公开(公告)号：US3933910A

公开(公告)日：1976-01-20

申请号：US469939

申请日：1974-05-14

申请人： Helmut Waldmann ,  Hermann Seifer ,  Wulf Schwerdtel ,  Wolfgang Swodenk ,  Kurt-Wilheim Eichenhofer

发明人： Helmut Waldmann ,  Hermann Seifer ,  Wulf Schwerdtel ,  Wolfgang Swodenk ,  Kurt-Wilheim Eichenhofer

IPC分类号： C07C251/88 ,  C07C20060101 ,  C07C67/00 ,  C07C241/00 ,  C07C119/00

CPC分类号： C07C251/88

摘要： A process for the production of ketazine corresponding to the general formula ##EQU1## in which: R.sub.1 and R.sub.2 are independently linear or branched alkyl radicals of from 1 to 8 carbon atoms or a phenyl radical, or taken together with the carbon atom to which they are attached represent a carbocyclic ring with 5 to 8 carbon atoms or a cyclic alkyl radical with 5 to 8 carbon atoms, comprising reacting ammonia, hydrogen peroxide and a ketone of the general formulaR.sub.1 - CO - R.sub.2in which R.sub.1 and R.sub.2 are as defined above, in the presence of hydrocyanic acid.

摘要翻译： 对应于通式R 1 R 1的制备酮嗪的方法ANGLE C = N-N = C ANGLE R2R2其中：

公开(公告)号：US5660810A

公开(公告)日：1997-08-26

申请号：US554331

申请日：1995-11-06

申请人： Hans-Ulrich Dummersdorf ,  Helmut Waldmann ,  Helmut Harle ,  Franz-Rudolf Minz ,  Fritz Gestermann

发明人： Hans-Ulrich Dummersdorf ,  Helmut Waldmann ,  Helmut Harle ,  Franz-Rudolf Minz ,  Fritz Gestermann

IPC分类号： B01J10/00 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  C01B7/04 ,  C01B7/00 ,  C01B17/16

CPC分类号： B01J10/00 ,  B01J10/005 ,  B01J12/00 ,  B01J19/0006 ,  B01J19/24 ,  C01B7/04 ,  B01J2219/00067 ,  B01J2219/00103 ,  B01J2219/00162 ,  B01J2219/00182 ,  Y10S423/12

摘要： In the method for the chemical reaction of gaseous educts the educts are brought to reaction in a phase contact apparatus 1 in the presence of a catalytically active corrosive liquid. This corrosive liquid is delivered hydropneumatically in an intermittent cycle in the circuit from a sump vessel 4 connected to the lower end of the phase contact apparatus 1 to a supply vessel 9, connected to the upper end of the phase contact apparatus (delivery cycle), from which the corrosive liquid drains through the phase contact apparatus 1 and a connecting line 11 connected at its lower end and then collects in the sump vessel 4 (drainage cycle).

摘要翻译： 在气相离子的化学反应的方法中，在催化活性腐蚀性液体的存在下，在相位接触装置1中使溶出物反应。 这种腐蚀性液体在电路中以间歇循环的方式从连接到相位接触装置1的下端的贮槽4向连接到相位接触装置的上端（输送周期）的供给容器9输送， 腐蚀性液体从其中通过相位接触装置1排出，连接线11在其下端连接，然后收集在贮槽4中（排水循环）。

公开(公告)号：US5322965A

公开(公告)日：1994-06-21

申请号：US113581

申请日：1993-08-27

申请人： Otto Immel ,  Gerhard Darsow ,  Helmut Waldmann ,  Gerd-Michael Petruck

发明人： Otto Immel ,  Gerhard Darsow ,  Helmut Waldmann ,  Gerd-Michael Petruck

IPC分类号： B01J23/40 ,  B01J23/46 ,  B01J23/648 ,  C07C209/26 ,  C07C209/72

CPC分类号： B01J23/40 ,  B01J23/462 ,  B01J23/648 ,  C07C209/26 ,  C07C209/72 ,  C07C2101/14

摘要： Optionally substituted cyclohexylamine and optionally substituted dicyclohexylamine can be obtained by catalytic hydrogenation of optionally substituted aniline, a catalyst being employed which contains ruthenium, palladium or a mixture of both metals, which are applied to a support of niobic acid or tantalic acid or a mixture of both. The catalyst contains the noble metal(s) in a total amount from 0.05 to 5% by weight, relative to the total weight of the catalyst. In the case of the use of both noble metals, their weight ratio to one another is 1:9-9:1.

