystalline molecular sieve in an alkaline liquid at a temperature below the crystallization temperature from 0.5 hour for up to 120 hours. Aging can affect both catalyst life and catalyst activity.
摘要翻译： 通过以下步骤制备结晶微孔硅铝磷酸盐（SAPO）分子筛：（a）提供具有以下范围内的摩尔组成的反应混合物：P：Al为0.75至1.25，Si：Al 2为0.01至0.32，H 2 O：Al 2为25 至50，R：Al 2为1至3，其中R表示结构导向剂（模板），其中基于氧化物形式计算铝，磷和硅源的摩尔比; （b）将混合物加热至150℃至250℃的结晶温度以在反应混合物内形成结晶分子筛; 和（c）在步骤（b）中结晶之后，在低于结晶温度的温度下将结晶分子筛在碱性液体中老化0.5小时达120小时。 老化可影响催化剂寿命和催化剂活性。
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公开(公告)号：US07375050B2
公开(公告)日：2008-05-20
申请号：US10425587
申请日：2003-04-28
IPC分类号： C01B15/16 , C01B25/26 , B01J27/00 , B01J27/182 , C07C1/00
CPC分类号： B01J29/7015 , B01J29/85 , C01B37/04 , C01B37/08 , C01B39/54 , C10G3/45 , C10G3/49 , C10G3/62 , C10G2400/20 , Y02P30/20 , Y10S423/32
摘要： Disclosed are methods and compositions of synthesis mixtures for the synthesis of aluminophosphates and silicoaluminophosphate molecular sieves, which enable the control and adjustment of the crystal particle size of aluminophosphates and silicoaluminophosphate molecular sieves. The synthesis mixture compositions used have two or more organic templates present at a molar ratio of total template to aluminum of ≦1.25; such a synthesis mixture is susceptible to control of product particle size through variation in the amount of seeds used in the synthesis.
摘要翻译： 公开了用于合成铝磷酸盐和硅铝磷酸盐分子筛的合成混合物的方法和组合物，其能够控制和调节铝磷酸盐和硅铝磷酸盐分子筛的晶体粒径。 所用的合成混合物组合物具有两个或更多个有机模板，其总模板与铝的摩尔比为<= 1.25; 这样的合成混合物易于通过合成中使用的种子的量的变化来控制产物的粒度。
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57.发明申请公开(公告)号：US20070191663A1
公开(公告)日：2007-08-16
申请号：US11699166
申请日：2007-01-29
CPC分类号： B01J29/7026 , C01B39/48 , C07C2/12 , C10G49/08 , C10G2400/20 , C10G2400/22 , C07C11/02
摘要： A method of making a crystalline molecular sieve of MFS framework type, said method comprising the steps of (a) adding at least one source of ions of tetravalent element (Y), at least one source of ions of trivalent element (X), at least one hydroxide source (OH−), at least one structure-directing-agent (R), at least one seed source (Seed), and water (H2O) to form a mixture having the following mole composition (expressed in term of oxide): YO2:(n)X2O3:(x)OH−:(y)R:(z)H2O+(m)Seed wherein the m is in the range of from about 10 wtppm to about 2 wt. % (based on total weight of the synthesis mixture), the n is in the range of from about 0.005 to 0.05, the x is in the range of from about 0.01 to about 0.3, the y is in the range of from about 0.03 to about 2; and the z is in the range of from about 3 to about 30; and (b) treating said mixture under crystallization conditions to form said crystalline molecular sieve substantially free of non-MFS material, wherein said crystallization conditions comprise a temperature in the range of from about 150° C. to about 250° C., and crystallization time less than 100 hr, the weight hourly throughput is at least 0.001 hr−1.
摘要翻译： 一种制备MFS框架型结晶分子筛的方法，所述方法包括以下步骤：（a）将至少一种四价元素（Y）的离子的至少一种源，至少一种三价元素（X）的离子源加入 至少一种氢氧化物源（OH - ），至少一种结构导向剂（R），至少一种种子源（Seed）和水（H 2 O 2） ）以形成具有以下摩尔组成（以氧化物表示）的混合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> YO 2： （n）X 2 O 3（x）OH - （y）R：（z）H 2 SUB> O +（m）种子<？in-line-formula description =“In-line Formulas”end =“tail”？>其中m在约10重量ppm至约2重量％的范围内。 ％（基于合成混合物的总重量），n在约0.005至0.05的范围内，x在约0.01至约0.3的范围内，y在约0.03至 约2; 并且z在约3至约30的范围内; 和（b）在结晶条件下处理所述混合物以形成基本上不含非MFS材料的所述结晶分子筛，其中所述结晶条件包括在约150℃至约250℃范围内的温度和结晶 时间小于100小时，重量小时生产量至少为0.001小时-1。
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58.发明授权Molecular sieve catalyst composition, its making and use in conversion processes 有权分子筛催化剂组成，其制备和用途在转化过程中公开(公告)号：US07160831B2
公开(公告)日：2007-01-09
申请号：US10178374
申请日：2002-06-24
申请人： Stephen N. Vaughn , Yun-feng Chang , Luc R. M. Martens , Kenneth R. Clem , Machteld M. Mertens , Albert E. Schweizer
发明人： Stephen N. Vaughn , Yun-feng Chang , Luc R. M. Martens , Kenneth R. Clem , Machteld M. Mertens , Albert E. Schweizer
IPC分类号： B01J29/06
