Amine-functionalized liquid polyisoprene
    55.
    发明授权
    Amine-functionalized liquid polyisoprene 失效
    胺官能化液体聚异戊二烯

    公开(公告)号:US07608658B2

    公开(公告)日:2009-10-27

    申请号:US12267086

    申请日:2008-11-07

    IPC分类号: C08K3/36 C08F36/02 C08F26/06

    摘要: This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an amine moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy) silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold.

    摘要翻译: 本发明公开了一种通过液体注射成型制造弹性制品的方法,所述方法包括以下步骤:(I)加热可固化组合物,其包含(1)由衍生自共轭二烯烃单体的重复单元组成的液体聚合物, 其中所述液体聚合物的重均分子量在5,000至100,000的范围内,并且其中所述液体聚合物用胺部分官能化,(2)羰基抑制铂催化剂,和(3)四(二烷基甲硅烷氧基 )硅烷交联剂,温度在30℃至100℃的范围内。 (II)将加热的可固化组合物以100℃至210℃的温度注入模具中以制备弹性体制品; 和(III)从模具中去除弹性制品。

    SILICA REINFORCED RUBBER COMPOSITION WHICH CONTAINS OLEYLAMMONIUM BROMIDE AND/OR MERCAPTOIMIDAZOLIUM BROMIDE COUPLING AGENTS TO ENHANCE ELECTRICAL CONDUCTIVITY AND ARTICLE OF MANUFACTURE, INCLUDING A TIRE, HAVING AT LEAST ONE COMPONENT COMPRISED OF SUCH RUBBER COMPOSITION
    58.
    发明授权
    SILICA REINFORCED RUBBER COMPOSITION WHICH CONTAINS OLEYLAMMONIUM BROMIDE AND/OR MERCAPTOIMIDAZOLIUM BROMIDE COUPLING AGENTS TO ENHANCE ELECTRICAL CONDUCTIVITY AND ARTICLE OF MANUFACTURE, INCLUDING A TIRE, HAVING AT LEAST ONE COMPONENT COMPRISED OF SUCH RUBBER COMPOSITION 失效
    含硅橡胶的二氧化硅增强橡胶组合物和/或加强电连接剂的马赛克咪唑羧酸偶联剂和包括这种橡胶组合物在内的至少一个组分的制造方法(包括轮胎)

    公开(公告)号:US06476115B1

    公开(公告)日:2002-11-05

    申请号:US09944818

    申请日:2001-08-31

    IPC分类号: C08J302

    摘要: This invention relates to a conjugated diene-based rubber composition reinforced with silica-based reinforcement together with a non-silane coupling agent as N-3-(1,2-dihydroxypropyl)-N-oleylammonium bromide and/or N-3-(1,2-dihydroxypropyl)-N-methyl-2-mercaptoimidazolium bromide for endeavoring to both couple synthetic aggregates of precipitated silica to elastomers and enhancing electrical conductivity of such rubber compositions which contain less than 25 parts by weight carbon black per 100 parts by weight elastomer. Said coupling agent materials may be provided for mixing with said diene-based rubber(s), for example, as individual materials, as at least one of said materials being supported on a carbon black carrier or as being pre-reacted, or otherwise pre-treated, with synthetic silica aggregates. The invention includes an article of manufacture, including a tire, having at least one component comprised of such rubber composition.

    摘要翻译: 本发明涉及一种用二氧化硅基增强剂与非硅烷偶联剂N-3-(1,2-二羟基丙基)-N-油基溴化铵和/或N-3-( 1,2-二羟基丙基)-N-甲基-2-巯基咪唑溴化物,用于将沉淀二氧化硅的合成聚集体与弹性体相结合并提高这种橡胶组合物的导电性,每100重量份含有少于25重量份的炭黑 弹性体。 所述偶联剂材料可以提供用于与所述二烯基橡胶(例如,作为单独的材料)混合,因为至少一种所述材料负载在炭黑载体上或作为预反应,或以其他方式预先 用合成二氧化硅聚集体。 本发明包括具有至少一种由这种橡胶组合物组成的组分的包括轮胎的制品。

    SILICA REINFORCED RUBBER COMPOSITION WHICH CONTAINS STABILIZED UNSYMMETRICAL COUPLING AGENTS AND ARTICLE OF MANUFACTURE, INCLUDING A TIRE, HAVING AT LEAST ONE COMPONENT COMPRISED OF SUCH RUBBER COMPOSITION
    59.
    发明授权
    SILICA REINFORCED RUBBER COMPOSITION WHICH CONTAINS STABILIZED UNSYMMETRICAL COUPLING AGENTS AND ARTICLE OF MANUFACTURE, INCLUDING A TIRE, HAVING AT LEAST ONE COMPONENT COMPRISED OF SUCH RUBBER COMPOSITION 失效
    含有稳定的不对称偶联剂的二氧化硅增强橡胶组合物和包括这种橡胶组合物的至少一个组分的制造方法(包括轮胎)

    公开(公告)号:US06465581B1

    公开(公告)日:2002-10-15

    申请号:US09768299

    申请日:2001-01-24

    IPC分类号: C08L5544

    摘要: This invention relates to use of stabilized unsymmetrical coupling agents for use in conjugated diene-based rubber compositions reinforced with silica-based reinforcement, namely use of stabilized 2-benzothiazyl-3-(triethoxysilylpropyl) disulfide and 3-(triethoxysilyl)propyl-N-maleamic acid. Said stabilized unsymmetrical coupling agent materials may be provided for mixing with said diene-based rubber(s), for example, as individual materials, as at least one of said materials being pre-reacted with aggregates of precipitated silica, said precipitated silica having hydroxyl groups (e.g. silanol groups) on its surface. The invention includes an article of manufacture, including a tire, having at least one component comprised of such rubber composition.

    摘要翻译: 本发明涉及使用稳定的不对称偶联剂,用于用二氧化硅基增强剂增强的共轭二烯基橡胶组合物,即使用稳定的2-苯并噻唑-3-(三乙氧基甲硅烷基丙基)二硫化物和3-(三乙氧基甲硅烷基)丙基-N- 马来酰胺酸。 所述稳定的不对称偶联剂材料可以提供用于与所述二烯系橡胶混合,例如作为单独的材料,因为至少一种所述材料与沉淀二氧化硅的聚集体预反应,所述沉淀二氧化硅具有羟基 基团(如硅烷醇基)。 本发明包括具有至少一种由这种橡胶组合物组成的组分的包括轮胎的制品。