摘要翻译： 任选取代的环己胺和任选取代的二环己胺可以通过任选取代的苯胺的催化氢化获得，使用的催化剂包含钌，钯或两种金属的混合物，其被施用于铌酸或钽酸的载体或 都。 催化剂含有相对于催化剂总重量为0.05-5重量％的贵金属。 在使用贵金属的情况下，它们彼此的重量比为1:9-9:1。

公开(公告)号：US5196592A

公开(公告)日：1993-03-23

申请号：US805441

申请日：1991-12-11

申请人： Otto Immel ,  Helmut Waldmann ,  Reinhard Langer ,  Gerhard Darsow ,  Hans-Josef Buysch

发明人： Otto Immel ,  Helmut Waldmann ,  Reinhard Langer ,  Gerhard Darsow ,  Hans-Josef Buysch

IPC分类号： B01J27/055 ,  B01J23/46 ,  B01J23/58 ,  C07B61/00 ,  C07C209/52 ,  C07C209/68 ,  C07C211/54 ,  C07C211/55 ,  C07C213/02 ,  C07C215/76 ,  C07C217/84 ,  C07C217/90 ,  C07D521/00

CPC分类号： C07C209/68

摘要： Diphenylamine, which can be substituted by lower alkyl and/or lower alkoxy, is obtained from the corresponding N-cyclohexylidene-aniline by catalytic dehydrogenation, a rhodium-containing catalyst being employed.

摘要翻译： 可以由低级烷基和/或低级烷氧基取代的二苯胺通过催化脱氢从相应的N-亚环己基苯胺获得，使用含铑催化剂。

公开(公告)号：US4714689A

公开(公告)日：1987-12-22

申请号：US894581

申请日：1986-08-07

申请人： Gunter Stammann ,  Zoltan Kricsfalussy ,  Helmut Waldmann ,  Joachim Schneider ,  Harald Medem

发明人： Gunter Stammann ,  Zoltan Kricsfalussy ,  Helmut Waldmann ,  Joachim Schneider ,  Harald Medem

IPC分类号： B01J23/90 ,  B01J23/96 ,  B01J38/12 ,  C07C67/00 ,  C07C209/00 ,  C07C209/36 ,  C07C211/46 ,  B01J23/94 ,  B01J38/16

CPC分类号： B01J38/12 ,  B01J23/90 ,  C07C209/36 ,  Y02P20/584

摘要： Catalysts for the gas-phase reduction of aromatic nitro compounds to aromatic amines are regenerated by treatment of the catalyst, at elevated temperature, with a gas mixture which contains oxygen, inorganic and/or organic amines and/or nitrogen oxides and, where appropiate, steam.

摘要翻译： 用于将芳族硝基化合物气相还原成芳族胺的催化剂通过在升高的温度下用含有氧，无机和/或有机胺和/或氮氧化物的气体混合物处理催化剂再生， 蒸汽。

公开(公告)号：US4661646A

公开(公告)日：1987-04-28

申请号：US800495

申请日：1985-11-21

申请人： Rolf Schalenbach ,  Helmut Waldmann

发明人： Rolf Schalenbach ,  Helmut Waldmann

IPC分类号： B01J27/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/56 ,  C07C33/035 ,  C07C67/00

CPC分类号： C07C29/56

摘要： 1-Butene-3,4-diol is prepared by heat treatment of 2-butene-1,4-diol in the presence of catalytically active substances under acid conditions.

摘要翻译： 通过在酸性条件下在催化活性物质的存在下热处理2-丁烯-1,4-二醇来制备1-丁烯-3,4-二醇。

公开(公告)号：US4593116A

公开(公告)日：1986-06-03

申请号：US620207

申请日：1984-06-13

申请人： Gunter Stammann ,  Johann Grolig ,  Robert Becker ,  Helmut Waldmann

发明人： Gunter Stammann ,  Johann Grolig ,  Robert Becker ,  Helmut Waldmann

IPC分类号： C07B61/00 ,  B01J31/00 ,  B01J31/28 ,  C07C67/00 ,  C07C239/00 ,  C07C269/00 ,  C07C125/065 ,  C07C125/067 ,  C07C125/073 ,  C07C125/075

CPC分类号： C07C269/00

摘要： Urethanes are made by reacting an organic nitro compound with an organic compound containing at least one hydroxyl group in the presence of carbon monoxide, hydrogen and a catalyst system. The carbon monoxide and hydrogen are used in quantities such that the molar ratio of CO to H.sub.2 is from 0.3:1 to 3:1. The catalyst system is made up of at least one noble metal or compound of a noble metal from Group VIIIB of the Periodic System of Elements, at least one organic nitrogen base and a co-catalyst combination of iron or copper oxidic or hydroxidic compound and a chloride compound. The product urethanes are useful in the production of isocyanates and pesticides.