CPC分类号： C10G3/49 , B01J29/83 , B01J29/84 , B01J29/85 , B01J37/0009 , B01J37/0045 , B01J2229/12 , B01J2229/14 , B01J2229/24 , B01J2229/34 , B01J2229/42 , C07C1/20 , C07C7/04 , C07C7/08 , C07C2529/85 , C08F10/00 , C08F110/02 , C08F110/06 , C10G2400/20 , C10G2400/22 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C11/04 , C08F4/12 , C08F4/16 , C08F4/025 , C08F4/005
摘要： The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to making a formulated molecular sieve catalyst composition from a slurry of formulation composition of a synthesized molecular sieve that has not been fully dried, a binder and an optional matrix material. In a more preferred embodiment, the weight ratio of the binder to the molecular sieve and/or the solid content of the slurry is controlled to provide an improved attrition resistant catalyst composition, particularly useful in a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
摘要翻译： 本发明涉及分子筛催化剂组合物，制备或形成分子筛催化剂组合物的方法，以及使用该催化剂组合物的转化方法。 特别地，本发明涉及从尚未完全干燥的合成分子筛的配方组合物的浆料，粘合剂和任选的基质材料制备配制的分子筛催化剂组合物。 在更优选的实施方案中，控制粘合剂与分子筛的重量比和/或浆料的固体含量，以提供改进的耐磨性催化剂组合物，特别可用于生产烯烃的转化方法 乙烯和/或丙烯，优选含有氧化合物的原料。
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公开(公告)号：US06838586B2
公开(公告)日：2005-01-04
申请号：US10335613
申请日：2002-12-31
申请人： Machteld M. Mertens , Brita Engels , Ronald G. Searle , Grigore Pop , Irina Rodica Tamas , Rodica Ganea , Ruxandra Birjega
发明人： Machteld M. Mertens , Brita Engels , Ronald G. Searle , Grigore Pop , Irina Rodica Tamas , Rodica Ganea , Ruxandra Birjega
CPC分类号： C10G3/49 , B01J29/85 , C01B37/08 , C07C1/20 , C07C2529/85 , C10G2300/703 , C10G2400/20 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The invention is directed to a method for making a silicoaluminophosphate (SAPO) molecular sieve from a reaction mixture comprising components present in amounts sufficient to form the SAPO, the reaction mixture having a first pH. The method comprises the steps of: adding an acid to the reaction mixture after the reaction mixture undergoes a change in pH from the first pH; and crystallizing the SAPO from the reaction mixture. The present invention is also directed to a silicoaluminophosphate molecular sieve made by this process.
摘要翻译： 本发明涉及从包含以足以形成SAPO的量存在的组分的反应混合物制备硅铝磷酸盐（SAPO）分子筛的方法，该反应混合物具有第一pH。 该方法包括以下步骤：在反应混合物从第一pH经历pH变化之后向反应混合物中加入酸; 并从反应混合物中使SAPO结晶。 本发明还涉及通过该方法制备的硅铝磷酸盐分子筛。
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60.发明授权Molecular sieve catalyst composition, its making and use in conversion processes 失效分子筛催化剂组成，其制备和用途在转化过程中公开(公告)号：US06787501B2
公开(公告)日：2004-09-07
申请号：US10178578
申请日：2002-06-24
申请人： Stephen N. Vaughn , Yun-feng Chang , Luc R. M. Martens , Kenneth R. Clem , Machteld M. Mertens , Albert E. Schweizer
发明人： Stephen N. Vaughn , Yun-feng Chang , Luc R. M. Martens , Kenneth R. Clem , Machteld M. Mertens , Albert E. Schweizer
IPC分类号： B01J2906
CPC分类号： C10G3/49 , B01J29/83 , B01J29/84 , B01J29/85 , B01J37/0009 , B01J37/0045 , B01J2229/12 , B01J2229/14 , B01J2229/24 , B01J2229/34 , B01J2229/42 , C07C1/20 , C07C7/04 , C07C7/08 , C07C2529/85 , C08F10/00 , C08F110/02 , C08F110/06 , C10G2400/20 , C10G2400/22 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C11/04 , C08F4/12 , C08F4/16 , C08F4/025 , C08F4/005
摘要： The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to making a formulated molecular sieve catalyst composition from a slurry of formulation composition of a synthesized molecular sieve that has not been fully dried, a binder and an optional matrix material. In a more preferred embodiment, the weight ratio of the binder to the molecular sieve and/or the solid content of the slurry is controlled to provide an improved attrition resistant catalyst composition, particularly useful in a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
摘要翻译： 本发明涉及分子筛催化剂组合物，制备或形成分子筛催化剂组合物的方法，以及使用该催化剂组合物的转化方法。 特别地，本发明涉及从尚未完全干燥的合成分子筛的配方组合物的浆料，粘合剂和任选的基质材料制备配制的分子筛催化剂组合物。 在更优选的实施方案中，控制粘合剂与分子筛的重量比和/或浆料的固体含量，以提供改进的耐磨性催化剂组合物，特别可用于生产烯烃的转化方法 乙烯和/或丙烯，优选含有氧化合物的原料。
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