摘要翻译： 聚氨酯是通过在一氧化碳，氢气和催化剂体系的存在下使有机硝基化合物与含有至少一个羟基的有机化合物反应来制备的。 一氧化碳和氢气的使用量使得CO与H 2的摩尔比为0.3:1至3:1。 该催化剂体系由至少一种元素周期表第VIIIB族的贵金属或贵金属的化合物，至少一种有机氮碱和铁或铜氧化物或氢氧化物的助催化剂组合和 氯化物。 产品氨基甲酸酯可用于生产异氰酸酯和农药。

公开(公告)号：US4582923A

公开(公告)日：1986-04-15

申请号：US735249

申请日：1985-05-17

申请人： Gunter Stammann ,  Robert Becker ,  Johann Grolig ,  Helmut Waldmann

发明人： Gunter Stammann ,  Robert Becker ,  Johann Grolig ,  Helmut Waldmann

IPC分类号： C07B61/00 ,  B01J31/00 ,  B01J31/26 ,  B01J31/28 ,  B01J31/32 ,  C07C269/04 ,  C07C271/06 ,  C07C271/20 ,  C07C271/26 ,  C07C271/38 ,  C07C125/067 ,  C07C125/065 ,  C07C125/073 ,  C07C125/075

CPC分类号： C07C271/06

摘要： Urethanes are made by reacting a primary amine with carbon monoxide and a compound containing at least one hydroxyl group in the presence of an oxidizing agent and a catalyst system. The catalyst system is made up of (i) a noble metal and/or a noble metal compound of a metal of the Eighth Secondary Group of the Periodic System of Elements and (ii) an oxidizing quinoid and/or a compound capable of being converted to an oxidizing quinoid compound under the reaction conditions. The catalyst system may optionally include (iii) metal compounds of elements of the Third to Fifth Main Groups and/or First to Eighth Secondary Groups of the Periodic System of Elements and/or (iv) a tertiary amine. This reaction is generally carried out at a temperature of from 100.degree. to 300.degree. C. and at a pressure of from 5 to 500 bars. The product urethanes are useful in the production of isocyanates and pesticides.

摘要翻译： 聚氨酯通过在氧化剂和催化剂体系的存在下使伯胺与一氧化碳和含有至少一个羟基的化合物反应来制备。 催化剂体系由（i）贵金属和/或贵金属化合物的元素周期表第八族中的金属和/或氧化醌类和/或能够转化的化合物组成 在反应条件下与氧化喹啉化合物反应。 催化剂体系可以任选地包括（iii）元素周期表系统的第三至第五主族和/或第一至第八中间的元素的金属化合物和/或（ⅳ）叔胺。 该反应通常在100〜300℃的温度和5〜500巴的压力下进行。 产品氨基甲酸酯可用于生产异氰酸酯和农药。

公开(公告)号：USRE31381E

公开(公告)日：1983-09-13

申请号：US121604

申请日：1980-02-14

申请人： Gunter Prescher ,  Gerd Schreyer ,  Otto Weiberg ,  Rolf Wirthwein ,  Helmut Waldmann ,  Hermann Seifert ,  Wulf Schwerdtel ,  Wolf Swodenk

发明人： Gunter Prescher ,  Gerd Schreyer ,  Otto Weiberg ,  Rolf Wirthwein ,  Helmut Waldmann ,  Hermann Seifert ,  Wulf Schwerdtel ,  Wolf Swodenk

IPC分类号： C07C409/24 ,  C07D301/14 ,  C07D301/32

CPC分类号： C07D301/14 ,  C07C407/00 ,  C07C407/003

摘要： Process for continuous production of propylene oxide (FIG. 1) from propylene and aqueous hydrogen peroxide. The aqueous hydrogen peroxide is first reacted with propionic acid in the presence of acid catalyst to form perpropionic acid (1). The perpropionic acid is taken up by extraction in benzene (5, 18) and following drying of the benzene solution (21), the perpropionic acid in the solution is reacted with propylene (24) for oxidation of the propylene to propylene oxide and conversion of the perpropionic acid back to propionic acid. The reaction mixture is worked up to separate propylene oxide, propionic acid and benzene (30, 32, 37, 39), and the latter two are recycled. In the benzene extraction (5, 18), an aqueous raffinate (7) is formed containing hydrogen peroxide and acid catalyst. The aqueous raffinate can be divided into a stream which is recycled to the propionic acid reactor (1), and a second stream which can be distilled to remove water with the concentrate being recycled to the propionic acid reactor (1).

公开(公告)号：US4370275A

公开(公告)日：1983-01-25

申请号：US250363

申请日：1981-04-02

申请人： Gunter Stammann ,  Robert Becker ,  Johann Grolig ,  Helmut Waldmann

发明人： Gunter Stammann ,  Robert Becker ,  Johann Grolig ,  Helmut Waldmann

IPC分类号： C07C69/96 ,  B01J27/00 ,  B01J31/00 ,  B01J31/18 ,  C07C68/00

CPC分类号： B01J31/181 ,  B01J31/1805 ,  C07C68/005 ,  B01J2531/16

摘要： The invention relates to a process for the preparation of carbonic acid esters with high selectivity and under reaction conditions which permit high space/time yields, said process being one in which an alcohol is allowed to react with a mixture of molecular oxygen and carbon monoxide in the liquid phase in the presence of a catalyst system containing copper, chemically bonded oxygen, chemically bonded halogen and at least one nitrogen base.

摘要翻译： 本发明涉及一种高选择性和在允许高空间/时间产率的反应条件下制备碳酸酯的方法，所述方法是使醇与分子氧和一氧化碳的混合物反应的方法 在含有铜，化学键合的氧，化学键合的卤素和至少一个氮碱的催化剂体系存在下的液相。